简介:Anewmethodforfabricatingorderedporoussiliconisreported.Atwo-dimensionalsilicananospherearrayisusedasatemplatewithahydrofluoricacid-hydrogenperoxidesolutionforetchingthenanospheres.Theinitialdiameteranddistributionoftheholesintheresultingporoussiliconlayeraredeterminedbythesizeanddistributionofthesilicananospheres.Thecorrosiontimecanbeusedtocontrolthedepthsoftheholes.ItisfoundthatthepresenceofaSiO_2layer,formedbytheoxidationoftheroughinternalsurfaceofthehole,istheprimaryreasonallowingthecorrosiontoproceed.Ultravioletreflectionandthermalconductivitymeasurementsshowthatthediameteranddistributionoftheholeshaveagreatinfluenceonpropertiesoftheporoussilicon.
简介:我们揭示并且解释thermopowerS/T的可伸缩的行为展出了由典型重费米子(HF)金属YbRh2在在温度T的磁场B的申请下面的Si2。我们证明一样的可伸缩被不同HF混合物例如表明?-YbAlB4和强烈相关的分层的钴氧化物[BiBa0.66K0.36O2]CoO2。用YbRh2是的Si2一个例子,,我们证明S/T的可伸缩的行为在antiferromagnetic阶段转变被违背剩余抵抗力0和状态的密度,N,经验在阶段转变跳,引起thermopower做二跳并且改变它的符号。我们的说明基于深刻地影响0和N的单个粒子的光谱变平。描绘S/T行为的主要特征,我们构造TBYbRh2Si2。我们为HF混合物的计算S/T在对试验性的事实的好同意并且支持我们的观察。
简介:Twofamiliesofcatalysts,basedonPdnanoparticlessupportedonceramicasymmetrictubularaluminamembranes,arestudiesinthedirectsynthesisofH_2O_2.TheyarepreparedbydepositingPdintwoways:(i)reductionwithN_2H_4inanultrasonicbathand(ii)byimpregnation-deposition.Thefirstpreparationleadstolargerparticles,withaveragesizeofaround11nm,whilethesecondpreparationleadstosmallerparticles,withaveragesizearound4nm.Thecatalyticmembranesweretestedasprepared,afterthermaltreatmentinairandafterfurtherpre-reductionwithH_2inmild(100℃)conditions.SampleswerecharacterizedbyTEM,CO-chemisorptionmonitoredbyDRIFTSmethodandTPR,whilecatalytictestshavebeenperformedinasemi-batchrecirculationmembranereactor.Experimentalcatalyticresultswereanalysedusingtwokineticsmodelstoderivethereactionconstantsfortheparallelandconsecutivereactionsofthekineticnetwork.SmallerparticlesofPdshowlowerselectivityduetothehigherrateofparallelcombustion,evenifthebetterdispersionofPdandthushighermetalsurfaceareainthesampleleadtoaproductivityinH_2O_2similarorevenhigherthanthesamplewiththelargerPdparticles.IndependentlyonthepresenceofsmallerorlargerPdnanoparticles,anoxidationtreatmentleadstoasignificantenhancementintheproductivity,althoughthecatalystprogressivelyreducesduringthecatalyticprocess.Theinhibitionoftheparallelcombustionreaction(towater)inducedfromthecalcinationtreatmentremainsafterthein-situreductionoftheoxidizedPdspeciesformedduringthepre-treatment.Thisislikelyduetotheeliminationofdefectsiteswhichdissociativelyactivateoxygen,andtentativelyattributedtoPdsitesabletogivethree-andfour-foldcoordinationofCO.
简介:Aseriesofoxygenpermeabledual-phasecompositeoxides60wt%Ce0.8Gd0.2O2-δ-40wt%LnBaCo2O5+δ(CGO-LBCO,Ln=La,Pr,Nd,Sm,GdandY)weresynthesizedthroughasol-gelrouteandeffectsoftheLn3+cationsontheirphasestructure,oxygenpermeabilityandchemicalstabilityagainstCO2wereinvestigatedsystemicallybyXRD,SEM,TG-DSCandoxygenpermeationexperiments.XRDpatternsrevealthatthelargerLn3+cations(La3+,Pr3+andNd3+)successfullystabilizedthedouble-layeredperovskitestructureofsinteredLBCO,whilethesmallerones(Sm3+,Gd3+,andY3+)resultedinthepartialdecompositionofLBCOwithsomeimpuritiesformed.CGO-PBCOyieldsthehighestoxygenpermeationflux,reaching2.8×10-7mols-1cm-2at925?Cwith1mmthicknessunderair/Hegradient.TheTG-DSCprofilesin20mol%CO2/N2andoxygenpermeabilityexperimentswithCO2assweepgasshowthatCGO-YBCOdemonstratesthebestchemicalstabilityagainstCO2,possiblyduetoitsminimumbasicity.ThestableoxygenpermeationfluxofCGO-YBCOunderCO2atmosphererevealsitspotentialapplicationintheoxy-fuelcombustionrouteforCO2capture.
