简介:HighactiveandstablegoldcatalystssupportedoncrystallineFe2O3andCeO2/Fe2O3werepreparedviathedeposition-precipitationmethod.ThecatalystwithaAuloadof1.0%calcinedat180°CshowedaCOconversionof100%at-8.9°C,whileAu/CeO2/Fe2O3convertedCOcompletelyat-16.1°C.Evenhavingbeencalcinedat500°C,Au/Fe2O3stillexhibitedsignificantcatalyticactivity,achievingfullconversionofCOat61.6°C.ThecatalystwithalowAuloadof0.5%couldconvertCOcompletelyatroomtemperatureandkepttheactivityunchangedforatleast150h.N2adsorption-desorptionmeasurementsshowthatthecrystallinesupportspossessedahighspecificsurfaceareaofabout200m2/g.CharacterizationsofX-raydiffractionandtransmissionelectronmicroscopyindicatethatgoldspecieswerehighlydispersedasnanoorsub-nanoparticlesonthesupports.Evenafterthecatalystwascalcinedat500°C,theAuparticlesremainedinanano-sizeofabout6―10nm.X-rayphotoelectronspectrarevealthatthesupportedAuexistedinmetallicstateAu0.ThemodificationofAu/Fe2O3byCeO2provedtobebeneficialtotheinhibitionofcrystallizationofFe2O3andthestabilizationofgoldparticlesindispersedstate,consequentlypromotingcatalyticactivity.
简介:AsimpleandefficientcascadeMichael/cyclizationreactionof3-aminoindolin-2-oneswithenones/enalswasidentifiedforthesynthesisofpotentiallybiologicallyactive3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles],usingDBUasanefficientcatalystandethyleneglycolasanenvironmentallybenignsolvent.Morediverse3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]analoglibrarieswerepreparedingoodyields(upto97%).Thestructureof3’,4’-dihydrospiro[pyrrol-3,2’-oxindoles]wasconfirmedbymassspectrometryanalysis,NMRanalysisandsinglecrystalX-raydiffraction.Themainadvantagesofthismethodincludetheavailabilityofstartingmaterials,simpleexperimentaloperation,shortreactiontime,aswellashighyieldsobserved.
简介:ThecomplexK3H4GeW9V3O40·8H2OcrystallizedinamonocliiniesystemwithspacegroupP2,Mr=2784.67,a=11.099(3),b=16.452(4),c=13.534(4),β=108.14°,Z=2,V=2348.493,F(000):2456,μ=239.7cm-1,De=3.932g/cm3.ThefinalR=0.083for4528non-zeroreflexions.ThestructureofanionsGeW9V3O40andGeW9O34belongstoA--type.
简介:AnaffordablesolutiontoTier-3RegionalCenter(RC)ispresentedinthistalk,asimpleprototypehasbeensetupforevaluationofthesystemperformance,thisprototypecanbeeasilyscaledtobiggerone.Asetofmeasurementshavebeenconductedinbothcomputerandnetworksystembehavioursinmultipleconcurrentlyrunningjobscontexts.Inthetalkthesemeasuredresultsaretalkedanddiscussed,includingsystemandnetworkeffectiveutilizationsandlimitations,andtheidentifiedbottlenecksindifferentnetworklayouts,andthecomparisonswithsimulation.
简介:Heavyionbeamsaregenerallyrecognizedasoneofpowerfulmutagensinplantbreedingtogeneratenewmutantswithidealorusefulagronomiccharacters[1].12C6+ionbeams(80MeV/u)acceleratedbyHeavyIonResearchFacilityinLanzhou(HIRFL)wereusedtoirradiatewheatsamples,oneofthemajorwheatvarietiesinQinghaiprovince,namedGaoyuan448.Theradiationdosesrangedfrom10to200Gy.Theirradiatedsamples,controls,andanothermajorwheatvarietynamedAbowereplantedinfarmlocatinginLeducountyofQinghaiprovincein2014.
简介:Soilconsolidationwouldinducevariationsofitstransportcoefficientssuchashydraulicconductivityanddiffusioncoefficient.Thispaperpresentsastudyoftheinfluenceofbarrierconsolidationontransportcoefficients,anda3Dtransportmodelbasedonmixturetheoryisproposedfordescribingthelinersthatinvolvecirculardefectsinthegeomembrane.TheelastoplasticALPHAmodelisrevisedbyusingthespatiallymobilizedplane(SMP)criterionforsimulatingthedeformationofthesoils.Then,the3Dmodelcouplingthenonlinearconsolidationandcontaminantadvection-diffusionissolvedusingthefiniteelementsoftwareABAQUS.Theresultsshowthattheimportanceofreducingthedefectsizeinthegeomembraneandthelinerporositytocontrolthecontaminantconcentrationincrease.
简介:Theauthorsproposeanovelmethodfortransportingmulti-viewvideosthataimstokeepthebandwidthrequirementsonbothend-usersandserversaslowaspossible.Themethodisbasedonapplicationlayermulticast,whereeachendpointreceivesonlyaselectednumberofviewsrequiredforrenderingvideofromitscurrentviewpointatanygiventime.Thesetofselectedvideoschangesinrealtimeastheuser'sviewpointchangesbecauseofheadoreyemovements.Techniquesforreducingtheblack-outsduringfastviewpointchangeswereinvestigated.Theperformanceoftheapproachwasstudiedthroughnetworkexperiments.
简介:Anewkindofmonomerswassuccessfullysynthesizedbythereactionbetween2-chloromethylcycloketalandtrimethylsilylcyanide,followedbyringclosureanddehaiogenation.Polymerizationsofthemonomerswerecarriedoutinbenzenesolutionat80℃withbenzoylperoxideasinitiator.BoththestructuresofmonomersandpolymerswerecharacterizedbyIR,1HNMR,13CNMRandelementalanalysis.
简介:TheIsodynetechniquebasedonthescatteredlightscanningfromathinlaserbeamcanbeusedtoobtaintheinformationinsidetheloadedobjectintheroomtemperaturenondestructively,soitisaverypowerfultechniquein3Dstressanalysis.Theproblemsarehowtointerprettheinformationandhowtogetsufficientinformationfromthefewinterferencefringe.Birefringencephaseshifttechniquecandistinguishthefringeordersautomaticallyandenrichtheinformationin256graylevelsbetweenmaximandminimlightintensity.InthepapertheIsodynebirefringencephaseshiftmethodwithanobliqueincidenceandequilibriumequationispresented,bywhichthe3DstressesinthemiddleplaneofaplatewithUshapenotchareseparatedsuccessfully.