学科分类
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287 个结果
  • 简介:3种煤沥青为研究对象,采用元素分析、平均分子量、核磁共振氢谱(1H—NMR)以及红外光谱分别对其进行表征和分析,使用改进Brown-Ladner法对煤沥青的结构参数进行计算,并构建出各煤沥青的平均分子结构模型。结果表明,煤沥青的基本结构单元是稠环芳烃连接烷基侧链并含杂原子,结构单元之间形成缔合体,缔合数为5~9。3种煤沥青的烷基侧链都很短,且均不包含环烷烃。构建的分子模型为煤沥青提供了形象的化学结构,有助于从分子水平加深对其认识和研究。

  • 标签: 煤沥青 微观结构 改进Brown-Ladner法 结构参数分子模型
  • 简介:SkeletalformofKNbO3crystalsgrowinginLi2B4O7solventwasin-situobservedat900CanditwasfoundthatshallowdepressionstartedtodeveloponthesurfaceofKNbO3crystalswhenthecrystalsizeexceededseveralmicron,typically7micron.BasedonthequantitativecriterionderivedbyChernov,theestimatedcriticalsizeofKNbO3crystalswas1micron,whichwasconsistentwiththeexperimentalmeasurement.Thekineticcoefficients,kcerandkc,,inthecriterionwereexperimentallyobtainedinthediffusive-convectiveanddiffusive-advectiveflowstatesrespectively.

  • 标签: 铌酸钾晶体 硼酸锂 结构 晶体尺寸 组织 KNBO3
  • 简介:参考测试方法平行地被执行,借助于化学分析,X光检查衍射,微分扫描calorimetry-thermogravimetry,扫描电子显微镜学和当面学习C4A3S的形成的极化的光显微镜和起核心作用的代理人的缺席。当tricalcium硅酸盐(C3S)显然支持C4A3S和增加desulfurization度的形成,结果与高钙和低热消费显示出那个起核心作用的代理人。在锻烧与C3S做的未加工的饭期间,没有C3S,C4A3S的谷物尺寸与那相比是更大的。并且在一样的锻烧水平,集体损失和热,消费属于CaCO3分解被减少。

  • 标签: 成核剂 S形 C4A3S X射线衍射仪 差示扫描量热 硅酸三钙
  • 简介:美国旧金山的BESPOKEINNOVATIONS3D科技工作室设计的新型定制3D打印假肢,不仅可根据不同客户的情况量身裁定,而且还十分时髦。项目研发负责人表示,他们通过对常见的假肢制作材料整流装置进行改进,研发出新一代整流罩,为他们的新型假肢项目奠定了坚实的基础。

  • 标签: 3D打印 假肢 定制 整流装置 制作材料 旧金山
  • 简介:索尼V1的后继者能否延续V1在人们心中的威望呢?

  • 标签: 发烧友 索尼V1
  • 简介:采用溶胶-凝胶工艺,以Ni(Ac)2、La(NO33为前驱原料,以乙醇和乙二醇甲醚为溶剂,以丙烯酸为稳定剂,乙酰丙酮(AcAc)为化学修饰剂制备了感光性LNO溶胶。通过其溶胶的紫外和红外吸收光谱研究了感光性LNO溶胶的紫外感光机理,并运用溶胶-凝胶直接感光法制备出LNO薄膜的微细图形。

  • 标签: 镍酸镧薄膜 微细加工 溶胶-凝胶直接感光法 微细图形
  • 简介:Thebovinehydroxyapatite(BHA)wasappliedtopreparebiologicaltissueengineeringscaffoldsbythemethodofextrusionfreeforming.Toachievethisgoal,BHAwereaddedtosodiumalginate(SA)solutiontoformaslurrysysteminappropriateproportion.Theresultingmixtureswerefabricatedtobeakindofcontrollableandporousscaffoldsfollowedwithcross-linkingin5%calciumchloride(CaCl2)solutionfor24h.Afterthat,thescaffoldsweresinteredinairat1000,1100,1200and1300℃for5h.Scanningelectronmicroscopy(SEM)andX-raydiffraction(XRD)studieswereperformedonthescaffoldstoanalyzeitsmicrostructureandconstituent.Toexploretheeffectofsinteringtemperatureonscaffolds,thecompressivestrength,volumeshrinkageandwaterabsorptivityofBHA-SAcompositescaffoldsaftersinteringwereinvestigated.TheresearchtestsindicatedthefeasibilityofapplyingBHApowderto3Dprinting.Besides,thescaffoldssinteredinarespectivelylowertemperaturepossessmuchmoreporesandperformedhigherwaterabsorptivity,whichmeansbettercellularaffinity.Andscaffoldssinteredbetween1100and1200℃presentshighercompressivestrength.

