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简介：采用表面等离子共振（SPR）生物传感器，分别固定Aβ及其单克隆抗体于传感芯片表面，实时监测Aβ与Cu（Ⅱ）混合前后与Aβ单抗体特异的结合过程，及Cu（Ⅱ）与Aβ亲和结合及解离情况．结果显示：Cu（Ⅱ）影响Aβ与Aβ单抗体的特异结合能力，加入Ca（Ⅱ）后Aβ不能与Aβ单抗体起特异免疫结合反应；Aβ与Cu（Ⅱ）的结合过程为快结合快解离的动力学过程．

简介：WeinvestigatethesurfacestructureandcompositionofaYBa2Cu3Oy(YCO)thinfilmodifiedbyCF4plasmafluorination.Inadditiontotheabsorptionofhydrocarbons,chemicalreactionsoftheYBCOsurfacetakeplaceduringCF4plasmatreatment.Variousx-rayphotoelectronspectroscopicdataarereportedanddiscussed.Theexistenceofathinbarrierisconfirmed,whichhomogeneouslycoverstheedgeofthebaseYBCOfilminourinterfaceengineeringJosephsonjunction.MeasurementsofAugerelectronspectroscopicdataandtheresistanceversustemperatureindicatethatthebarrierisacontrollable-insulatinglayer.

简介：ReactionsofCuSCNwithtetramethylthiuramdisulfideinCH3CNinthepresenceofstyreneandN,N,N',N',N'-pentamethyldiethylenetriaminegaverisetoanewcopper(Ⅰ)complexofN,N'-dimethyldithio-cabamate{[Cu(S2CNMe2)]2}n.ThetitlecompoundcrystallizedinthetriclinicP-1spacegroupwithlatticeparametersα=0.7610(4)nm,b=0.8911(4)nm,c=0.9268(5)nm,α=68.66(1)°,β=83.88(2)°,γ=79.31(2)°,V=0.5748(5)nm^3,Z=2.Thecompoundhasaunique1DchainstructurecomposedofCuSCSCuSCSeight-memberedringsandapairofCu-Sbonds,thestructureofwhichhasbeendeterminedbysingle-crystalX-raycrystallography.Theisolationofthiscompoundmayprovidesomehelpfulinformationforthecauseoftheinductionperiodsofthereverseatomtransferradicalpolymerization.

简介：N复杂的Cu2+的相互作用，有DNA的N二度(2-aminoethyl)-2,6-pyridinedicarboxamide(BAP)被agarose胶化电气泳动分析学习。结果显示BAP-Cu2+建筑群能以生理的状况支持supercoiledDNA的phosphodiester债券的劈开，哪个是3.2畤瑣潩?牯杩湩漠?敧杯慲桰捩漠楲楧?景眠湩獥吗？？

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简介：Threenewcomplexes[Ni(H2L)][Fe(CN)5(NO)]2·6H2O(1),[Ni(H2L)][Fe(CN)5(NO)]2·4H2O(2)and[Cu(H2L)][Fe-(CN)5(NO)]2·4H2O(3)(L=3,10-bis(2-aminoethyl)-1,3,5,8,10,12-hexaazacyotetradecane)arepreparedandcharacter-izedbyIR,elementalanalysesandsingle-crystalX-rayanaly-ses,indicatingthattheyarethefirstexamplesoftrinurlearni-troprnsside-bridgedMFe2(M=CuandHi)complexes.Inthethreecomplexes,thecentralmetalatoms(M)areallsix-coor-dinatedbythenitrogenatomsfromthemacroeyclicligandandtwocyano-bridgesatthetrans-positionstoformdistortedocta-hedralconfigurations.TheaxialN—M—NlinkageisnearlyverticaltotheequatorialplanedefinedbyfourcoordinatingNatomsofmcroeyclicligand.TheC≡N—Nibondangleof172.6°incompleox1isapparentlylargerthanthoseincom-plexes2and3(152.57°and136.37°,respectively).Thethreecomplexesareallconnectedbyhydrogenbondsinto3Dnet-works.Thisstudyshowsthatthecyano-bridgedtrinuclearspeciescouldbegeneratedviathecontrolofthechargeofthebuildingblocks.

