Fe_(3–x)O_4raspberryshapednanostructures/graphenenanocompositesweresynthesizedbyaone-steppolyol-solvothermalmethodtobetestedaselectrodematerialsforLi-ionbattery(LIB).Indeed,Fe_(3–x)O_4raspberryshapednanostructuresconsistoforiginalorientedaggregatesofFe_(3–x)O_4magnetitenanocrystals,ensuringalowoxidationstateofmagnetiteandahollowandporousstructure,whichhasbeeneasilycombinedwithgraphenesheets.TheresultingnanocompositepowderdisplaysaveryhomogeneousspatialdistributionofFe_(3–x)O_4nanostructuresatthesurfaceofthegraphenesheets.TheseoriginalnanostructuresandtheirstronginteractionwiththegraphenesheetsresultedinverysmallcapacityfadinguponLi+ionintercalation.Reversiblecapacity,ashighas660mAh/g,makesthismaterialpromisingforanodeinLi-ionbatteriesapplication.