简介：ThehydrolysisofcephanoneinTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsionwerestudiedbymeansofUV-Visabsorptionspectroscopy.Theresultsshowthatcomparedwithwater,TritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsioncaninhibitthehydrolysisofcephanone.TheinhibitioneffectsofTritonX-100micelleandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiononthehydrolysisofcephanonearerelatedtothelocationofcephanoneintheinterphasesofTritonX-100micellesandTritonX-100/n-C5H11OH/H2O(O/W)microemulsiondroplets.

简介：针对多种类不锈钢多元素成分解析问题,应用X射线荧光光谱分析软件UniQuant,采用扩展基本参数法对多元不锈钢、双相不锈钢进行光谱干扰校正和基体校正,重新设定和优化多元不锈钢基体元素的测试条件,计算背景因子、杂质因子、谱线灵敏度系数和光谱重叠系数,测定Si、Mn、S、P、Ni、Cr、Cu、Mo、V、Al、Ti、Nb、Co、Ta、Fe的相对标准偏差在0.04%-3.8%,Ca、Zr、W、As、Sb、Sn的相对标准偏差在5.4%-20.3%,未知样品检测值与认定值比对结果相当理想,Ni、Cr的平均偏差小于0.05%,可以用很少标准样品实现各类型不锈钢多元素成分准确检测,检测范围宽,适用性好。

简介：在MP2/6-311＋＋G＊＊水平上优化乙烯酮自由基与LiX（X=F,Cl,Br）形成锂键复合物.当卤素的电负性很强（如F元素）,使得Li原子处于缺电子状态,此时,电子给体会把电子偏移向锂,形成共价性较强的锂键.而当卤素的电负性减弱时,锂键中主要成分逐渐变为离子键,并且此时锂键性质还要受电子给体影响.另外,由于HCCO为缺电子结构,电负性较弱且体积较大的卤素中的孤对电子会与HCCO之间通过静电相互作用,使得HCCO…Li—X键夹角变小,接近120°.锂键性质对HCCO…LiX（X=F,Cl,Br）复合物中Li—X的伸缩振动频率有直接影响.当锂键表现为共价性时,该频率红移,而当锂键表现为离子性时,该频率蓝移.但是,由于Cl的电负性与O的接近,C的电负性与Br接近所以,在O…Li…Cl和C…Li…Br中容易形成共振结构,导致远大于在其他复合物中的红移.

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简介：Wereportthatβ’-Gd2(MoO4)3crystalshavebeengrownbytheCzochralski(CZ)method.Westudiedthegrowthconditionsfoβ’-Gd2(MoO4)3crystal.Acompatisonbetweentheresistance-heatedmethodandradiofrequencyinduction-heatedmethodisdescribed.Also,theinsituobservationofthedomainstructurebythemicroscopeandbysynchrotronradiationX-raytopographyundertheconditionsofDCpolarizationvoltageandtempertaturechangewerecarriedout.Experimentsshowedthatmultidomainstructureincludingferroelectricandferroelasticdomainsoccurredinβ’-Gd2(MoO4)3cystal.Usuallyferroeletiricdomainsappearedintheas-growncrystalandferroelasticdomainsappearedinthepolishedthinnerpiece.BothferroelectricandferroelasticdomainsdisappearedwhenthetemperatureofthecrystalpiecewashigherthantheCurietempperatureTcandtheycouldbereproducedwhenthetemperatureofthecrystalpiecewasloweredbelowTC.WhenaDCpolarizationvoltagerangingfrom150to500Vwasappliedonac-axisβ’-Gd2(MoO4)3piecehavingathicknessof0.5mm,themultidomainwouldgraduallytransformtoasingledomain.Thisresualmeansthatitispossibletomakeaperiodicallypoledβ’-Gd2(MoO4)3crystal.2001ElsevierScienceB.V.Allrightsreserved.

简介：提出了以自制的标准样品,采用单点法绘制校准曲线,利用X射线荧光光谱仪测定FeSiB非晶薄带样品中硅、硼和铁的含量。对于4个FeSiB非晶合金薄带样品中硅、硼和铁进行了10次测定,其分析结果的相对标准偏差分别为0.4%~0.5%、1.3%~4.2%和0.2%~0.4%。方法的分析结果与火花源原子发射光谱法、化学重量法和电感耦合等离子体原子发射光谱（ICP-AES）法的测定值吻合较好。方法快速、简便,薄带样品无需制样,适用于FeSiB非晶合金薄带的快速成分分析。

