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500 个结果
  • 简介:存取2-substituted-N1-carbethoxy-2,3-dihydro-4(1H)一条灵巧、有效、新奇途径-quinazolinones是被代替N-carbethoxyanthranilamide冷凝作用用p-toluenesulfonic酸refluxing2,2,2-trifluoroethanol或hexafluoroisopropanol烷基,aromatic或异种aromatic醛开发催化剂。

  • 标签: 三氟乙醇 六氟异丙醇 氟溶剂 溶剂效应 喹啉氮杂化合物
  • 简介:Thetitlecomplex,[La(baec)1/2(H2btec)1/2(H2O)]n(H4btec=1,2,4,5-benzenetetracarboxylicacid)(1)wassynthesizedbythehydrothermalreactionof1,2,4,5-benzenetetracarboxylicdianhydridewithLa(NO3)3·6H2OinH2O,andcrystallizesinthetriclinicsystem,spacegroupP-1withα=0.64403(3)nm,b=0.94500(4)nm,c=0.96380(5)nm,α=88.535(2)°,β=100.314(2)°,γ=76.6470(10)°,V=1.69968(10)nm^3,Z=2,andfinalR=0.0274,Rw=0.0735.In1,eachLa(Ⅲ)ioniscoordinatedbyeightoxygenatomsfromsixcarboxylategroupsandonecoordinatedwatermolecule.TwodifferentcoordinstionmodesofH4btecwerePresentinthestructure,oneofwhichcontainstwoprotonatedcarboxylategrougpstobalancethecharge.

  • 标签: 水热合成 镧配合物 结构 1 2 4 5-苯四羧酸
  • 简介:Aseriesofnovel1H-benzimidazol-1-ylacetatesand1H-benzimidazol-1-ylpropionatescontaining1H-1,2,4-triazolemoietyweresynthesizedundermicrowaveirradiationbymulti-stepreactions,inyieldsof87-94%.TheirinvitroantifungalactivitiesagainstBotrytiscinereaandSclerotiniasclerotiorumwereevaluatedbymycelialgrowthratemethod.AllthetargetcompoundsexhibithighactivitiesagainstB.cinereawiththeEC50valuesof7.96-21.74μg/mL,higherthanthatofcarbendazim.

  • 标签: 抗真菌活性 苯并咪唑 乙酸酯 体外 合成 基团
  • 简介:SYNTHESISOF3-ARYL-H,4H)ACRIDONESANDTHEIRDERIVATIVES¥RongYIN;GuangFanHAN;YuTianLI(DepartmentofMedicalLaboratory,JilinMediea...

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  • 简介:霍尔多项谎言代数学和量组结构作为结构系数起一个重要作用,是众所周知。由使用表示范畴性质仿射发抖,计算霍尔多项任务仿射发抖能被归结为数一些矩阵方程答案数字。这个方法被使用了不能分解代表获得霍尔多项类型Ãm(m≥1)。

  • 标签: 多项式 仿射 模块 计算方法
  • 简介:Theground-stateandthermodynamicpropertiesofquantummixed-spinchainsof1/2-1/2-1-1and3/2-3/2-1-1areinvestigatedbyaquantumMonteCarlosimulationwiththeloop-clusteralgorithm.For1/2-1/2-1-1chain,wefindithastwophasesseparatedbyanenergy-gapvanishingpointintheground-state.For3/2-3/2-1-1chain,thenumericalresultsshowtwoenergy-gapvanishingpointsisolatedbydifferentphasesinitsground-state.Ourcalculationsindicatethatallthesegroundstatephasescanbeunderstoodbymeansofvalence-bond-solidpicture,andthethermodynamicbehavioratfinitetemperaturesiscontinuousasafunctionofparameterα=J2/J1.

  • 标签: 蒙特卡罗模拟 混合自旋链 铁磁性 基态 热力学性质 能隙
  • 简介:HAND ̄(13)CNMRSTUDYOFINCLUSIONCOMPLEXATIONOFDSSWITHβ-CYCLODEXTRIN¥QingXiangGUO;TanREN;ZiZhongLIandYouChengLIU(NationalLabora...

  • 标签: 13C NMR
  • 简介:In2010,theBESCollaboration[1]foundaclearenhancementintheK0K0massdistributionintheJ=ψ!ηK0K0decay.SuchanenhancementisusuallyasignatureofanL=0resonancearoundthreshold,whichinthiscasewouldcorrespondstoanh1statewithquantumnumbersIG(JPC)=0??(1+??).Thish1statewaspredictedbytheChiralUnitarytheoryintheKKinteraction.Becauseoftheconversationlaw,thisstatecanonlydecaytoK0K0channel,andcanbestudiedefficientlyintheJ=ψ!ηK0K0decay.

  • 标签: SIGNATURE SIGNATURE QUANTUM CLEAR can BES
  • 简介:Anewspectralproblemisproposed,andnonlineardifferentialequationsofthecorrespondinghierarchyareobtained.Withthehelpofthenonlinearizationapproachofeigenvalueproblems,anewfinite-dimensionalHamiltoniansystemonR2nisobtained.Ageneratingfunctionapproachisintroducedtoprovetheinvolutionofconservedintegralsanditsfunctionalindependence,andtheHamiltonianflowsarestraightenedbyintroducingtheAbel-Jacobicoordinates.Atlast,basedontheprinciplesofalgebracurve,thequasi-periodicsolutionsforthecorrespondingequationsareobtainedbysolvingtheordinarydifferentialequationsandinversingtheAbel-Jacobicoordinates.

  • 标签: 数学分析 数学理论 应用数学 函数
  • 简介:<正>(a1/2)2和(a21/2兄妹俩,一来花果山就受到众猴儿青睐,争相和他俩交朋友,哪知有的小猴对他俩不礼貌,有时还受到了委屈,于是他俩就到猴王那里去告状,兄妹俩来到猴王面前,深深行了个鞠躬礼说:“报告猴王,小猴儿常把我俩张冠李戴,用我俩来解题时,

  • 标签: 算术平方根 非负数 花果山 二次根式 彻底认识 彻底了解
  • 简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.

  • 标签: 分子结构 势能函数 自旋轨道耦合 电子态
  • 简介:摘要无人机摄影测量技术比较灵活,并且操作简单,因此,很多行业广泛使用。无人机摄影测量技术矿山储量动态监测中使用,能够快速,准确并实时监测矿山储量变化,从而为相关部门矿产开采提供技术支持,有利于防止矿产资源浪费。本文针对无人机摄影测量技术矿山储量动态监测应用进行了分析。

  • 标签: 无人机 摄影技术 矿山储量 动态监测
  • 简介:用变分方法证明H~1(R~N)上一个限制半线性椭圆特征问题解存在性.所获得三个解:一个是正解,一个是负解.对于第三个解,本文只证明了它存在性,没有确定它是正解,负解,还是变号解.

  • 标签: 椭圆特征问题 临界点理论 多解
  • 简介:一系列2,4,5-triarylvitro作为ALK5禁止者代替了1H-pyrazol-3(2H)-ones,,是desigened,综合并且评估。大多数混合物1μmol/L展出了显著ALK5抑制活动并且没在30μmol/L显示重要cytotoxicities。

  • 标签: 激酶 抑制剂 合成 生物评估 吡唑