Elastic behavior of saturated porous materials under undrained freezing

(整期优先)网络出版时间:2013-06-16
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Theelasticbehaviorofsaturatedporousmaterialsunderundrainedfreezingisinvestigatedbyusingaporomechanicalapproach.Thermodynamicequilibriaareusedtodescribethecrystallizationprocessofthepartiallyfrozensolutioninbulkstateandconfinedstateinpores.Byphasetransitionatfreezing,fusionenergy,thermalcontractionofsolid,solutionandicecrystals,volumechangesofcrystallizationbuildupremarkableporepressurethatinducesexpansionorshrinkageofsolidmatrix.Owingtothelowerchemicalpotentialwhenporewatermixeswithsalts,fewericeformsinpores.Penetrationoficeintotheporousmaterialsincreasesthecapillarypressure,butlimitse?ectontheporeliquidpressureandthestrainofsolidmatrix.Onthecontrary,theporepressureinducedbysolutiondensityrisesassaltconcentrationincreasesandcausessignificantshrinkageofsolidmatrix.