简介：Si-richsiliconnitridefilmsarepreparedbyplasma-enhancedchemicalvapordepositionmethod,followedbythermalannealingtoformtheSinanocrystals(Si-NCs)embeddedinSiNxfloatinggateMOSstructures.Thecapacitance–voltage(C–V),current–voltage(I–V),andadmittance–voltage(G–V)measurementsareusedtoinvestigatethechargingcharacteristics.Itisfoundthatthemaximumflatbandvoltageshift(△VFB)duetofullchargedholes(～6.2V)ismuchlargerthanthatduetofullchargedelectrons(～1V).ThechargingdisplacementcurrentpeaksofelectronsandholescanbealsoobservedbytheI–Vmeasurements,respectively.FromtheG–VmeasurementswefindthattheholeinjectionisinfluencedbytheoxideholetrapswhicharelocatedneartheSiO2/Si-substrateinterface.CombiningtheresultsofC–VandG–Vmeasurements,wefindthattheholechargingoftheSi-NCsoccursviaatwo-steptunnelingmechanism.TheevolutionofG–VpeakoriginatedfromoxidetrapsexhibitstheprocessofholeinjectionintothesedefectsandtransferringtotheSi-NCs.

简介：Ceriumoxidenanoparticlescoatedbysodiumbis(2-ethylexyl)sulphosuccinate(AOT)werepreparedbyusingamicroemulsionmethod.Transmissionelectronmicroscopyrevealedanaverageparticlesiaeof2-3nm.X-raydiffractionshowedthattheceriumoxidenanoparticlesretaintheCeF2-typecubicstructureslikethebulkcrystal.Theintermediatevalenceofformallytetravalentcompoundshadbeendetectedbyx-ray-absorptionnear-edgestructetravalentcompoundshadbeendetectedbyx-ray-absorptionnear-degestructure(XANES)spectraofCeLIIIabsorptioninbulkCeO2andtheceriumoxidenanoparticles.Twowellresovedwhitelinescanbeassignedtotheelectronconfigurationsof4f^0Land4f^1L,respectively,whereLdenotesaligandhole.Atthesametime,theceriumoxidenanoparticlesalsoshowedthestructuralfeatresoftrivalentcompounds,incomparisontothetrivalentCe(NO3)3·6H2O.FuorLorentzianfunctionsandtwoarctanfunctionswereusedtofitthenormalizedXANESspectra.Theextendedx-ray-absorptionfine-structure(EXAFS)techniquewasusedtoprobethelocalatomicstructuresaroundtheabsorberCe.ThemultielectrornexcitationeffectontheEXAFSspectrawaseliminated.Acor-shellmodelwasusedtodeducethenear-neighbourstructuralparametersaroundcerium.BulkCeO2witheightoxygenatomslocatedat2.343AwasusedasthereferencesampletoextractthebackscatteringamplitudeandphaseshiftoftheCe-Obond.OnehalfoftheatomelocateatthecorepartwiththeCeF2-typecubicstructures(eightoxyensat2.343AaroundCe),theotherhalfoftheatomsareamorphousphaselocatedintheshellpart(surfaceofthenanoparticles)withapproximatelyCe2O3structuralfeatures(averageedsevenoxygensat2.50AaroundCe).

简介：theAlternatingSegmentCrank-Nicolsonschemeforone-dimensionaldiffusionequationhasbeendevelopedin[1],andtheAlternatingBlockCrank-Nicolsonmethodfortwo-dimensionalproblemin[2].Themethodshavetheadvantagesofparallelcomputing,stabilityandgoodaccuracy.Inthispaperforthetwo-dimensionaldiffusionequation,thenetregionisdividedintobands,aspecialkindofblock.ThismethodiscalledthealternatingBandCrank-Nicolsonmethod.

简介：摘要高质量电能和水电站安全、稳定运行深度联系，而这离不开行之有效的监控。因此，本文从不同角度入手客观分析了中小型水电站计算机监控系统软件设计与实现，促使计算机监控系统运行更加可靠，实时高效监控的同时持续改进供电质量，满足广大人民群众日常生产生活以及经济发展对电能的需求，持续提升水电站运行效益。

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简介：提出了偏振能量色散x射线荧光光谱法测定炼钢污泥中化学成分的方法，优化了仪器的工作条件。在最佳分析条件下，测定了炼钢污泥样品中TFe、SiOz、MgO、AIzOs、P和CaO的含量，所测定的6种成分的相对标准偏差均小于3％，并对污泥试样进行了测定，其分析结果与用化学法的测定值相一致。采用偏振能量色散X射线荧光光谱法测定炼钢污泥中TFe等成分周期短、准确度高，方法简便、快速，完全能满足生产需求。

简介：本文首次采用高温高压固相反应法合成类钙钛矿化合物Ba1－xLaxTiO3（x＝0．0，0．1，0．2，0．3，0．4，0．5）。XRD谱的测量结果表明，在压力为2．8GPa，温度为850℃下，稀土La在BaTiO3中的替代导致结构从立方到四方到正交的结构转变，因此，Ba1－xLaxTiO3体系体现结构转变规律和丰富的物相结构。

