简介：Newmetal-freeorganicdyesensitizerscontainingmono-triphenylamineorbis-triphenylamineastheelectrondonor,athiopheneastheπ-conjugatedsystem,andacyanoacrylicacidmoietyastheelectronacceptorweresynthesized.Theopticalandelectrochemicalpropertiesofthedyeswereinvestigated,andtheirperformanceassensitizersinsolarcellswasevaluated.Dye-sensitizedsolarcellsbasedondyecontainingbis-triphenylamineastheelectrondonorproducedaphoton-to-currentconversionefficiencyof6.06%(Jsc=14.21mA/cm~2,Voc=0.62V,ff=0.69)under100mW/cm~2simulatedAM1.5Gsolarirradiation(100mW/cm~2).

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简介：Inthispaper,westudytheCauchyproblemforthe3DgeneralizedNavier-Stokes-Boussinesqequationswithfractionaldiffusion:{ut+（u·▽）u+v∧2αu=-▽p+θe（3）,e3=（0,0,1）T,θt+（u·▽）θ=0,Dicu=0.Withthehelpofthesmoothingeffectofthefractionaldiffusionoperatorandalogarithmicestimate,weprovetheglobalwell-posednessforthissystemwithα≥5/4.Moreover,theuniquenessandcontinuityofthesolutionwithweakerinitialdataisbasedonFourierlocalizationtechnique.Ourresultsextendonesonthe3DNavier-Stokesequationswithfractionaldiffusion.

简介：Anewmethodforfabricatingorderedporoussiliconisreported.Atwo-dimensionalsilicananospherearrayisusedasatemplatewithahydrofluoricacid-hydrogenperoxidesolutionforetchingthenanospheres.Theinitialdiameteranddistributionoftheholesintheresultingporoussiliconlayeraredeterminedbythesizeanddistributionofthesilicananospheres.Thecorrosiontimecanbeusedtocontrolthedepthsoftheholes.ItisfoundthatthepresenceofaSiO_2layer,formedbytheoxidationoftheroughinternalsurfaceofthehole,istheprimaryreasonallowingthecorrosiontoproceed.Ultravioletreflectionandthermalconductivitymeasurementsshowthatthediameteranddistributionoftheholeshaveagreatinfluenceonpropertiesoftheporoussilicon.

简介：本文讨论了求解Sylvester方程AXB＋CX=D的OROD迭代法（正交残量法和正交方向迭代法）的几个重要性质，证明了该算法产生的误差序列是单调递减的，同时给出了该算法的最小化性质的精确刻画，最后给出了一些数值例子．

简介：Inthispaper,weinvestigatetheglobalexistenceandlongtimebehaviorofstrongsolutionsforcompressiblenematicliquidcrystalflowsinthreedimensionalwholespace.TheglobalexistenceofstrongsolutionsisobtainedbythestandardenergymethodundertheconditionthattheinitialdataareclosetotheconstantequilibriumstateinH~2-framework.IftheinitialdatasinL~1-normarefiniteadditionally,theoptimaltimedecayratesofstrongsolutionsareestablished.WiththehelpofFouriersplittingmethod,onealsoestablishesoptimaltimedecayratesforthehigherorderspatialderivativesofdirector.

简介：利用水热工艺,选用有机配体3,3’,5,5’-四甲基-4,4’-联邻二氮杂茂（H2X）和CuCl2·2H2O为起始原料,合成了1个新的多酸基杂化化合物[Cu2（H2X）2（Mo6O19）]·2H2O被合成.采用X-射线单晶衍射、红外光谱、元素分析和热重分析等手段对该化合物的结构进行了表征.单晶测试结果表明该化合物为1D链状化合物,属于三斜晶系,P-1空间群,晶胞参数a=0.9469（3）nm,b=0.9544（3）nm,c=2.0599（6）nm,α=90.717（4）°,β=93.518（5）°,γ=102.802（4）°,V=1.8112（9）nm3,Z=4,R1=0.0829,wR2=0.1512.

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简介：利用L-脯氨酸催化的5-氯水杨醛（1）与6-甲基-4-羟基吡喃酮（2）的缩合反应及硫酸铜催化下与1,3-二甲基-5-氨基吡唑（3）的串联反应,合成得到了10-氯-1,3-二甲基-5-（2-氧代丙基）色烯并[4,3-d]吡唑并[3,4-b]吡啶-6（3H）-酮（4）和10-氯-5-二乙氧基甲基-1,3-二甲基色烯并[4,3-d]吡唑并[3,4-b]吡啶-6（3H）-酮（5）.化合物5的结构通过单晶X射线衍射法确定：晶体属于三斜晶系,空间群P-1;相对分子质量Mr=803.68;晶胞参数a=1.03160（10）nm,b=1.42900（13）nm,c=1.44268（15）nm;V=1.9448（3）nm~3;Z=2;晶胞密度Dc=1.372g/cm~3;吸收系数μ=0.228mm-1;单胞中电子的数目F（000）=840.晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子为R=0.0681,wR=0.2051.在晶体结构中色烯环与吡啶环及吡唑环近似于共平面.