学科分类
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2 个结果
  • 简介:Whenliquidsteelslagproducedfromsteelmakingprocesswastreatedintothepost-coldslagbyconventionalmethods,thegreatdealofslagheatwasdissipatedintotheenvironment,causingalotofenergywasteandenvironmentalpollution.Inthisstudy,anovelapproachofdirectutilizationofhotsteelslagasarawmaterialandslagheatfortheproductionofglass-ceramicswasproposedandexperimentallytested.Inordertosimulateliquidslagfromsteelmakingelectricfurnace,40%water-quenchedslagwasremeltedat1450℃andthenmixedwith60%meltingadditives(silicapowder,aluminapowderandsodiumoxide,etc.)andsubsequentlymeltedtogetherat1500℃for1hintomodifiedliquidslagwhichwascast,heat-treated,annealedandtransformedintoglass-ceramics.Theheat-treatedglasssampleswereinvestigatedusingdifferentialthermalanalysis(DTA),X-raydiffraction(XRD),andscanningelectronmicroscopy(SEM).Theresultsshowthatdominantcrystallinephaseisdiopside[CaFe(SiO3)2]andtheshapeofthecrystalislikethegranule,diameterisabout0.2-0.6μm.Aglass-ceramicwithnucleationtemperatureof695℃fortwohoursandcrystallizationtemperatureof893℃foronehourand1163℃forhalf-hourexhibitedthebestcombinationofproperties.Thismethodofslagmixedwithmeltingadditivestoadjustthecompositionoftheparentglassisimportantfortheindustrialproductionofglass-ceramicsbydirectutilizationofhotsteelslag.

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