学科分类
/ 10
199 个结果
  • 简介:LuminescencelifetimeofCe(Ⅲ)forCe0.9RE0.1P5O14,whereREdenotesrareearthionsotherthanCe(Ⅲ),wasmeasuredbymeansofthetime-correlatedsinglephotoncountingtechnique.Ithasbeenfoundthatthelifetimedataarecapableofelucidatingtheenhancementorquenchingofcerium(Ⅲ)luminescencebyalienREions(otherthanCe)indoublydopedceriumpentaphosphatecrystal.

  • 标签: REP5O14crystal Luminescence LIFETIME CE
  • 简介:Inthepasttenyearstheeomplementarytristimulusspeetrophotometryll],eTs,hasseenitsdiverseappli-eations{2一61thoughmostresearehesremaininrelativelysimpesystems,andlessworkhasbeeninvolvinkinetiereaetions.AnattemPthasbeenmadeontheinvestigationofsomecomPlieatedsystemseontainingrareearthsandmeta一acetylchloroPhosPhonaz

  • 标签: COMPLEMENTARY tristimulus SPECTROPHOTOMETRY KINETIC characteristics SIMULTANEOUS
  • 简介:ThechemicalstateofgrainboundarycosegregationofCeandPinFe-P-CealloysystemwasstudiedbymeansofAugerElectronSpectroscopy(AES).TheAugerpeaksofCesegregatedatgrainboundariesarefoundwithintherangeof60~180eV.BycomparingwiththeAugerspectraoftheFe-Ce-Pintermetalliccompound,itissupposedthatthereisatwo-dimensionalinterfacialphaseatgrainboundarieswithCeandPcosegregationwhichissimilartothestructureoftheFe-Ce-Pcompound.

  • 标签: GRAIN BOUNDARY cosegregation CERIUM PHOSPHORUS AES
  • 简介:Aseriesofthecoconutactivatedcarbons(CAC)basedabsorbentsmodifiedwithCuandCe(Cu/CAC,Cu/Ce/CAC)werepreparedbyimpregnationtechnologyforcarbondioxidecapture.TheadsocrptionequilibriumsofCO2onCu/CACandCu/Ce/CACweremeasured.TheresultsshowedthattheadsorptioncapacityofCO2ontotheactivatedcarbonmodifiedwithCu/Ceincreasedwiththedecreasingtemperatureinthesamepressure.TheadsorptioncapacityofCO2onCu/CACwashigherthanthatoftheblankCAC,andcomparedwiththeCu/CAC,theadsorptioncapacityofCO2ofCu/Ce/CACwiththemassratioofCu/Ce=30wasimprovedat298and303K.Inaddition,theadsorptionequilibriumdataforCO2atvarioustemperatureswasfittedtoLangmuir,FreundlichandD-Risothermmodels.ItwasfoundthattheD-RequationwasthebestmodelforfittingtheadsorptiondataonCu/Ce/CACatdifferenttemperatures.

  • 标签: ADSORPTION CO2 CAPTURE CU CE rare
  • 简介:SphericalYAG:Ce3+phosphorparticleswithnarrowsizedistributionwerepreparedbyspraypyrolysis.Theeffectsoftheconcentrationofsolution,theflowrateofcarriergasandtheannealingtemperatureonthephosphormorphologywerestudied.Theproductivityofprecursorparticlesshowsatrendofdropafterrisingwiththeincreaseofconcentration.Raisingtheflowrateofnitrogencanimprovetheproductivityoftheprecursorparticles.Phosphorpreparedbyspraypyrolysishasobviouslyhigheremissionintensitythanthatsynthesizedbysolidstatereaction,spraypyrolysismakesCe3+ionswelldistributedinthecrystallatticeastheluminescentcenters,andphosphorparticleshaveregularsphericityandnarrowsizedistribution.

