学科分类
/ 8
153 个结果
  • 简介:MossbauerEffectofRapidlyQuenchedAl-Fe-V-Si-MmAlloysWangJianqiang(王建强),ChaoYuesheng(晁月盛),ZengMeiguang(曾梅光),ZhangBaojin(张宝金),Ch...

  • 标签: M SSBAUER SPECTROSCOPY Misch METAL Al-Fe-V-Si-Mm
  • 简介:针对方大特钢公司60Si2Mn弹簧扁钢产品出现剪切端面裂纹问题,进行裂纹检测、剪切温度试验和不同温度下力学性能检测;分析发现剪切时的温度对裂纹产生的影响,发现剪切裂纹是剪切应力作用于偏析较严重部位形成的裂纹源在残余应力释放过程中扩展形成的横向裂纹.根据分析结果,在生产实践中分别对炼钢、轧制工序采取相应措施,有效控制了弹簧扁钢的剪切端面裂纹.

  • 标签: 弹簧扁钢 裂纹 剪切温度 偏析 原因分析
  • 简介:镍离子本身具有鲜艳的兰绿色,这一特性可用于镍的测定。文章结合La-Ni-Al合金中镍的测定方法研究,重点考察了本色光度法测镍的相关条件,设计了La-Ni-Al合金中镍的分析方法。方法具有高选择性、准确、简便、快速、经济的优点。

  • 标签: 离子本色光度法 常量镍分析 测定方法
  • 简介:分析了影响45Mn17Al3钢磁导率性能的主要因素。通过工业试验确定了合理的化学成分、热处理工艺制度及试样表面加工要求等。试验结果表明,45Mn17Al3钢在800、4000及8000A/m三个磁场强度下,相对磁导率μr≤1.005,满足了某些特殊工程对磁性能的较高要求。

  • 标签: 45Mn17Al3钢 磁导率 化学成分 热处理工艺 表面加工要求
  • 简介:EffectofMnsubstitutionforFeincubicLavesZr0.1Tb0.9(Fe1-xMnx)2andY0.1Tb0.9(Fe1-xMnx)2com-poundsispresented.Similarresultsinbothsystemsareobtained:ThestructureandthemagnetismofTbFe2arebothinfluencedslightlybyasmallamountofYorZrsubstitutionforTb;Withincreasingxvalue,thelatticeconstantincreasesmonotonously;theCurietemperaturedecreaseslinearly;whilesaturationmagnetizationincreaseslinearly.ForthesmallamountofMnsubstitutionforFeinbothsystems,magnetostrictionissignificantlylargerthanthatinthepureironalloys.Thelargestmagnetostrictionof|γ‖-|γ|=2200×10-6atmagneticfieldof2×107/4πA/misobtainedforY0.1Tb0.9(Fe0.95Mn0.052.

  • 标签: MN MAGNETOSTRICTION Magnetic properties Cubic Laves
  • 简介:有一致形态学的新奇红射出的K2(Ge,Si)F6:Mn4+黄磷被一起沉淀方法综合。纯K2有P636阶段>除P3m1空间组以外的mc空间组就被Si的加入在K2在房间温度的GeF6根据XRD描述。薄片状的显示出的SEM图象和为K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+黄磷分别地。光致发光刺激(PLE)和光致发光(PL)在K2GeF6:Mn4+和K2(Ge,Si)F6:Mn4+系统。并且K2有Si的GeF6:Mn4+显示出一座强壮的山峰。同时水晶的地包围Mn4+变化能在这个氟化物系统影响腐烂时间。带的设备的颜色范围基于K2(Ge,Si)F6:Mn4+和K2分别地,GeF6:Mn4+到达了多达94.58%NTSC(国家电视标准委员会)和94.386%NTSC那基于氮化物红黄磷比那高得多。在K2(Ge,Si)F6:Mn4+黄磷的所有这些原来的特征作为为改善灯光和常规白LEDs的显示质量的红黄磷为潜在的应用是合乎需要的。

  • 标签: 红色荧光粉 白光LED SI Ge 发光性能 合成
  • 简介:TheNd60Fe20Al8Co10B2alloywaspreparedbysuctioncastingofthemoltenalloyintoacoppermoldunderargonatmosphere.Themicro-structuralandmagneticpropertychangesintheNd60Fe20Al8Co10B2alloyduringcrystallizationwereinvestigatedbyX-raydiffraction(XRD),differentialscanningcalorimetry(DSC),scanningelectronmicroscope(SEM)andthevibratingsamplemagnetometer(VSM).TheprecipitationandNd-richandFe-richphaseshavenosignificanteffectontheintrinsiccoercitityforNd60Fe20Al8Co10B2alloyannealedbelow723K.However,thegrowthofFe-richphasedecreasesthesaturatemagnetizationandremanenceofthealloy.Thehardmagneticbehaviorisdisappearedwhenthealloyisfullycrystallized.