简介:HL-2AisthefirsttokamakwithdivertorinChina.TheobjectivesofHL-2Aaretoproducemoreadaptabledivertorconfigurationstostudyenergyexhaustandimpuritycontrol,andtostudyenhancedcoreplasmaconfinementbyprofilecontrolandmoderateplasmashaping.HL-2Ahaswelloptimizedoperationalflexibilityandexcellentaccessi-bilityforthediagnosticsystemstofacilitatevariousplasmaexperiments.
简介:CO2methanationhasbeenahottopicbecauseofitsimportantapplicationinthespacecraftandpotentialutilizationofcarbondioxide.Nickelcatalystisactiveforthisreaction.However,itsactivitystillneedstobeimproved.Dielectricbarrierdischarge(DBD)plasma,initiatedatambientconditionandoperatedat~150°C,hasbeenemployedinthisworkfordecompositionofnickelprecursortoprepareNi/MgAl2O4.Theplasmadecompositionresultsinhighdispersion,uniquestructure,enhancedreducibilityofNiparticlesandpromotedcatalyst-supportinteraction.AnimprovedactivityofCO2methanationwithahigheryieldofmethanehasbeenachievedovertheplasmadecomposedcatalyst,comparedtothecatalystpreparedthermally.Forexample,themethaneyieldoftheplasmapreparedcatalystis71.8%at300°Cbutitis62.9%overthethermalpreparedcatalyst.ThecatalystcharacterizationconfirmedthatCO2methanationovertheDBDplasmapreparedcatalystfollowspathwayofCOmethanation.
简介:IntheinterlayerexpansionofthelayeredzeoliteprecursorCOK-5,aSn,salt,bis(2,4-pentanedionate)-dichlorotin[Sn(acac)2Cl2],insteadofasilylatingagentwasusedtolinkthelayersat180°C.Theobtainedmaterial,whichisdesignedasSn-COE-5,showsashiftofthefirstXRDreflection,whichisverysimilartothatofCOK-5interlayerexpandedwithdichlorodimethylsilane(DCDMS),indicatinganincreaseininterlayerdistance.X-raydiffraction(XRD),N2sorptionisotherms,inductivelycoupledplasma(ICP),andX-rayphotoelectronspectroscopy(XPS)supporttheincorporationofisolatedSnsitesinthesample.Intheconversionofglucosetolevulinicacid,Sn-COE-5exhibitsmuchhigheractivitythanCOK-5,whichisduetothepresenceofLewisacidicsitesintheSn-COE-5.
简介:Weproposeandexperimentallydemonstratea2×2thermo-optic(TO)crossbarswitchimplementedbydualphotoniccrystalnanobeam(PCN)cavitieswithinasilicon-on-insulator(SOI)platform.Bythermallytuningtherefractiveindexofsilicon,theresonancewavelengthofthePCNcavitiescanbered-shifted.WiththehelpoftheultrasmallmodevolumesofthePCNcavities,only~0.16mWpowerisneededtochangetheswitchingstate.Withaspectralpassbandof0.09nmatthe1583.75nmoperationwavelength,theinsertionloss(IL)andcrosstalk(CT)performancesweremeasuredasIL(bar)=-0.2dB,CT(bar)=-15dB,IL(cross)=-1.5dB,andCT(cross)=-15dB.Furthermore,thethermaltuningefficiencyofthefabricateddeviceisashighas1.23nm/mW.
简介:Lifetimemeasurementsoflow-lyingexcitedstatesin87Zrand87Nbhavebeenperformedviaandcoincidences.The124MeV32SbeamwasdeliveredfromtheSector-FocusingCyclotron(SFC)oftheHeavyIonR-esearchFacilityinLanzhou(HIRFL).Theparentnuclei87Nband87Mowereproducedbytherespectivereactions58Ni(32S,3p)and58Ni(32S,2p1n),atabeamenergy100MeVthroughthe8mAldegrader.
