简介:合成了通式为K10H5[Ln(PMo7W2VO39)2].nH2O(Ln-La^3+,Ce^3+,Pr^3+,Nd^3+,Sm^3+,Eu^3+,Gd^3+,Dy^3+,Yb^3)的9种五元新型杂多配合物,并用元素化学分析,TG,ICP,IR,UV,31^1P,51V-NMR,ESR,XPS,XRD进行了表征,结果表明新配合物仍保持Keggin结构,稀土元素处于配合物的内界。借助TG-DTA,不同温度下的IR,XRD的水溶性实验考察了新配合物的热解性质,得出了热稳定的温度范围为400℃-500℃,为催化研究提供了依据。
简介:Theadsorptioncapabilityofloamsoilfornano-TiO2affectedbytheamountandintensityofleachedwaterhasbeeninvestigatedbysimulatingthenaturalrainfallprocessundertheleachingcondition.Theresultsshowthattheamountandtheintensityofleachedwateraretwoimportantfactorsaffectingtheadsorptioncapabilityofloamsoilfornano-TiO2.Theresultsindicatethatthedepthoftheloamsoilcontainingamaximalamountofnano-TiO2isproportionaltotheamountofleachedwater,whileitisinverselyproportionaltotheintensityofleachedwater,ataconstantamountoftheleachedwater.Itwasalsofoundthattheadsorptioncapabilityofsoilsfornano-TiO2canbeimprovedbyaddingothermaterials,suchasdissolvedorganicmatter(DOM),bentoniteandstraw.ItwasfoundthatDOMisthebestsorbentforimprovingtheadsorptioncapabilityofloamsoilfornano-TiO2,followedbybentonite,whilestrawisnotsuitableforthemodificationofloamsoil.Theimprovementofadsorptioncapabilityofloamsoildependsontheamountoftheseadditives.Nano-TiO2canbeeffectivelyadsorbedonthesurfacelayerofloamsoilcontaininganappropriateamountofadditive.
简介:忍受2,6二度(imino)的一系列钴建筑群含苯氧基的ligands,LCoCl2[L=2,6-(ArNCH)2CH3C6H2OH]被ligand2,6二度(imino)的反应综合有钴二氯化物的相等的鼹鼠的酚,和这些建筑群被元素的分析描绘,1HNMR,MS和红外系列。一建筑群的结构被单个水晶X光检查衍射分析决定。
简介:InT12SO4+Na2SO4+di(2-ethylhexyl)dithiophosphoricacid+n-CsH18+watersystem,theT1^+equilibriummolalitiesweremeasuredationicstrengthfrom0.1to2.0mol·kg^-1containingNa2SO4assupportingelectrolyteinaqueousphaseandatconstantmolalityofextractantattemperaturesfrom278.15to303.15Kinorganicphase.ThestandardextractionconstantsK^0atvarioustemperatureswereobtainedbymethodsofextrapolationandpolynomialapproximation.Thermodynamicquantitiesfortheextractionprocesswerecalculated.
简介:Theaggregationbehaviorandstructureofhydrophobicallymodifiedblockcopolymersofacrylamideand2-phenoxylethylacrylatewereinvestigatedbyviscometry,1HNMRrelaxation,2DNOESY,fluorescenceanddynamiclightscattering.Itwasfoundthattheaggregationbehaviorwasstronglydependentontheconcentrationofpolymersolutionandthehydrophobecontents.Withvaryingconcentrationfrom2.0,6.0,8.0to12.0g/L,thereweredifferentaggregatemorphologiesdistributedinaqueoussolutions,suchasmonopolymerchain,micelle-likeaggregate,multi-micelleaggregateandcross-linkednetwork.Accordingtothemodelofaggregation,itcangiveareasonableexplanationonthelargemagnitudeenhancementofviscositywiththeincreasingofpolymerconcentration.Additionaldataof2DNOESYandfluorescenceshowthatthecopolymerwithhigherhydrophobecontent(molarfraction≥1%)islikelytoformintra-molecularassociation.
简介:Thenon-isothermaldecompositionoflead2,4,6-trinitroresorcinatemonohydrate,Pb(TNR)·H2O,wasinvestigatedbymeansofTG-DTA,DSCandIR.Thethermaldecompositionmechanismandthedissociatedkineticswerealsoinvestigated.ThekineticparameterswereobtainedfromtheanalysisoftheDSCcurvesbyintegralanddifferentialmethods.ThemostprobablekineticmodelfunctionofthedehydrationreactionofPb(TNR)·H2Owassuggestedbythecomparisonofthekineticparameters.
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简介:Inthisletter,Fe2O3UFP(UltrafineParticles)hydrosolandorganosolwithhighthirdorderopticalnonlinearsusceptibility(3)havebeenreportedforthefirsttime.ThesurfacialmodificationofFe2O3UFPwithdodecylbenzenesulfonateions(DBS)canenhancethenonlinearopticalresponsethroughinterfacialconfinementofelectronmotion.Theinvolvedmechanismisdiscussed.
简介:基于刚性配体2-(4-噻唑基)苯并咪唑和二价金属铜离子在水热条件下成功地合成了2个Keggin型多酸化合物[CuⅡ(L1)2(H2O)]2[SiW12O40](1)和[(L1)4(L2)2(H3PMo12O40)2]·5H2O(2)(L1=2-(4-噻唑基)苯并咪唑,L2=苯并咪唑).通过单晶X-射线、红外光谱和元素分析对化合物1和2进行了表征.在化合物1中,存在2个独立的结构单元:Keggin型多酸和蝴蝶状的络合物阳离子[Cu(L1)2(H2O)]2+.化合物2为含有混合配体的超分子结构,由Keggin型多酸、4个游离的L1和2个L2配体组成.此外,研究了化合物1和2的电化学和光催化性能.
简介:Novelsulfur-containingcompounds(3a–3c,4a–4c)wereobtainedinethanolwith1,3-diphenyl-2-propanoneasthestartingmaterial.Theadvantagesofthisprocedureweremildreactionconditions,simpleprotocol,andhighyields.ThestructuresoftheproductswerecharacterizedbyIR,1HNMR,MSandelementaryanalysis.Thecrystalofthenewcompound4abelongstomonoclinic,spacegroupC2witha=18.727(3),b=6.5179(9),c=13.7576(18),b=131.0610(10)°,V=1266.2(3)A3,Z=2,Dc=2.136g/cm3,μ=1.078mm-1,F(000)=843,R=0.0490andwR=0.1247for3211observedreflectionwithI>2δ(I).X-rayanalysisrevealsthatthemoleculeisnotsymmetrical,themolecularstructureisstabilizedbyweakp–pstackinginteractions,andnoclassicalhydrogenbondscanbeobserved.
简介:Tetrabutylammoniumorpotassiumsaltsoforganometalllicderivativesoflacunarypolyanion(RM)3P2W15O59^n-(RM=CpTi,CpZr,C4H7O2SnorC5H9O2Sn)havebeenpreparedandstructurallycharacterizedbyelementalanalysis,IR,UV-Vis,^1HNMRand^183WNMRspectroscopies.Thetitlecomplexesexhibitantitumoractivityinvitro.
简介:Anovelaciddyeacidwassynthesizedbythecondensationreactionbetweenbromamineacidand2-amino-6-nitrobenzothiazoleanditsanti-UVprotectionpropertieswereevaluated.Theresultsshowedthatsilkdyedwiththisdyehadverygoodultravioletradiationprotectioncapabilityandexcellentdyeingperformance.TheUV-absorptionmechanismofthisdyewasalsodiscussed.