  • 标签: Nd60Fe20Al8Co10B2 铸造合金 结构 磁性能 XRD DSC
  • 简介:Aseriesofnovelbluelong-lastingphosphorescencephosphorsSr6Al18Si2O37:Eu2+,RE3+(RE3+=Ho3+,Gd3+,Dy3+andPr3+)werepreparedbytheconventionalhigh-temperaturesolid-statereactioninareductiveatmosphere.TheirpropertiesweresystematicallyinvestigatedutilizingX-raydiffraction(XRD),photoluminescence,phosphorescenceandthermoluminescence(TL)spectra.ThephosphorsemittedbluelightthatwasrelatedtotheemissionofEu2+dueto5d-4ftransition.Brightbluelong-lastingphosphorescence(LLP)couldbeobservedaftertheexcitationsourcewasswitchedoff.Fortheoptimizedsample,thebluelong-lastingphosphorescencecouldlastfornearly4hinthelightperceptionofthedark-adaptedhumaneye(0.32mcd/m2).TheeffectsofRE3+ionsonphosphorescencepropertiesofthephosphorswerestudied,andtheresultsshowedthattheco-dopingofRE3+ionsgreatlyenhancedtheintensityofthepeakaround315Kwhichwasrelatedtothelonglastingphosphorescenceofthephosphorsatroomtemperatureandconsequentlyimprovedtheperformanceofthebluephosphorescencesuchasintensityandpersistenttime.

  • 标签: 荧光粉 长余辉 磷光 蓝色 发光特性 高温固相反应
  • 简介:Ca-dopedBaMgAl10O17:Eu2+,Mn2+(BAM)bluephosphorsweresynthesizedbyfluxassistedsolid-statereactionmethodusingCaF2andBaF2asco-flux.GooddispersityandparticlesizehomogenizationofhexagonalpurephaseBAMwereobtainedbysinteringat1400℃.TheeffectsoftheCa2+ionscontentonthestructure,morphologyandphotoluminescencepropertiesofthephosphorswerestudied.TheresultsindicatedthattheincorporationofCacoulddecreasethelatticeconstant,improvethehomogeneityanddispersityandenhancethephotoluminescence(PL)intensityofthephosphoreffectively.TheoptimumBa0.86Ca0.04Mg0.97Al10O17:0.1Eu2+,0.03Mn2+PLintensitywasenhancedforabout30%andrelativebrightnesswasimprovedabout4%.Furthermore,thesynthesizedBAMandcommercialBAMphosphorswereannealedfor30minat600oCinair.TheCa-dopedphosphorshadstrongeremissionintensity,higherbrightnessandbetterchromaticitystabilitythanthatofthecommercialphosphor.TheseresultsindicatedthatCa-dopedbluephosphorshadgoodpotentialapplicationsinthecommercialtricolorfluorescentlampsaswellasinotherdisplayandlamps.

  • 标签: 光致发光特性 蓝色荧光粉 钙掺杂 氟化钡 氟化钙 蓝色荧光体
  • 简介:EffectofCe-Mg-Si(lightRE)andY-Mg-Si(heavyRE)nodulizersonthemicrostructuresandmechanicalpropertiesofheavysectionductileironwasinvestigatedtodevelopthematerialofspent-nuclear-fuelcontainers.Twoas-castsweretreatedbythesamequalitypercentageoflightREandheavyRE,respectively.Fourpositionswerechosentostandfordifferentsolidificationcoolingratesofspecimens.Thetensilestrength,elongationandimpacttoughnessofspecimenstreatedbyheavyREwereallhigherthanthoseofthespecimenstreatedbylightRE.Withthedecreaseofcoolingrate,themechanicalpropertiesoftwospecimensdecreased,andthefracturemorphologychangedfromductilefracturetobrittlefracture.TheimprovingeffectofmechanicalpropertiesbetweenheavyREandlightREwasobviousduetothebetteranti-degradationpropertyofheavyRE.Whilethesolidificationprocesslastedformorethan250min,theimprovingeffectwasnotobviousduetoseriousspheroidalizationdecaying.

