简介:GaxIn1-xAs1-ySbyalloyshavebeengrownbyatmosphericpressureMOCVDonn-GaSb(Te-doped)substrate.Thesohdcompositionwasdeterminedbyusingelectronmicroprobe.ThealloysofGalnAsSbwithcompositioninmiscibilitygapweresuccessfullygrown.TheopticalpropertiesofGaxIn1-xAs1-ySbylaverswerecharacterizedbythephotoluminescenceandtheinfraredabsorption.Thespectralresponsesofp+-GaInAsSb/p-GaxIn1-xAs1-ySby/n-GaSbdetectorsshowedwavelengthcutoffat2.4μmanddetectivity-D*=5×108cmHz1/2/Watroomtemperature.
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简介:RapidsolidificationofCu-Pbmonotecticalloyshasbeenaccomplishedduringfreefallina3mdroptube.BothmacrosegregatedanduniformlydispersedstructuresareobservedinCu-40wtpctPballoydroplets,whereasdropletsofcompositionCu-64wtpctPbexhibitonlymacrosegregationmorphologies.Themicrostructuresarestronglydependentondropletsize.Thehigherundercoolingtendstofacilitateliquidphaseseparationandresultsinmoreextensivemacrosegregationinsmallerdroplets.ThereexistsapronouncedtendencyforthePb-richliquidtooccupythesurfaceofthedropletsofbothcompositions,resultingfromthequitelowersurfacetensionofthePb-richphaseandcausingaPb-richlayeratthesurfaceofthesolidifieddroplet.ThenucleationofmonotecticcellsintheCu-40wtpctPbdropletswithdispersedstructurespreferentiallyoccursatthedropletsurface.Asinglenucleationeventtakesplacemorefrequentlyasdropletsizeisreduced.
简介:TherearetwotpyesofphasetransformationsinFe-MnandFe-Mn-Sialloyswhenthetemperatureisdecreased,γ(fcc)→ε(hcp)martensitictransformation(MT)andparamagnetic-antiferromagnetictransition(AMT)ofγphase.Fromthethermodynamicpointofview,theformerusuallyappearsinaslightlyhighertemperaturerangethanthelatterbecauseifisgenerallyacceptedthatthemagnetictansitionhasasuppressingeffectonthethermallyinducedεmartensite(Satoetal.,1984.,BogachevandZvigintzeva,1976;Murakamietal.,1987:Yangetal.,1992)GartsteinandRobinkin(1979)eventhoughtthattheγ-εtransformationshouldbeterminatedbelowNeeltemperature(TN)duetothedecreaseoffreeenergyarisingfromtheAMTofγphase.However,someexperimentalresultshaeindicatedtheformationofεphasebelowT(LiandWayman,1994:Fujimori.1966).Inthepresentwert.thebehavorofγ-εtransformationbelowTNwasfurtherinvestigatedbyclectricalresistancemeasurements.
简介:ThisworkstudiesTedopingeffectsonthedirectbandgapphotoluminescence(PL)ofindirectGaxIn1-xPalloys(0.72≤x≤0.74).Thetemperature-dependentPLshowsthattheenergydifferencebetweendirectΓvalleyandindirectXvalleysisreducedduetothebandgapnarrowing(BGN)effect,andthedirectbandtransitiongraduallydominatesthePLspectraastemperatureincreases.CarrierthermalizationhasbeenobservedforTe-dopedGaxIn1-xPsamples,asintegratedPLintensityincreaseswithincreasingtemperaturefrom175to300K.Theactivationenergyforcarrierthermalizationisreducedasdopingconcentrationincreases.BothBGNeffectandcarrierthermalizationcontributetothecarrierinjectionintotheΓvalley.Asaresult,thedirectbandtransitionisenhancedintheTe-dopedindirectGaxIn1-xPalloys.Therefore,thePLintensityoftheGa0.74In0.26Psamplewithactivedopingconcentrationof9×1017cm-3isincreasedbyfivetimescomparedwiththatofanominallyundopedsample.ItisalsofoundthatthePLintensityisdegradedsignificantlywhenthedopingconcentrationisincreasedto5×1018cm-3.Fromcross-sectiontransmissionelectronmicroscopy,nolargedopantclustersorotherextendeddefectswerefoundcontributingtothisdegradation.
简介:在不同温度的非结晶的CuHf合金的结构的因素由使用高温度X光衍射计的redetermined。theshort范围顺序结构而且中等范围的顺序结构在非结晶的CuHfalloys存在,这被发现不仅。合金融化的CuHf的动态粘性被扭力的摆动粘度计测量。脆弱过热CuHf合金融化基于粘性数据被计算。形成CuHf的能力的玻璃是的试验性的结果表演仔细与脆弱有关他们的超级加热融化。在中等范围顺序结构和脆弱之间的关系过热融化也在非结晶的CuHfalloys被建立了。与supercooled液体的脆弱相对照,过热的液体的脆弱答应一条更好的途径到反映形成液体的玻璃的动力学。
简介:Thedevelopmentofthermalanalysistechniquesforevaluationofcastalloymeltqualityanditscurrentapplicationsinthefoundrywerereviewed.Thecharacteristicsofthecurrentthermalanalysistechniqueswereanalyzed.Anewcomprehensivemethodforcoolingcurverecognitionhasbeenproposed.Theevaluationofcastalloymeltqualitywasrealized.
