学科分类
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491 个结果
  • 简介:Amain-chainliquidcrystallineionomer(MLCI)containingsulfonicgroupwassynthesizedbyaninterfacialcondensationreaction.TheMLCIwasblendedwithpolybutyleneterephthalate(PBT)andpolypropylene(PP).MLCIinteractedwithboththedispersed(PP)phaseandthematrix(PBT)phasetomodifytheinterfacialinteractionofPBTandPP.Differentialscanningcalorimetry(DSC),scanningelectronmicroscopy(SEM)andFTIRimagingsystemanalysisdemonstratedthesignificanceofinterfacialinteractioninthepolymerblends.MLCIbroughtaboutgoodadhesionattheinterfacial,whichreducedthedispersephasesizeandenabledafinePPphaseatmatrix.ThemechanicalpropertiesoftheternaryblendswereimprovedwhenaproperamountofMLCIwasadded.Thiswasattributedtoenhancedadhesionattheinterface,whichinvokedbettermechanicalpropertiesintheblends.

  • 标签: 界面相互作用 液晶离聚物 PBT 磺酸基 PP 共混改性
  • 简介:Condensationofmethyl7-methylcoumarin-4-acetate(2)withprimaryaminesandwithan-thranilicacidgave7-methyl-2-oxo-N-aryl-2H-[1]-benzopyran-4--acetamide(4a—d)and(7),respectively.Compound7underwentcyclizationtogive2-(7-methyl-2-oxo-2H-[1]-benzopyran-4-yl)-methyl-4H-3,1-benzoxazin-4-one(3).Thereactionof3witharomaticaminesgavethecorrespondingquinazolonederivatives5whichtautomerisestothethermodynamicallymorestableisomer6,whereasitsreactionwithGrignardreagentsandaromaticaldehydesgave8a,8b,and9a,9b,respectively.

  • 标签: LACTONE COUMARIN aromatic aldehydes AMINES CYCLIZATION
  • 简介:Threenewpolysesquisiloxane-boundplatinumcomplexesweresynthesizedviahydrolysisofN,N-di(β-ethylmercaptoethyl)γ-(triethoxysilyl)propylamineorcohydrolysisofthemonomerwithdodecyltriethoxysilaneorwithphenylpropylthiethoxysilaneandimmobilixationonfumedsilica,followedbyreactingwithpotassiumplatiniteinacetoneunderargonatmosphere.Theplatinumcomplexesexhibitedhighcatalyticactivityforthehydrosilylationofolefinsbytriethoxysilane.Theeffectsoftemperatureandtheamountofcomplexonthecatalyticactivity,aswellastherecoveryandreusabilityofthecatalystswereinvestigated.

  • 标签: 合成 聚倍半硅氧烷 铂络合物 二(乙基硫氢基乙基)氨基团 三乙氧基甲硅烷 催化作用
  • 简介:通过吝啬地的近似,Gaussian近似,不安扩大,和一个3理论的地理论上的重正常化组分析的详细研究,我们证明不稳定性修理了理论的点,和他们的联系不稳定性代表,与可伸缩和一阶的阶段转变在一个地驱动的分级的4模型展出的普遍性行为相当可能相关,在它的批评温度和近的th下面放大并且领先修正到可伸缩的Finitetime被考虑。我们也证明一阶的阶段转变的不稳定性代表Yang庇护边奇特等价于那些,并且采用后者改进我们前者的估计。结果与存在数字结果同意很好。

  • 标签: 重整化群理论 相变动力学 CA模型 一阶 标量 驱动
  • 简介:Theinteractionsofoxidativeradicals(Br2,HOetc.)withN-phosphoryldipeptidederivatives(NDM-TrpOMeandNDT-MetOMe)havebeeninvestigatedbyusingpulseradiolysisatdifferentpHvalues.IthasbeenfoundthatBr2andHOradicalsoxidizetheMet-siteandTrp-siteinthedipeptidederivativesviaformationofthethree-electron-bondedintermediateandindolylradicalsimultaneously.Thentheintramolecularelectrontransferalongthepeptidebackboneoccurs.Therateconstantsofelectrontransfer,k,havebeendeterminedandthereactionmechanismhasbeendeduced.

  • 标签: N-Phosphoryl DIPEPTIDE oxidation electron transfer pulse
  • 简介:Difluorocarbenegeneratedfromthedecompositionoffluorosulfonyldifluoroaceticacid(2)reactedwithvarioussodiumsaltsofN-heterocycliccompounds(1)givingthecorrespondingdifluoro-methylatedproductsinacetonitrileat10—40℃.Benzotriazole(1a),benzimidazole(1b)andimidazole(1c)wereconvertedinto1-(difluoromethyl)benzotriazole(3a),1-(difluoromethyl)benzimidazole(3b)and1-(difluoromethyl)imidazole(3c)respectively.Indole(1d)reactedwith2togive-(fluorosulfonyldifluoro-acetate)indole(2d)ratherthantheexpecteddifluoromethylatedderivatives.

  • 标签: HETEROCYCLIC imidazole INDOLE ACETONITRILE acetate giving
  • 简介:N-nitrosaminesarestrongcarcinogensforhumans.Thispapergivesanoverviewofthenitrosmainesincigarettesmokeincludingtheformation,theharmfulness,theanalyticalmethodsofthenitrosmainesandtheadsorptionsanddegradationsofN-nitrosamines.

  • 标签: N-亚硝酸 烟草 解析方法 吸附降解
  • 简介:Aroutingtreeforasetoftasksisadecisiontreewhichassignsthetaskstotheirdestinationsaccordingtothefeaturesofthetasks.Aweightedroutingtreeisonewithcostsattachedtoeachlinkofthetree.Linksofthesamefeaturehavethesamecost.Itisprovedthattheproblemoffinding?routingtreeoftheminimumcostforagivensetoftasksoftwofeaturesisNP-complete.

  • 标签: ROUTING ATTACHED labeled finding COSTS 二七
  • 简介:1-17 Vibrational Properties of Na_1-17VibrationalPropertiesofNa_¥ZhangFengsllou;E.SuraudlandR.GlowinskiZItisknownthatsmallso...

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  • 简介:N阶电阻网络等效电阻进行了研究,应用虚拟电流法给出了这类问题的两个普适规律,并将所得结果与其它相关结果进行了比较

  • 标签: N阶 电阻网络 虚拟电流 等效值
  • 简介:Bythereactionofpoly(bromoacetylstyrene)(EBPS)withthiaurea(TU),akindofnovelchelatingresinwithheterocyaclicringofsulfurandnitrogen,poly[4-(2-amino)thiazoleyl-4-vinylben=ene],wassynthesized.ItsstructurewascharacterizedbyFTIRandelementalanalysis.Thefactorswhichhaveinfluenceonthereactionsuchasreactiontime,solvents,andmolarratioofreactantswereinvestigated.

  • 标签: 合成 螯合树脂 含硫含氮杂环化合物 | 反应时间
  • 简介:AnewchemilurninescencelabelN-(β-carboxypropionyl)luminol(CPL)wasusedtolabelsheepanti-humanIgG(SaHIgG).Thelabeledantibodywasstableandcouldbedetectedatleastdownto10-17~10-16mol.Themolarincorporationratiowasestimatedtobe0.26molofCPLpermolofSaHIgG.TherewerenoapparentchangesintheimmunoreactivityofthelabeledSaHIgGandinthequantumefficiencyoftheCPLafterlabeling.

  • 标签: CHEMILUMINESCENCE IMMUNOASSAY N-(β-carbaxypropionyl)luminol sheep anti-human IgG