简介:TodepictthedetailsthatCHOP(C/EBPhomologousprotein)regulatesautophagyandapoptosisinbreastcancercells,theexpressionofCHOPwasinhibitedbytransfectionwithsiRNAsequence.AsshowninFig.1,radiati-Fig.1CHOPinhibitionbysiRNAatmRNAandproteinlevelsafterradiation.onelicitedahigherexpressionofCHOPintheNCgroupcomparedwithcontrol.However,thishigherexpressionwassignificantlyinhibitedinthesiRNAgroup.
简介:采用粉末压片制样,利用X射线荧光光谱分析仪,对石灰石、白云石等灰岩类标准物质拟合校准曲线,建立了X射线荧光光谱(XRF)法同时测定灰岩类样品中主次量组分(SiO2、Al2O3、TFe2O3、MgO、CaO、K2O、Na2O、MnO、P)的快速分析方法。通过灼烧减量对SiO2、Al2O3、TFe2O3、MgO、CaO5种主量成分含量进行换算后建立校准曲线,大大地改善了分析的准确度和精密度。通过实验优化了制样条件,对灰岩类试样进行精密度考察,各组分含量的相对标准偏差(RSD)<2%;对石灰石、白云石标准样品和实际样品进行准确度考察,测定值与标准推荐值或传统方法的测定值一致。
简介:Twotransmissioncurvedcrystalspectrometersaredesignedtomeasurethehardx-rayemissioninthelaserfusionexperimentofComptonradiographyofimplosiontargetonShenGuang-IIIlaserfacilityinChina.Cylindricallycurvedα-quartz(10–11)crystalswithcurvatureradiiof150and300mmareusedtocoverspectralrangesof10–56and17–100keV,respectively.Thedistancebetweenthecrystalandthex-raysourcecanbechangedoverabroaddistancefrom200to1500mm.Theopticaldesign,includingtheintegralreflectivityofthecurvedcrystal,thesensitivity,andthespectralresolutionofthespectrometers,isdiscussed.WealsoprovidemechanicdesigndetailsandexperimentalresultsusingaMoanodex-raysource.High-qualityspectrawereobtained.Weconfirmedthatthespectralresolutioncanbeimprovedbyincreasingtheworkingdistance,whichisthedistancebetweentherecordingmediumandtheRowlandcircle.
简介:阴极材料李[CoxNiyMn1?x?y]为锂的O2第二等的电池被一条新线路作为一位先锋用分层的双氢氧化物(LDH)准备了。结果有-NaFeO2结构的分层的阶段在菱形的系统结晶,与有到0.47nm的夹层间距结束的空格组R-3m。X光检查光电子光谱学(XPS)被用来测量公司,Ni和Mn的氧化状态。在结构和李的电气化学的性质上改变Co/Ni/Mn比率的效果[CoxNiyMn1?x?y]O2被X光检查衍射和电气化学的测试调查了。产品表明了相当稳定的骑车行为,与为有Co/Ni/Mn=1/1/1的分层的材料的118mAh/g的一个可逆能力。
简介:Aseriesoftitlecompoundsaswellastheirprecursorsweresynthesizedbyprecursorroute.TheirPXRDpatternswerecharacterizedwithZrW2O8orZrMo2O8modelbyRietveldmethod.Thethermalcontractionsofthecompoundsweredeterminedaccordingtothevariable-temperaturePXRDdataandNTEcoefficientswerepresented.Thetwo-phasemixtureofZrW0.4Mo1.6O8wasalsoanalyzedindividually.
简介:目前,国内没有关于半钢发热剂的国家标准检测方法,只能根据组分范围分别检测各个组分,不仅耗时而且使用的大量化学试剂对环境造成污染。故研究了X-射线荧光光谱法快速测定半钢发热剂中Si,P,S的方法。采用粉末压片制样,研究其制样条件,包括磨样时间、压样时间和压力对测定结果的影响。采用其它方法定值提供的检测样品,作为x-射线荧光光谱法内控标准样品,采用经验系数法进行基体校正,通过解谱拟合建立校准曲线,校准曲线建立后仪器建立漂移校正程序。实验结果精密度好,各元素的相对标准偏差在0.15%-1.3%。准确度满足生产需求,实验方法可用于快速检测半钢发热剂化学组分。
简介:ThedetailedmicrostructuresofNi80Fe20/Fe50Mn50superlatticeshavebeencharacterizedusingbothx-raydiffractiontechniquesandtransmissionelectronmicroscopy.Theobrivouslayeredstructure,typicalcolumnstructureandtwinswhichexistinNi80Fe20/Fe50Mn50superlatticeswereobservedthroughperformingtransmissionmicroscopy.Bycombiningthetechniqueoflowanglex-rayreflectivity(specularandoff-specularscans)withtheanomalousscatteringeffectandhigh-anglex-raydiffraction(usingconventionalx-ray),wequantitativelyanalysedthemicrostructuralvariationasafunctionofannealingtemperature.Itisfoundthatthelateralcorrelationlength,the(111)peakintensityofthesuperlatticesandtheaveragemultilayercoherencelengthallincreasewithariseinannealingtemperatureannealingcandecreasetherootmean-squareroughnessattheinterfacesofNi80Fe20/Fe50Mn50superlattices.theobtainedmicrostructuralknowledgewillbehelpfulinunderstandingthemagneticpropertiesoftheni80Fe20/Fe50Mn50exchangebiassystem.
简介:传统的化学分析方法分析硅酸盐类矿物样品组份,操作过程繁琐、分析周期长、劳动强度较大,分析结果受分析人员及各种试剂因素影响较大。采用国产能量色散X-射线荧光分析仪,以Li2B4O7和LiBO2作混合熔剂,NH4NO3为氧化剂,熔融制作玻璃熔片,对硅酸盐中SiO2等10个主要成分含量进行同时分析,建立了能量色散X-射线荧光光谱法测定硅酸盐主成分含量的方法,准确度和精密度均达到了规范要求,得到了较为满意的分析结果。