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简介：Adoubleactivecentersystem,namelySalen-Cu（Ⅱ）@MIL-101（Cr）,wassuccessfullysynthesizedviathe“shipinabottle”approach,whichactedasabifunctionalmaterialforbothcaptureandconversionofCO2inasingleprocess.Forthefirsttime,Salen-Cu（Ⅱ）@MIL-101（Cr）catalystwasdevelopedforthesynthesisofpropylenecarbonatefromCO2andpropyleneoxideunderroomtemperatureandambientpressurewithayieldof87.8%over60h.Furthermore,thereactionmechanismwasalsodiscussed.

简介：利用室温液相还原、晶种生长的方法,成功的制备了大小形貌均一、性能稳定且具有磁性的Fe3O4@Cu2O复合纳米粒子,并且对制备的Fe3O4@Cu2O纳米粒子进行了光催化性能的研究.在以紫外光为光源的照射下,合成的Fe3O4@Cu2O纳米粒子对有机染料甲基蓝溶液起到很好的降解作用.更重要的是,在外加磁场的作用下,Fe3O4@Cu2O纳米粒子容易回收,具有良好的可循环利用性能.

简介：ThecompressionbehaviourofPd39Ni10Cu30P21bulkmetallicglassisivestigatedatroomtemperatureupto23.5GPausinginsituhighpressureenergydispersivex-raydiffractionwithasynchrotronradiationsource.Pressureinducedstrucuralrelaxationofthebulkmetallicglassisexhibitedwithinthepressurerange.Itisfoundthatbelowabout5GPa,theexistenceofexcessfreevolumecontributestorapidstructuralrelaxation,whichgivesrisetorapidvolumeticchange.Underhigherpressure,furtherrelaxationresultsinstructuralstiffness.

简介：Thenatureofresistivetransitionofhigh-qualitycrystallinethinfilmsofYBa2Cu3O7-δhasbeenstudiedundermagneticfields(H)appliedalongthecdirectionoverawiderangeofdopedholes,p,intheCuO2planes.Thefield-andtemperature-dependentin-planeresistivity,ρab(T,H),hasbeenanalyzedwithinthethermallyassistedflux-flow(TAFF)formalism.Thefluxactivationenergy,U(T,H),hasbeenextractedfromthisanalysis.Thelow-Tpartoftheρab(T,H)datacanbedescribedbyanactivationenergyhavingthefunctionalformofU(T,H)=(1-t)m(H-0/H)β,wheret=T/Tc(reducedtemperature),andH0isafieldscalethatprimarilydeterminesthemagnitudeofU(T,H).Thetemperatureexponent,m,showsasystematicvariationwithp,whereasthefieldexponent,β,isinsensitivetothepvaluesandisclosetounity.TheH0,ontheotherhand,changesrapidlyaspisvaried.U(T,H)islinkedtothepinningpotentialandconsequentlyonthesuperconductingcondensationenergy.Sincethenormalstatepseudogapdirectlyaffectssuperconductingcondensationenergy,aclearcorrespondencebetweenH0andthePGenergyscale,εg,isfound.Possibleimplicationsoftheseresultsarediscussed.

