简介:采用表面处理法修饰稀土氧化物WO3、CeO2,制备了WO3/CeO2/环氧树脂基多层辐射防护材料。利用扫描电镜(SEM)观察材料的微观结构;用多道Y谱仪和GammaVision软件对该多层辐射防护材料进行了辐射防护性能测试;运用蒙特卡洛模拟软件EGSnrc对光子在材料中的输运过程进行模拟,并通过计算注量,得出该材料线性衰减系数的理论值,与γ谱测试结果进行比较;比较双层结构中,WO3以及CeO2的先后顺序对于该多层辐射防护材料的影响。结果表明,制备的材料功能性颗粒分布均匀,有轻微团聚现象,在低能区间,CeO2在前的多层材料防护性能较为优越,但是在高能区间WO3在前的防护性能较好,模拟计算的线性衰减系数与实验结果基本吻合。
简介:ThemorphologyeffectofZr-dopedCeO2wasstudiedintermsoftheiractivitiesintheselectiveoxidationofstyrenetostyreneoxideusingtert-butylhydroperoxideastheoxidant.Inthepresentwork,ZrdopedCeO2nanorodsexhibitedthehighestcatalyticperformance(yieldofstyreneoxideandTOFvalue)followedbynanoparticlesandnanocubes.FortheZr-dopedCeO2nanorods,theapparentactivationenergyis56.3kJ/mol,whichismuchlowerthanthevaluesofcatalystssupportedonnanoparticlesandnanocubes(73.3and93.4kJ/mol).Thehighresolutiontransmissionelectronmicroscopyresultsindicatedthat(100)and(110)crystalplanesarepredominantlyexposedforZr-dopedCeO2nanorodswhile(100)and(111)fornanocubes,(111)fornanoparticles.TheremarkablyincreasedcatalyticactivityoftheZrdopedCeO2nanorodsismainlyattributedtothehigherpercentageofCe3+speciesandmoreoxygenvacancies,whichareassociatedwiththeirexposed(100)and(110)crystalplanes.Furthermore,recyclingstudiesprovedthattheheterogeneousZr-dopedCeO2nanorodsdidnotloseitsinitialhighcatalyticactivityafterfivesuccessiverecycles.
简介:TheinfluenceofrareearthoxideCeO2onmicrostructureandwearresistanceofM80S20thermalsprayandthermalsprayweldingcoatingsisstudiedusingopticalmicroscope,scanningelectronmicroscope,X-rayenergydispersionspectroscope,X-raydiffractometerandweartestingmachine.Theresultsshowthattheaddi-tionof8%CeO2canimprovethemicrostructure,microhardnessandwearresistanceofcoatingssignificantly.
简介:高度取向附生、纯(001)面向的CeO2电影被激光在SrTiO3(001)底层上种没有任何气体的分子的横梁取向附生方法周围。CeO2的Layer-by-layer取向附生的生长模式被证实由在situ思考高精力的电子衍射(RHEED)观察。高分辨率的X光检查衍射(HRXRD)和高分辨率的传播电子显微镜学(HRTEM)结果显示了STO(100)//CeO2(100),STO[100]//CeO2[110]为out-of-plane和在里面飞机的取向附生的关系分别地。取向附生的电影的形成机制也根据一个理论模型被讨论。LMBEceria电影的化学状态被评估并且证实因为Ce3+和氧空缺的存在被介绍。
简介:CeZr,CeYZr,LaCeZr,LaCePrZr,LaCePrYZr,和LaCePr稳固的答案经由一起沉淀方法被准备,并且借助于X光检查衍射(XRD)和Brunauer-Emmett-Teller(赌注)技术描绘了。稳固的答案的氧存储能力(振荡)被脉搏技术评估,催化活动用一台4隧道催化作用设备被估计。稳固的答案介绍了立方的结构,这被看见。特定的表面区域和热稳定性能被做Y进稳固的答案提高。当做大量La减少了时,做La的小数量在热耐久性上有积极效果特定的表面区域和热稳定性。LaCePrZr和LaCePrYZr固体解决方案用在Nd抽取在特定的表面区域和热稳定性介绍了某个更高的值以后,与LaCePr充实的Baotou稀土元素矿物质残余综合了,当为汽车的经济催化剂用尽纯化,从而启用被过去常。ceria氧化锆固体答案的表面上的涂层Al2O3或SiO2层增加了特定的表面区域和热抵抗。
简介:Loadedonthecordierite,therareearthdopedcompositecatalystwaspreparedbysol-gelmethodcombinedwithdippingtechnique.TakingOrthodichlorobenzeneasmodel,thecatalystwasusedtoremovethedioxinsofthewastegas.Theresultsshowedthatat280℃andgasspacevelocitybeing8000h-1,theorthodichlorobenzenecouldberemovedeffectivilybythepreparedCeO2-TiO2-V2O5compositecatalystwhoseactivitywasremarkablyenhancedbythedopingofCe,whiletheindustrialside-streamtestofdioxinsfromrefuseincinerationsmokeindicatedthatthedecompositionratecouldreachabove93%underthesameconditions.
简介:Praseodymium(Pr)wasimpregnatedtoCeO2-ZrO2solidsolutionbyanimpregnationmethod.Theas-obtainedPrmodifiedCeO2-ZrO2wasimpregnatedwith1wt.%Pdtopreparethecatalysts.ThestructureandreducibilityofthefreshandhydrothermallyagedcatalystswerecharacterizedbyX-raydiffraction(XRD),Raman,X-rayphotoelectronspectroscopy(XPS),COchemisorptionandH2temperature-programmedreduction(H2-TPR).Theoxygenstoragecapacity(OSC)wasevaluatedwithCOservingasprobegas.EffectsofimpregnatedPronthestructureandoxygenstoragecapacityofcatalystswereinvestigated.TheresultsshowedthattheagedPr-impregnatedsampleshadmuchhigherOSCandbetterreducibilitythantheunmodifiedones.TheschemeofstructuralevolutionsofthecatalystswithandwithoutPrwasalsoestablished.PartialoftheimpregnatedPrdiffusedintothebulkofCeO2-ZrO2duringageing,whichinhibitedthesintering,andincreasedtheamountofoxygenvacanciesinCeO2-ZrO2support.Furthermore,thoseimpregnatedPrspecieswhichcoveredonthesurfaceofthesupportobstructedthestrongmetal-supportinteractionbetweenPdandCesoastoreducetheencapsulationofPdaswellasthebackspill-overoftheoxygenduringthecatalyticprocess.