Design of Fe(3–x)O4 raspberry decorated graphene nanocomposites with high performances in lithium-ion battery

(整期优先)网络出版时间:2016-02-12
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Fe_(3–x)O_4raspberryshapednanostructures/graphenenanocompositesweresynthesizedbyaone-steppolyol-solvothermalmethodtobetestedaselectrodematerialsforLi-ionbattery(LIB).Indeed,Fe_(3–x)O_4raspberryshapednanostructuresconsistoforiginalorientedaggregatesofFe_(3–x)O_4magnetitenanocrystals,ensuringalowoxidationstateofmagnetiteandahollowandporousstructure,whichhasbeeneasilycombinedwithgraphenesheets.TheresultingnanocompositepowderdisplaysaveryhomogeneousspatialdistributionofFe_(3–x)O_4nanostructuresatthesurfaceofthegraphenesheets.TheseoriginalnanostructuresandtheirstronginteractionwiththegraphenesheetsresultedinverysmallcapacityfadinguponLi+ionintercalation.Reversiblecapacity,ashighas660mAh/g,makesthismaterialpromisingforanodeinLi-ionbatteriesapplication.