简介：AseriesofmesoporousCu-Mn-Al2O3(CMA)materialswassynthesizedatmoderatetemperatureandtheirstructureswerecharacterizedbyXRD,N2physicaladsorptionandTPRtechniques.Itwasfoundthatusingmetalcomplexion[Cu(NH3)42+-Mn(NH3)62+]asrawmaterialsiseasiertoformgood-structuremesoporousCu-Mn-Al2O3materialsthanusingitsnitratesalt[Cu(NO3)2-Mn(NO3)2].TheTPRtestsresultsindicatethatCuOandMnOxwerehomogeneouslydispersedinthemesoporousmaterials.TheircatalyticapplicationtopreferentialcatalyticoxidationofCOinahydrogen-richstreamwasstudied.TheactivityvariesintheorderofCMA(1:1,molarratio)>CMA(1:2)>CMA(2:1)>CMA(CP)>CMA(1:0)≈CMA(0:1).TheCMA(1:0)andCMA(0:1)haveloweractivitycomparedtoothersamples,implyingthatthereexistedcoordinationeffectbetweenCu-Mninthesamples.TheselectivityvariedintheorderofCMA(0:1)≥CMA(1:2)>CMA(1:1)>CMA(2:1)>CMA(1:0)athighertemperature(≥120°C),indicatingthatincreasingtheCucontentenhancedtheconversionofH2.ThesampleCMA(CP)madebycoprecipitationmethodhasalowerCOoxidationactivityandselectivitythanitscounter-partsofmesoporousCu-Mn-Al2O3materials[CMA(1:2)],thisattributedtothelowersurfaceareaoftheformerandpoorinteractionofCuOwithMnOx.

简介：利用电介质的平均能带模型计算了PrBa2Cu3O7的化学键参数，得到Cu(1)-O键的人价性为0．41，Cu(2)－O键的平均共价性为0．28，应用由共价性和要化率定义的化学环境因子计算了^57Fe在PrBa2Cu3O7中的Mossbauer同质异能位移，确定了^57Fe在PrBa2Cu3O7中的价态和占位情况。

简介：Metalion-imprintedlycrosslinkedchitosanresin1andresin2werepreparedbytheuseofCu^2+andNi^2+astemplateionsandglutaraldehydeascrosslinkingagent,respectively,ThroughinvestigationontheadsorptioncapactiesandbindingconstantsforCu^2+,Ni^2+andCo^2+ionsonchitosanresins,resin1andresin2exhibittheadsorptionselectivityforthemixturesolutionof1L1Cu^2+andNi^2+ions.Theadsorptionselectivityofmetalion-imprintedresinsfortheirtemplateionsinmuchhigherthanthatofuncrosslinkedchitosanresin.

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简介：ACupro-8-thioquinolinecoordinationpolymer,[Cu^I(C9H6NS)]n,wassynthesizedbymethano-thermalreactionofCuCland8,8′-dithiodiquinoline(dtdq)inamolarratioof2:1at160℃for7d.X-Raysinglecrystalstructuredeterminationrevealedtheformationofaone-dimensionalstructurebelongingtomonocliniccrystalsystem,spacegroupP21/cwithcellparametersa=0.8043(1)nm,b=1.8949(3)nm,c=1.1048(1)nm,β=110.109(4)°,V=1.5810(4)nm^3andZ=4,Thecrystalwasfoundtobestableuptoapproximately300℃bythermalanalysisandhaveanenergygap(Eg)of2.0eVexhibitedbyUV-Vis-NIRreflectancespectrum.

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简介：YBa2Cu3Ox(YBCO)thinfilmsgrownondifferentsubstrateswithand/orwithoutEu2CuO4(ECO)bufferlayerwereinvestigatedbyX-raywideanglediffraction,reflection,diffusescatteringandtopography.TheresultsshowthatfortheyttriastabilizedZrO2(YSZ)substrate,thepresenceofanECObufferlayerimprovesthecrystallinequalityoftheYBCOfilm,whileanegativeeffectisobservedfortheSrTiO3(STO)substrate.ThelateralcorrelationlengthforasamplegrownonaYSZsubstratewithECObufferLayerismuchgreaterthangrownonanSTOsubetrate.TheSTOsubstrateusedhasmosaicstructure.2001ElsevierScienceB.V.Allrightsreserved.