学科分类
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16 个结果
  • 简介:Thetreatmentoftheindustrialwastewater,inwhichtheconcentrationoftriethylamine(TEN)andCODcrwasaround3450mg/Land22400mg/Lrespectively,wasstudiedbyadsorptionofmacroporousresins,ResultsdemonstratethatthepolymericadsorbentCHA-111hasexcellenteffectontheadsorptionanddesorptionofTEN.TheconcentrationofTENintheeffluentislessthan30mg/L,andtheremovalefficiencyofTENandtotalCODcrexceed99%and95%respectively.TheaccumulationandresourcereuseofTENcanberealizedinthisprocess.

  • 标签: 工业废水处理 三乙胺 聚合吸附剂
  • 简介:AmmoniumcanchangethetypeofnaturalclinoptilolitefromJinyunofZhejiangProvinceofChina.Thecharacterofexchangeandselectivityofammoniumtypeclinoptilolitetothealkaliandalkaline-earthmetalwereinvestigated,theheatresistanceandnitricacid-resistanceofnaturalclinoptilolitewerediscussed.AlltypesofclinoptilolitewereresearchedbymeansofX-ray,IRspectroscopy,DTAanalyses.Theionexchangewasexperimentedbycolumnoperation,indicatingthatthevalidamountofexchangecapacityofNH4^+typeclinoptilotiesismorethan25mg/g.

  • 标签: 离子交换 天然倾斜发光沸石 钾盐
  • 简介:Systematicstudiesonthetreatmentandreuseoftheacidindustrialwatewatercontainingsodium2-Naphthylsulfonate(β-salt)from2-NaphthanolproductionprocessbyND-910resin(madebyself)isreportedinthispaper.Undertheoperationconditionsofinitialβ-saltconcentrationof10000-25000mg/LandinitialCODCrof20000-40000mg/L,theremovalratesofSodium2-NaphthylsulfonateandCODCrareover95%andover89%,respectively.Theeffluentcanbedischargeddirectlyafterbiologicaldegradation.TheworkingsorptioncapacityofND-910Resinforβ-saltisover230g/kg.Analkali-waterwashprocedureisutilizedtoregenerateresinandthereclaimingrateofβ-saltisover98%.

  • 标签: 2-萘并吡咯生产 废水处理 废水再用
  • 简介:Inthispaper,thetwoeffluentsfromPBA(3-phenoxy-benzaldehyde)productionprocessweretreatedbypolymericadsorbentCHA-111.PBAorPBC(3-phenoxy-benzoicacid)wasrecoveredfromthewastewaterintheprocessofneutralization.Asasecondarytreatmentmethod,adsorptionwithCHA-111showedbetterefficiencythanphotocatolyticdecompositionandsolventextraction.Theoptimaltechnologicalparameterswere:adsorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:2.0BV/hr(bedvolumeperhour),roomtemperature;desorption:currentvelocity:1.0BV/hr,80℃,8%sodiumhydroxideaqueoussolutions.Inconclusion,99.9%CODintheneutralizingwastewaterand98.4%CODinthehydrolysiswastewaterareremovedsuccessfully.

  • 标签: 聚合吸附剂 3-苯氧基苯甲醛 废水处理
  • 简介:Wastewaterfromproductionprocessof2,3-acidwastreatedbyadsorptionusingmacroporousresinNDA-708.Afteronlyone-steptreatmentbyresinadsorption,removalefficiencyofthreekindsofnaphthalenechemicalswasabove99%;removaleficiencyofCODcrwasabove96%.Underproperoperatingcondition,desorptionefficiencywasaround100%.Therunningrecordsoftheindustrialfacilityshowedthatthenaphthlenechemicalsindesorptioneffluentcouldbereusedwithoutobviousinfluenceonthequalityoftheproduct.

  • 标签: 2 3-酸 生产过程 废水处理
  • 简介:ThewastewaterfromnaphtholAs-EproductionprocesswastreatedwithmacroporouspolymericadsorbentNDA-222.NaphtholAs-Eand2,3-acidinthewastewatercouldberemovedcompletelyandtheTotalOrganicCarbon(TOC)ofthewastewaterwasdecreasedmorethan98%from1655mg/Ltolessthan30mg/L.TheadsorbatescouldbedesorbedcompletelywithNaOHaqueoussolution.

  • 标签: 废水处理 资源 再利用
  • 简介:Polyethylenimine-polyL-lysinePEI-PLL共聚物经由PEI开始的L离氨酸N-carboxyanhydrideLysZ-NCA的戒指洞聚合被综合。有siRNA的PEI-PLL的complexation被粒子尺寸和希腊语的第六个字母潜力大小学习。流动cytometric分析和共焦的成像显示出它的优秀细胞内部的trafficking能力。PEI-PLL在vitro比商业PEI-25k显示了更高的基因silencing效率和更低的cytotoxicity。在antitumor学习,PEI-PLL进一步与siVEGF被相结合并且显然为CT26肿瘤模型的处理显示出肿瘤抑制效果。因此,PEI-PLL是在vivo的进一步的antitumor处理的一个有希望的siRNA搬运人候选人。

  • 标签: L-赖氨酸 SIRNA 聚乙烯亚胺 肿瘤治疗 载体 酸改性
  • 简介:ThetreatmentofsalicylicacidmanufacturingwastewaterbyNDA-100resinwasinvestigated.ThesorptionintensityofphenolwasfoundtobestronglydependentonpHoftheaqueousphase.EquilibriumadsorptiondatafittobothLangmuirandFreundlichmodels.ThecolumnadsorptionshowedthatthisprocesswassuitableforthetreatmentofsalicylicacidmanufacturingwastewaterAbout99.9%CODcrremovalwasobtainedundertheoptimaloperatingconditions.Theresincouldbecompletelyregeneratedwith1BV8%(w/w)NaOH+2BVH2O,therecoveryof98.9%ofthesubstancewasreached.Thisprocessmakesitpossibletorecoverthevaluablematerialfromthewastewaterandtoimprovetheeffluentwaterquality.