简介：ThecatalyticactivitiesofMnOx-WO3/TiO2forselectivecatalyticreduction(SCR)ofNOwithNH3wereinvestigatedinawiderangeoftemperatureandreactioncondition.ItyieldedaNOxconversionof80.3%-99.6%andaN2productselectivityof100%-98.7%during100°Cto350°Catgashourlyspacevelocity(GHSV)=18900h-1.Inthepresenceof0.01%SO2and6%H2Oat120°C,theNOxconversioncanmaintain98.5%.At300°Candwith0.07%SO2inreactantstream,theNOxconversionstabilizedat99%ashighasthecommercialV-W/TiO2catalyst'slevel.Thesteady-statekineticsstudyshowsthatO2playedapromotingrole.Inthepresenceoflessthan1.5%O2,NOxconversioncanincreasesharplywiththeincreaseofO2concentration.ThereactionorderwaszerowithrespecttoNH3andfirstwithrespecttoNOwithexcessO2andH2O.Thekineticsactiveenergy(Ea)ofMn-W/TiO2wascalculatedtobe6.24kJ/molaccordingtothekineticexperimentatvarioustemperatures,muchlowerthanthoseofothercatalystsreportedintheliterature.Mn-W/TiO2isanexcellentcatalystforSCRofNOwithNH3bynow.

简介：Tonguesquamouscellcarcinoma(ToSCC)isthemostcommontypeofheadandnecksquamouscellcarcinomaandisthesixthleadingcauseofcancerdeathsworldwide[1].Inclinicaloncology,radiationtherapyisastandardtreatmentusedfortumors.Numerousstudieshaveshownthatconventionalradiotherapyusedincancertreatmentmayincreasetheriskofmetastasisofmalignanttumorcells[2–4].Toimprovepatientsurvival,thepotentialformetastasisoftumorsinresponsetoradiationneedstobeaddressed.

简介：二维拉氏自适应流体动力学软件LAD2D，是采用建立在拉氏自适应结构和非结构网格上的有限体积格式，可以计算平面二维和柱对称二维多物质大变形弹塑性流体动力学问题。LAD2D软件系统主要由5部分组成：主控程序、数据模块、前处理模块、主体计算模块、网格模块和后处理模块。其中主体计算采用了结构网格与非结构网格联合使用的拉氏网格体系，计算格式采用了有限体积格式。网格模块包括网格生成、自适应网格加密（AMR技术）和网格重分技术，以及网格改变后物理量守恒重映技术。LAD2D软件系统由主体程序、二维网格生成程序（GRID2D）、二维自适应网格加密程序（AMR2D）、二维自适应程序（ADAPT2D）f[I-维物理量重映程序（REMAP2D）组成。

简介：Self-emissionx-rayshadowgraphyprovidesamethodtomeasuretheablation-fronttrajectoryandlow-modenonuniformityofatargetimplodedbydirectlyilluminatingafusioncapsulewithlaserbeams.Thetechniqueusestime-resolvedimagesofsoftx-rays(>1keV)emittedfromthecoronalplasmaofthetargetimagedontoanx-rayframingcameratodeterminethepositionoftheablationfront.Methodsusedtoaccuratelymeasuretheablation-frontradius(δR=±1.15μm),image-to-imagetiming(δ(t)=±2.5ps)andabsolutetiming(δt=±10ps)arepresented.Angularaveragingoftheimagesprovidesanaverageradiusmeasurementofδ(Rav)=±0.15μmandanerrorinvelocityofδV/V=±3%.ThistechniquewasappliedontheOmegaLaserFacility[Boehlyetal.,Opt.Commun.133,495(1997)]andtheNationalIgnitionFacility[CampbellandHogan,PlasmaPhys.Control.Fusion41,B39(1999)].

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简介：Twoseriesofmixedoxides,CoAlMandMgAlM(M=Cr,Mn,Fe,Co,Ni,Cu),werepreparedbycalciningtheircorrespondinghydrotalcite-likecompounds(HTLc).TheratioofMg:Al:M(orCo:Al:M)was3:1:1.ThecatalyticactivityofallsamplesforthereactionofNO+COwasinvestigated.TheresultsshowedthattheactivityofCoAlMwasmuchhigherthanthatofMgAlM.ThestructureandthepropertyofredoxwerecharacterizedbyXRDandH2-TPR.TheresultsindicatedthatonlyMgOphasewasobservedaftercalciningMgAlMhydrotalcites,andthetransitionmetalsbecamemorestable.Thespinel-likephaseappearedinallofCoAlMsamplesafterthecalcination,andthetransitionmetalswerechangedtobemoreactive,andeasilyreduced.TheactivitiesofthreeseriesofmixedoxidesCoAlCuobtainedfromdifferentpreparationmethods,differentratioofCo:Al:Cuandatdifferentcalcinationtemperatures,werestudiedindetailforproposingthemechanismofreaction.TheabilityofadsorptionofNOandCO

简介：阐述了关于确定二维连续型随机变量（X，y）函数ax＋by概率分布的多种方法．