Thecarbon-13spin-spinrelaxationtimesoffluorine-containingionomersaremeasuredandmotionalcorrelationtimesτ_oandτ_darecalculatedbyusingVJGMmodel.Theresultsshowthatthemotionsofpolymermainchaininionomersbecomemoredifficultwithincreasingofionizationdegreeandcontentsoffunctionalgroup,anddependonthefinestructuresandstabilityofionicmicrodomains.