  • 标签: BOVINE bone HYDROXYAPATITE ball MILLING SINTERING
  • 简介:Amathematicalmodelforthethree-dimensionalsimulationoffreedendriticgrowthandmicrostructureevolutionwasdevelopedbasedonthegrowthmechanismofcrystalgrainsandbasictransferequationssuchasheat,massandmomentumtransferequations.Manyfactorsincludingconstitutionalundercooling,curvatureundercoolingandanisotropy,whichhadvitalinfluencesonthemicrostructureevolution,wereconsideredinthemodel.SimulatedresultsshowedthatfinalmicrostructuralpatternsandfreedendriticgrowthcouldbepredictedreasonablyandcalculatedresultswerecoincidentwithexperimentalThesimulatedresultsoffreedendriticgrowthindicatedthatthestrengthofanisotropyhassignificanteffectsonfreedendriticgrowth,dendriteprofile,microsoluteandtemperaturedistribution.Thedendriticgrainprofileswithfully-grownparallelsecondaryarmtendtobeformedattheintensiveanisotropy,whilenearoctahedralgrainprofileswithsmallprotuberancesofsurfaceatlowstrengthofanisotropy.Thesimulatedresultsoffreedendriticgrowthalsoindicatedthattherearesmallmoltenpoolsleftininterdendriticareas.Thisishelpfultounderstandthefundamentaloftheformationofmicrostructurerelateddefectssuchasmicrosegregationandmicroporosity.

  • 标签: MODELING and simulation DENDRITIC GRAIN growth
  • 简介:Thevolatilizationkineticsofantimonytrisulfideinsteamatmospherewasstudiedwiththermogravimetryattemperaturesfrom923to1123K.Atheoreticalmodelwasdevelopedtocalculatetheoverallrateconstantandthemasstransfercoefficientingasphases.Theexperimentalresultsshowthatthevolatilizationrateisenhancedwithincreasingtemperatureandsteamflowrate.Thevolatilizationrateismainlycontrolledbythemasstransportingasphases.Theapparentactivationenergyfortheprocessisfoundtobe59.93kJ/mol.ItisdemonstratedthatSb2S3isdominantlyoxidizedintoSb2O3andH2Sbywatervaporinthevolatilizationprocess.Someantimonymetalisformed.Thereactionmechanismisdiscussedinaccordancewithexperimentaldata.

  • 标签: Sb2S3 挥发性 热量分析法
  • 简介:Throughmeasuringthecoefficientoflinearexpansion,thestructureandpropertiesoftheLi2O-Al2O3-SiO2lowexpansionglassceramicscontainingB2O3arestudiedbyJRandXRD.ItisshoutnthattheIRmethodisefficientinthestudyoftheglass-ceramicsstructure.Thereisa"Boronabnormality"inthesystemwhichhasanimportantinfluenceonthepropertiesoftheglass-ceramics.

  • 标签: boron ABNORMALITY LI2O-AL2O3-SIO2 system glass ceramics
  • 简介:对数码相机来说.500万像素已经是今天最起码的要求了.而照相手机也不甘落后。夏普第一个在其90GSH手机上加入了300万像素照相头.而现在.诺基亚N80也披挂上阵了.手机拍下的300万像素数码照片非常不错.将它打印成7×5英寸照片时,再也不会像200万像素照片那样出现质量损失了。除了照相之外,N80还能够通过3G网络和Wi-Fi高速上网,内置了MP3播放器和蓝牙,而且支持GSM四频网络,在世界几乎任何地方都能正常工作,惟一要抱怨的就是它的身材有些太敦实了。

  • 标签: 300万像素 MP3播放器 3G网络 照相头 奇数 照相手机
  • 简介:用溶胶-凝胶法制备了系列掺杂(La0.8Ln0.2)2/3Ca1/3MnO3(Ln=La,Ce,Pr,Nd,Sm,Eu)纳米级晶体。对比在La被其它镧系元素部分替代后,引起的A位离子平均半径的改变和磁矩变化对电输运及磁阻性能的影响,实验分析表明,各个样品在同样大小磁场下的磁电阻存在较大的差别,样品的磁电阻随原子序数的增加而明显变大,由镧系收缩引起晶格畸变所产生的本征磁电阻占主导地位,随着外加磁场的增加,不同掺杂样品间的峰值电阻差异被弱化;各掺杂样品间的转变温度差与掺杂离子半径差和磁矩差密切相关,且离子半径的差异对转变温度的改变贡献更大。

  • 标签: 溶胶-凝胶法 纳米晶体 等量掺杂 磁电阻
  • 简介:Eu(TTA)4CsHsNC16H33(TTA:1-(2-Thenoy)-3,3,3-Trifluoracetate)isencapsulatedinSi-MCM41modifiedwithN-(3-Trimethoxysilethyl)ethylenediamine.Theemissionspectrumoftheassemblyshowsonlya5D0→7F2transition.Ascomparedwiththerareearthcomplexitself,thelifetimeoftheassemblybecomeslongeranditsstabilityundertheUVradiationismuchbetter.

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