简介:Inthiswork,thewettability,agingandshearpropertiesofanewtypeoflead-freesolderpasteSn-07Ag-05Cu+BiNi(SACBN07)wasinvestigatedbyconductingaseriesofcomparisonexperimentswithSAC305andSAC0307solderpaste.TheresultsshowthatwettabilityofSACBN07isalmostequaltoSAC305,andbetterthanthatofSAC0307solderpaste.Thethicknessofintermetalliccompound(IMC)layerinSACBN07/Cuislowerthanthatofothertwotypesofsolderjointafteraging.AndCu_3SnlayerofSACBN07/CuisthinnerthanthatofSAC305andSAC0307.Inaddition,theSACBN07solderjointsperformthebestshearstrengthamongthesethreetypesofsolderpastes.
简介:Cesiumcontentintheseawateris3.0910-4mg·L-1,andammonium-typemordenitewasusedtoexchangecesiumfromcesiumsource.K-typemordenitewasobtainedbyhydrothermalsynthesismethod.Afterammonium-modified,ionexchangepropertiessuchassaturatedionexchangecapacitiesandselectivitycoefficientsforalkalimetalionsweredetermined.Atthesametime,ionexchangeisothermalcurvesofammonium-typemordeniteforCs+andNH4+weredeterminedat25°C.Pitzerelectrolytesolutiontheorywasusedtoworkoutactivitycoefficientsofthesystem,andtheKiellanddiagramoftheionexchangesystemwasobtained.Thecalculatedequilibriumconstant(Ka)andionfreeenthalpy(DG0)ofmordeniteforCs+andNH4+are1.455and-930.3J·mol-1,respectively,indicatingthationexchangeprocessofammonium-typemordeniteforcesiumisaspontaneousprocess.
简介:ProblemsaboutsurfacemountingprocessforfinepitchdevicesandreasonsonsolderbridgingofLtypeleaddevicesweldedaredepicted.Bridgingmechanismandinfluencefactorsareanalyzedwithtwo-dimensionalgeometricmodel.Basedonthis,high-densitysurfacemounttechnology(SMT)forfinepitchLtypeleaddevicesheatedbyscan-ninglaserisraised.SurfacemountprocessforQFP208onprintedcircuitboard(PCB)isstudied.Theresultsoftestsarethatitisquitepossibletosolvethesolderbridgingofsurfacemountingforpitchdeviceswithscanninglaser-heat-ingmethod.
简介:Precipitationresponseofarecentlydevelopedb-typeTi–25Nb–2Mo–4Snalloy(wt%)duringagingwasinvestigatedindetail.Experimentalresultsindicatethatthemetastableωorequilibriumαphasecanformalternativelyevenunderthesameagingcondition,dependingontheconditionpriortotheaging,i.e.,solutiontreatmentorseverecoldrolling.Thisprovides,forthefirsttime,thedirectevidenceforthecompetitionbetweenωandαinagedβ-typeTialloys.Thispeculiaragingresponseisfoundtobecloselyrelatedtohigh-densitydislocationsandgrainboundarieswhichsuppresstheformationofωbutfavortheprecipitationoffineaphase.
简介:NanocrystallineMg2Ni-typealloyswithnominalcompositionsofMg20Ni10–xCux(x=0,1,2,3,4,massfraction,%)weresynthesizedbyrapidquenchingtechnique.Themicrostructuresoftheas-castandquenchedalloyswerecharacterizedbyXRD,SEMandHRTEM.Theelectrochemicalhydrogenstorageperformancesweretestedbyanautomaticgalvanostaticsystem.ThehydridinganddehydridingkineticsofthealloysweremeasuredusinganautomaticallycontrolledSievertsapparatus.Theresultsshowthatalltheas-quenchedalloysholdthetypicalnanocrystallinestructureandtherapidquenchingdoesnotchangethemajorphaseMg2Ni.Therapidquenchingsignificantlyimprovestheelectrochemicalhydrogenstoragecapacityofthealloys,whereasitslightlyimpairsthecyclingstabilityofthealloys.Additionally,thehydrogenabsorptionanddesorptioncapacitiesofthealloyssignificantlyincreasewithrisingquenchingrate.
简介:Theeffectsoflow-CoAB5typehydrogenstoragealloyspreparedbyquenchingandannealingontheperformancesofMH-Nibatterieswereinvestigated,andthecharacteristicsofthelow-CoAB5typehydrogenstoragealloyswerecomparedwiththoseofthehigh-CoAB5typehydrogenstoragealloyaswell.Theresultsshowedthatthefasterthecoolingofthelow-Cohydrogenstoragealloyis,thebetterhomogeneityofthechemicalcompositionforthealloyandthelongercyclelifeofthebatteryare,buttheelectrochemicaldischargecapacityandhigh-ratedischargeabilityarereduced.Thehigh-ratedischargeabilityandchargeretentionofMH-Nibatteriesfortheconventionalas-castannealedlow-Cohydrogenstoragealloyweresuperiortothosefortherapidlyquenchedlow-Cohydrogenstoragealloyandthehigh-Cohydrogenstoragealloy,butalittleinferiorinthecyclelife.
简介:InordertoimprovetheelectrochemicalcyclestabilityofLa-Mg-Nisystem(PuNi3-type)hydrogenstoragealloy,NiinthealloyswaspartiallysubstitutedbyM(M=Cu,Al,Mn).AnewLa-Mg-NisystemelectrodealloysLa0.7Mg0.3Ni2.55-xCo0.45Mx(M=Cu,Al,Mn;x=0,0.1)werepreparedbycastingandrapidquenching.Theeffectsofelementsubstitutionandrapidquenchingonthemicrostructuresandelectrochemicalperformancesofthealloyswereinvestigated.TheresultsbyXRD,SEMandTEMshowthatthealloyshaveamultiphasestructure,includingthe(La,Mg)Ni3phase,theLaNi5phaseandtheLaNi2phase.Therapidquenchingandelementsubstitutionhaveanimperceptibleinfluenceonthephasecompositionsofthealloys,butbothchangethephaseabundanceofthealloys.Therapidquenchingsignificantlyimprovesthecompositionhomogeneityofthealloysandmarkedlydecreasesthegrainsizeofthealloys.TheCusubstitutionpromotestheformationofanamorphousphaseintheas-quenchedalloy,andareversalresultbytheAlsubstitution.Theelectrochemicalmeasurementindicatesthattheelementsubstitutiondecreasesthedischargecapacityofthealloys,whereasitobviouslyimprovesthecyclestabilityofthealloys.ThepositiveinfluenceofelementsubstitutiononthecyclelifeofthealloysisinsequenceAl>Cu>Mn,andnegativeinfluenceonthedischargecapacityisinsequenceAl>Mn>Cu.Therapidquenchingsignificantlyenhancesthecyclestabilityofthealloys,butitleadstoadifferentextentdecreaseofthedischargecapacityofthealloys.