简介:Precipitationresponseofarecentlydevelopedb-typeTi–25Nb–2Mo–4Snalloy(wt%)duringagingwasinvestigatedindetail.Experimentalresultsindicatethatthemetastableωorequilibriumαphasecanformalternativelyevenunderthesameagingcondition,dependingontheconditionpriortotheaging,i.e.,solutiontreatmentorseverecoldrolling.Thisprovides,forthefirsttime,thedirectevidenceforthecompetitionbetweenωandαinagedβ-typeTialloys.Thispeculiaragingresponseisfoundtobecloselyrelatedtohigh-densitydislocationsandgrainboundarieswhichsuppresstheformationofωbutfavortheprecipitationoffineaphase.
简介:ThispaperinvestigatesthesolidificationbehaviouroftheAg—Cueutecticalloymeltundercooledupto100K.ItisrevealedthatlamellareutecticsgrowinadendriticformintheAg-Cueutecticmeltwithundercoolingequaltoorgreaterthan76K.Asundercoolingincreases,theremeltedfractionoftheprimaryeutecticsduringrecalescencerises.Thesevereremeltingandthesubsequentripeningoftheprimaryeutecticdendritesleadtotheformationofanomalouseutectics.
简介:ThehydrogenstoragepropertiesofTi1.2Fe+xCa(x=1%,3%and5%inmassfraction)alloyswasinvestigated.ResultsshowthatthemodifiedalloyscanbeactivatedwithoutanythermaltreatmentatroomtemperatureduetotheadditionofCaandexcessTiinthealloys.HydrogenstoragepropertiesofthesemodifiedalloysvarywithCaamountandreactiontemperature.Inaddition,theinfluencemechanismoftheadditionofCaandexcessiveTiontheactivationbehaviorandhydrogenstoragecapacityofthealloyswasdiscussed.
简介:PhasesandmicrostructuresofthreehighZncontainingAl–Zn–Mg–Cualloyswereinvestigatedbymeansofthermodynamiccalculationmethod,opticamicroscopy(OM),scanningelectronmicroscopy(SEM)energydispersivespectroscopy(EDS),X-raydiffraction(XRD),anddifferentialscanningcalorimetry(DSC)analysis.TheresultsindicatethatsimilardendriticnetworkmorphologiesarefoundinthesethreeAl–Zn–Mg–Cualloys.Theas-cast7056aluminumalloyconsistsofaluminumsolidsolution,coarseAl/Mg(Cu,Zn,Al)2eutecticphases,andfineintermetalliccompoundsg(MgZn2).Bothofas-cast7095and7136aluminumalloysinvolvea(Al)eutecticAl/Mg(Cu,Zn,Al)2,intermetallicg(MgZn2),andh(Al2Cu).Duringhomogenizationat450°C,fineg(MgZn2)candissolveintomatrixabsolutely.Afterhomogenizationat450°Cfor24h,Mg(Cu,Zn,Al)2phasein7136alloytransformsintoS(Al2CuMg)whilenochangeisfoundin7056and7095alloys.ThethermodynamiccalculationcanbeusedtopredictthephasesinhighZncontainingAl–Zn–Mg–Cualloys.
简介:MicrostructureandtextureofTi-Nb-Sibasedalloys,preparedbywaterquenchingfromβ-phasefield,coldrollingandrecrystallizationheattreatmentfollowedbywaterquenching,wereinvestigatedintermsofopticalmicrostructureandanalysisofX-raypolefigureresult.Inas-quenchedsample,relativelyrandomdistributionofpolefigurewasdetectedwithoutshowingaspecifictexturecomponent.Inas-coldrolledsample,however,itisfoundwell-developedseveraltexturecomponentsconsistingofrotatedcube,α-fiberandγ-fibertexturecomponentswhicharefrequentlyobservedinbcc-structuredmetalsandalloyswerefound.Therefore,texturecomponentsdevelopedinthepresentalloysarecloselyrelatedtothedeformationofβ-phaseeventhoughsmallamountofα″phaseco-existinthemicrostructure.Inrecrystallizedsample,α-fibertexturecomponentisweaklydetectedwhiletheothertexturecomponents,rotatedcubeandγ-fibercomponents,appearstoberelativelyunchanged.Noadditionaltexturecomponentsweredetectedbesidesthosetexturecomponentsobservedinthecoldrolledsamples.
简介:W-25Cualloysweremicrowavesinteredina2.45GHzmultimodeapplicator.Thedensification,microstructureandtheirdependenceonsinteringmodeandFeadditionwereinvestigatedindetail.Owingtothevolumetricheatingintrinsicinmicrowaveprocessing,amicrostructurewithlargerWgrainsizeincenterregionswasobservedasagainstlargergrainsizeinedgeregionsforconventionalsintering.Microwavesinteringdemonstratesitsintrinsicadvantagessuchasrapidheatingrate,densificationenhancementandmicrostructuralhomogeneity;butitundesirablypromotesWgraingrowth.Undermicrowavesintering,theroleofFeadditiononcompactconsolidationisnotsosubstantialasunderconventionalsintering.MoreoverFedegradesthemicrostructuralquality,generatingworseuniformityandcoarserWgrains.