  • 标签: 大断面球铁 机械性能 微观结构 球化剂
  • 简介:Pr2Fe14B-La2Fe14B系统被衍射(XRD),微分扫描热量测定(DSC)和扫描电子显微镜学(SEM)与精力装备了的X光检查粉末调查散X光检查光谱学(版本)。水晶结构参数被完整侧面的Rietveld精炼决定。结果揭示了那所有合金(Pr1-xLax)2Fe14B使Nd2Fe14有空格组P42/mnm的B类型结构并且形成了连续固体在x=0.0之间的解决方案并且1.0。格子参数一,c,单位房间体积V和c/a比率与La集中线性地增加了。由thermogravimetry分析决定了,居里温度(TC),阶段转变温度和融化的温度(Pr1-xLax)2Fe14B在La内容之上线性地减少了。基于DSC大小和X光检查粉末衍射考试的结果,Pr2Fe14B-La2Fe14B系统被建立。

  • 标签: 水晶结构 格子参数 居里温度 热分析 稀土元素
  • 简介:Theslowtensiletests,dynamichydrogenchargingtensiletestsandhydrogenevolutiontestsafterhydrogenchargingwereusedtostudytheeffectsofrareearthmetal(REM)onhydrogenbehaviourinasteel16Mn(St.52).TheratiosofRE/Swerechosenas0,0.7,2.2and7.7,respectively.ItwasshownthatthesteelwithRE/S=2.2givealowerhydrogenembrittlementsusceptibilitythanothers.ThesteelswithoutREMcanadsorbmuchmoreamountofhydrogenthanthatwithREMunderthesamehydrogenchargingconditions.Andtheamountofadsorbedhydrogenfortheforinercanbeevolvedeasierthanthatforthelatteratroomtemperature,50℃and80℃,respectively.Theexperimentalresultswereexplainedbythetraptheoryofhydrogen,theshort-circuitdiffusionpathsintheinterfacesbetweentheelongatedMnSinclusionsandthematrix,andstrongabilityofREMtoadsorbhydrogen.

  • 标签: TENSILE elongated STEELS CHARGING adsorbed BEHAVIOUR
  • 简介:ToevaluatethepossibilityofusingGd-Si-Gealloysinmagneticrefrigerators,samplesofGd-Si-GealloysweremadeofdomesticGd.Themagnetocaloriceffectofsampleswasestimatedbymagneticentropychange(-ΔSm)calculatedfromM-HcurvesaccordingtoMaxwellrelation.ThefirstorderphasetransformationwasdestroyedduetotheimpuritiesinthecommercialGd,sothatnogiantmagnetocaloriceffectwasfound.ThesamplesmadeofpurifiedGdexhibitfirstorderphasetransformation,andthe-ΔSmisbasicallyconsistentwiththepublisheddataofAmeslaboratory,USA.ThisworkprovesthatGd-Si-GealloysmadeofdomesticGdcanbeutilizedinmagneticrefrigerators.

  • 标签: 金属材料 稀土元素 巨磁致发热效应 钆-硅-锗合金 钆杂质 稀土元素
  • 简介:Magnetizationanddemagnetizationcurvesandhysteresisloopsapplieddifferentmagnetizing.fieldsinsinteredNd-Fe-BandNd-Dy-Fe-Bmagnetsfromthermallydemagnetizedanddcfield-demagnetizedstateswereinvestigatedattemperaturesofupto150℃.Thefirst-quadrantremagnetizationcurvesandthecurvesofcoerciveforces_MH_CversusrernagnetizingfietdsH_mfromdcfield-demagnetizedstateatroomtemperatureshowasteparoundmagnetizingfieldasabsolutevalueofthemaximumintrinsiccoercivity.Thestepsof_MH_C-H_mcurvesshiftedtolowerremagnetizingfieldsandtheshapesofmagnetizationcurveschangedfromsteptypetoprecipitoustypewhentemperaturewentupto100~150℃orafterthespecimenwasthermallydemagnetizedatatemperaturehigherthantheCurietemperature.Thesteepriseofkneecoereivitywithincreasingmagnetizingfieldisbehindthatof_MH_C.NotethatthemagnetichardeninginsinteredNd-Fe-Bmagnetsiscontrolledbypinningofdomainwalls.

  • 标签: MAGNETIZATION COERCIVITY thermally HYSTERESIS ABSOLUTE walls