简介:Amain-chainliquidcrystallineionomer(MLCI)containingsulfonicgroupwassynthesizedbyaninterfacialcondensationreaction.TheMLCIwasblendedwithpolybutyleneterephthalate(PBT)andpolypropylene(PP).MLCIinteractedwithboththedispersed(PP)phaseandthematrix(PBT)phasetomodifytheinterfacialinteractionofPBTandPP.Differentialscanningcalorimetry(DSC),scanningelectronmicroscopy(SEM)andFTIRimagingsystemanalysisdemonstratedthesignificanceofinterfacialinteractioninthepolymerblends.MLCIbroughtaboutgoodadhesionattheinterfacial,whichreducedthedispersephasesizeandenabledafinePPphaseatmatrix.ThemechanicalpropertiesoftheternaryblendswereimprovedwhenaproperamountofMLCIwasadded.Thiswasattributedtoenhancedadhesionattheinterface,whichinvokedbettermechanicalpropertiesintheblends.
简介:Condensationofmethyl7-methylcoumarin-4-acetate(2)withprimaryaminesandwithan-thranilicacidgave7-methyl-2-oxo-N-aryl-2H-[1]-benzopyran-4--acetamide(4a—d)and(7),respectively.Compound7underwentcyclizationtogive2-(7-methyl-2-oxo-2H-[1]-benzopyran-4-yl)-methyl-4H-3,1-benzoxazin-4-one(3).Thereactionof3witharomaticaminesgavethecorrespondingquinazolonederivatives5whichtautomerisestothethermodynamicallymorestableisomer6,whereasitsreactionwithGrignardreagentsandaromaticaldehydesgave8a,8b,and9a,9b,respectively.
简介:Threenewpolysesquisiloxane-boundplatinumcomplexesweresynthesizedviahydrolysisofN,N-di(β-ethylmercaptoethyl)γ-(triethoxysilyl)propylamineorcohydrolysisofthemonomerwithdodecyltriethoxysilaneorwithphenylpropylthiethoxysilaneandimmobilixationonfumedsilica,followedbyreactingwithpotassiumplatiniteinacetoneunderargonatmosphere.Theplatinumcomplexesexhibitedhighcatalyticactivityforthehydrosilylationofolefinsbytriethoxysilane.Theeffectsoftemperatureandtheamountofcomplexonthecatalyticactivity,aswellastherecoveryandreusabilityofthecatalystswereinvestigated.
简介:Theinteractionsofoxidativeradicals(Br2,HOetc.)withN-phosphoryldipeptidederivatives(NDM-TrpOMeandNDT-MetOMe)havebeeninvestigatedbyusingpulseradiolysisatdifferentpHvalues.IthasbeenfoundthatBr2andHOradicalsoxidizetheMet-siteandTrp-siteinthedipeptidederivativesviaformationofthethree-electron-bondedintermediateandindolylradicalsimultaneously.Thentheintramolecularelectrontransferalongthepeptidebackboneoccurs.Therateconstantsofelectrontransfer,k,havebeendeterminedandthereactionmechanismhasbeendeduced.
简介:Difluorocarbenegeneratedfromthedecompositionoffluorosulfonyldifluoroaceticacid(2)reactedwithvarioussodiumsaltsofN-heterocycliccompounds(1)givingthecorrespondingdifluoro-methylatedproductsinacetonitrileat10—40℃.Benzotriazole(1a),benzimidazole(1b)andimidazole(1c)wereconvertedinto1-(difluoromethyl)benzotriazole(3a),1-(difluoromethyl)benzimidazole(3b)and1-(difluoromethyl)imidazole(3c)respectively.Indole(1d)reactedwith2togive-(fluorosulfonyldifluoro-acetate)indole(2d)ratherthantheexpecteddifluoromethylatedderivatives.
简介:Aroutingtreeforasetoftasksisadecisiontreewhichassignsthetaskstotheirdestinationsaccordingtothefeaturesofthetasks.Aweightedroutingtreeisonewithcostsattachedtoeachlinkofthetree.Linksofthesamefeaturehavethesamecost.Itisprovedthattheproblemoffinding?routingtreeoftheminimumcostforagivensetoftasksoftwofeaturesisNP-complete.
简介:1-17 Vibrational Properties of Na_n1-17VibrationalPropertiesofNa_n¥ZhangFengsllou;E.SuraudlandR.GlowinskiZItisknownthatsmallso...
简介:Bythereactionofpoly(bromoacetylstyrene)(EBPS)withthiaurea(TU),akindofnovelchelatingresinwithheterocyaclicringofsulfurandnitrogen,poly[4-(2-amino)thiazoleyl-4-vinylben=ene],wassynthesized.ItsstructurewascharacterizedbyFTIRandelementalanalysis.Thefactorswhichhaveinfluenceonthereactionsuchasreactiontime,solvents,andmolarratioofreactantswereinvestigated.
简介:AnewchemilurninescencelabelN-(β-carboxypropionyl)luminol(CPL)wasusedtolabelsheepanti-humanIgG(SaHIgG).Thelabeledantibodywasstableandcouldbedetectedatleastdownto10-17~10-16mol.Themolarincorporationratiowasestimatedtobe0.26molofCPLpermolofSaHIgG.TherewerenoapparentchangesintheimmunoreactivityofthelabeledSaHIgGandinthequantumefficiencyoftheCPLafterlabeling.
简介:Theβ-carboxylicgroupplaysanimportantroleinthepeptideformation,esterificationandtheesterexchangeatthephosphorylgroupofN-phosphorylatedasparticacid.