  • 标签: 水杨酸 制造业 废水处理 高交联聚合吸附剂(NDA-100)
  • 简介:ThetreatmentofsorbicacidmanufacturingwastewaterbyNDA-150resinwasinvestigated.Theexperimentsshowthatthisprocessissuitableforthetreatmentofsorbicacidmanufacturingwastewater.About98%sorbicacidand50%CODcrwereremovedunderoptimaloperatingconditions,and70%ofsorbicacidinsorbicacidmanufacturingwastewaterwasreclaimed.Thisprocessmakesitpossibletorecovervaluablematerialsfromthewastewaterandtoimprovethequalityofeffluentwater.

  • 标签: 超交联聚合吸附剂 废水处理 山梨酸 生产工艺 NDA-150树脂
  • 简介:Theeffluentfromphenylaceticacid(PhCH2COOH)productionprocesscanbetreatedwithNDA-999macroporouspolymericadsorbentwithabout100%remopvalefficiencyofPhCH2COOH,benzylalcohol(PhCH2OH)andbenzaldehyde(PhCOHO)aswellasthedecreaseinTotalOrganicCarbon(TOC)from4691mg/lto<300mg/L.3.7kgphCH2COOHand120kgNaClwillberecoveredfromperm^3wastewaterandtheadsorbentcanbereusedafterbeingregeneratedbyNaOHaqueoussolutionandmethanol.Goodeconomic,socialandenvironmentalresultscanbeachievedwiththismethod.

  • 标签: 苯乙酸 聚合吸收剂 废水处理
  • 简介:ThePVCservesofmacroporoussulfoniccation-exchangeresinswerepreparedbythesulfonationofamacroporousPVCbeadwithconcentratedsulfonicacidorchlorosulfonicacid.theresultingsulfonicresinwasemployedintheinvestigationofcatalyticesterificationandsolfteningofwater,Theresultsshowthattheyieldsofestersreach60.0-84.4%accordingasdifferentfattyacidsandalcohols,therefractiveindexesofestersobtainedresemblethosereportedinthereferencesbasically,meanwhile,345Lsoftenedwaterwhichholds≤0.06mmol/Lhardnesswouldbepreparedby1Lwetsulfonicresinreusingfor4times.Theresultingsulfonicresinswouldhave1.6-2.0or2.5-3.0mmol/gexchangecapacitybyusingconcentratedsulfonicacidorchlorosulfonicacidassulfonatingagent,respectively,Thesulfonicresinhasamacroporousstructuretakingthemorphologywithagglomeratesofminutelysphericalgelparticlesascharacteristic.

  • 标签: 合成树脂 催化酯化 水处理
  • 简介:Fromaneconomicalpointofviewboththequalityoftheionexchangeresinsandthetechnologyusedinthefieldofindustrialwatertreatmentareimportantforasuccessfulperformance.Ingeneral,twodifferenttechnologieshavebeenestablishedonthemarket:ThemaindiffernecesbetweentheCO-andcountercurrenttechnologeswillbediscussedanddataconcerningtherequirementofchemicalsforregenerationandthequalityofthedeionizedwaterwillbeopposed.Inadditionseveraldifferentvarietiesofthemoderncountercurrenttechnologies,developedandpatentedbyBayerAG,willbedescribedandtheadvantages,dependingontheapplicationandthedemandonthequalityofthedeionizedwater,pointedout.Inviewofstrongerregulationsconcerningtheconsumptionofregenerationchemicals,andwastewater,andalsobecauseofthesuperiorqualityoftheproducedwater,themarketshareofcountercurrenttechnologieswillcontinuetoincreaseworld-wide.

  • 标签: 拜耳反向电流系统 离子交换理论 拜耳逆流系统 相互流系统 水处理
  • 简介:Thetreatmentandresourcereuseof1,2,4-acidproducingwastewaterbyself-mademacroporousadsorptionresinND,A-107wasstudiedinthispaper.Optimumadsorptionanddesorptionprocessparameterswereacquiredbysystematicallystudy.ThepolymericresinNDA-107indicatedgoodadsorption&desorptionof1,2,4-acidinthewastewater.Theremovalefficiencyof1,2,4-acid,CODerisabout78%,72%respectively.Itisevidentthatthisadsorptionprocessisanefficienttreatmentmethodfor1,2,4-acidproducingwastewater.Atthesametime,theaccumulationandresourcereuseofl,2,4-acidcanberealizedinthisprocess.

  • 标签: 资源再利用 废水处理 1 2 4-产酸废水 大孔聚合物吸附剂
  • 简介:由Wittmann和Lotz等的isotactic聚丙烯(iPP)的三个领域的概念的介绍。是在在结晶化行为和作为结果的性质上理解melt结构的影响的重要进展。为了进一步理解melt的物理性质,组织,在在三个领域的热处理以后的iPP的水晶的结构系统地被调查。在在不同领域对待以后,它被发现那水晶形态学包括spherulitic的尺寸和birefringence,光线、正切的lamellae的比例,等等,有显然不同的特征。我们的学习表明在域II的原子核局部地订的链和导致的存储器效果创作不能在退火下面被擦掉处理当在域III的原子核水晶碎片创作时,它将在退火下面聚集进程。基于我们的结果,高度图解的图被建议在三个不同领域说明melt结构的可能的物理特征。

  • 标签: 等规聚丙烯 结晶行为 形态演化 治疗 熔体结构 物理性质