简介:InthispaperweusedMOF-5andCu3(BTC)2toseparateCO2/CH4andCH4/N2mixturesunderdynamicconditions.Bothmaterialsweresynthesizedandpelletized,thusallowingforameaningfulcharacterizationinviewofprocessscale-up.ThematerialswerecharacterizedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Byperformingbreakthroughexperiments,wefoundthatCu3(BTC)2separatedCO2/CH4slightlybetterthanMOF-5.BecausethecrystalstructureofCu3(BTC)2includesunsaturatedaccessiblemetalsitesformedviadehydration,itpredominantlyinteractedwithCO2moleculesandmoreeasilycapturedthem.Conversely,MOF-5withasuitableporesizeseparatedCH4/N2moreefficientlyinourbreakthroughtest.
简介:Radiotherapyisacommontreatmentmodalityforheadandneckcancers,nasopharyngealcancers,primarybraintumorsandbrainmetastases.Alargenumberofpatientsintheworldwithprimaryormetastaticbraintumorswillrequirelargevolumeorwholebrainirradiationeveryyear.However,therapeuticirradiationnotonlykillstumorcells,butalsoinjuresnormalbraintissue,whichiscommonlyassociatedwithsignificantfunctionalmorbidityanddecreasedqualityoflifeinpatientstreatedwithbrainradiotherapy[1].
简介:用微波高温固相法合成了Er^3+单掺Lu2O3,Li^+与Er^3+共掺Lu2O3及Li^+,Zn^2+,Mg^2+掺杂Lu2O3∶Er^3+的荧光粉。实验表明金属离子Li^+、Zn^2+、Mg^2+、Er^3+掺杂Lu2O3,不影响Lu2O3的立方晶相。扫描电子显微镜测量表明,Li^+掺杂可以有效改善粉体的分散性和形貌,Li^+,Zn^2+,Mg^2+共掺杂获得的粉体颗粒分布更加均匀,粒径范围为80~100nm。379nm激发下,Li^+与Er^3+共掺样品发光较单掺Er^3+样品在565nm处的发光增强了4.5倍,而Li^+、Zn^2+、Mg^2+与Er^3+共掺样品较其发光增强5.3倍。980nm激发下,Li^+与Er^3+共掺样品,Li^+、Zn^2+、Mg^2+与Er^3+共掺样品的发光分别比单掺Er^3+样品在565nm处发光增强23倍与39倍,在662nm处发光强度分别增强20倍与43倍。379nm激发下,较单掺Er3+的样品,掺杂Li^+的样品和Li^+,Zn^2+,Mg^2+和Er^3+共掺的样品荧光寿命均有所增加,而Zn^2+、Er^3+共掺及Mg^2+、Er^3+共掺样品的荧光寿命则有所缩短。
简介:Nuclearmassisoneofthefundamentalquantityofatomicnucleus.Thetotalbindingenergyofanucleusderivedfromtherelatedmassvaluesreflectsalltheinteractionsamongtheconstitutingnucleons.Massesofshort-livedA=2Z+3nucleiof112SnprojectilefragmentshavebeenmeasuredattheexperimentalcoolerstorageringCSRe,employingtheIsochronousmassspectrometry(IMS).TheexperimentwasconductedattheHeavyIonResearchFacilityinLanzhouatthebeginningof2016.Theprimarybeamof112Sn35+wasaccumulatedinthesynchrotronCSRmandacceleratedto467.91MeV/u.Secondarybeamwereproducedbyimpingingthehighintensity112Sn35+beamontoa10mmberylliumtargetwhichwaslocatedattheentranceoftheradioactivebeamlineRIBLL2.Theprojectilefragmentsof112Snemergedfromthetargetwerethentransmitted,separatedinflightthroughRIBLL2andfinallyinjectedintoCSRe.
简介:Weperformfirst-principlecalculationsforthestudyoftheorthorhombicRb2Cd2(SO4)3structure.Electronicenergybands,totalandpartialdensitiesofstatesarereportedandanalysed.Itisfoundthatoxygenatomic2pelectronsstronglyhybridizewithRb/orCd4dandS2pstates,resultingintwo-typeionicgroupswithweakcouplings.Itisshownthatmacroscopicdomainwallsoriginatefromsuchweak-couplingionicgroups,arisingatthecellboundaries.Theasymmetriccationbonds(Rb-OandCd-O)andthesubsequentrotationsoftheS04tetrahedracanleadtothedrivingforceoftheferroelectricbehaviour.Thepredictedpyroelectriccurrenteffectsareobservedexperimentallyintheferroelectricphase.