  • 标签: 钇铝石榴石 稀土 热解 制备 发光二极管 荧光性质
  • 简介:Resinsofcomplexesmadefromagarose-Ce4+(RCA-Ce)andchitosan-Ce4+(RCC-Ce)wereprepared.Hydrolysisratesofmethamidophos,omethoateandchlorpyrifostreatedbyRCA-Cewere32.39%,27.12%and46.62%,respectively,thoseofchlorpyrifosandmethamidophosinmungbeansproutjuice38.28%and35.45%,andthatofchlorpyrifosinteaextract59.76%.HydrolysisratesofproteininteaextracttreatedbyRCA-Ceincreasedby86.46%.RCC-Cecouldbeemployedintheapplejuiceproduction.Thecontentsofmethamidophosandparathion-methylinthejuicetreatedbyRCC-Cedecreased58.76%and71.92%.Furthermore,RCC-Cewasusedtoclarificationforbeerbythewaysofacolumn.RCC-Cecouldhydrolyzesensitiveproteinandincreasecontentsoffreeaminoacidinthebeer.Therefore,thebeertreatedbyRCC-CecouldstayoxidationandagingprocedureduetosomemetalionsbeingabsorbedbyRCC-Ce.

  • 标签: RESINS POLYSACCHARIDES CERIUM hydrolyze protein ORGANOPHOSPHOROUS
  • 简介:Thesynthesisofprecursorofgreenphosphors,LaPO4:Ce,Tb,bymeansofco-precipitationwithcocurrentflowfeedwasstudied.Theeffectsofthereactiontemperature,thekindandconcentrationoftheacidinthebottomwater,andthechargingrateonthephysicalproperties,suchasparticlesize,wereinvestigated.Itisfoundthattheparticlesizeofthepowderiscontrollablebyadjustingacidityinbottomwaterandchargingrate.Thepowderwithdiametersizeof3to5μmwasobtained.ItsXRDandSEMwereanalyzed.XRDpatternsoftheas-preparedgreenphosphorpowdersdisplaythetypicalpeaksofCePO4.SEMshowsthatthemorphologyofpowdersisball-shaped.

  • 标签: LaPO4:Ce TB PRECURSOR green PHOSPHORS CO-PRECIPITATION
  • 简介:AnovelsolidsolutionCe6MoO15wasachieved.Theirstructureandoxideionicconductivitywerestudied.BasedonCe6MoO15,rareearthelementsubstitutiononceriumsiteshowsthatallresultingoxidesenhancetheconductivityfurther,andhavehighoxide-ionconductivity,whichmaybeakindofpromisingmaterialforSOFCs.

  • 标签: Ce6MoO15 FAST OXIDE ION conductor RARE
  • 简介:Ceriasphereswithdifferentsizesandsulfurizedproductswithcorrespondingmorphologywerepreparedbyhydrothermalandgas-solidreactionmethodat600–800°CunderCS2atmosphereforashorttime,respectively.Dimensionaleffectinpreparationofγ-Ce2S3wasfirstlyinvestigatedbymeansoftechniquessuchasscanningelectronmicroscopy(SEM),X-raydiffraction(XRD),thermalgravimetricanalysis(TGA)andspectrophotometer.Theresultsshowedthatwhenceriananoparticleswithsmallsizewereusedasprecursors,theγ-Ce2S3couldbepreparedatthelowertemperatureandthebadlysinteredproductswereobtained;whenceriananoparticleswithlargesizewereemployedasprecursors,pureγ-Ce2S3wasdifficultlyobtainedevenifthetemperaturewasupto800°Candtheproductstendedtokeeptheiroriginalsize.Theheat-resistancepropertyoftheγ-Ce2S3withlargesizewasbetterthanthesmallerone,andthepureγ-Ce2S3preparedfromprecursorwithsmallsizehadagoodpigmentaryperformance.

  • 标签: 耐热性能 前体 扫描电子显微镜 颜料 形貌 二氧化铈
  • 简介:有不同元素dopings的极其细小的基于Ce的氧化物nanoparticles(Zr,Y)被传播micropores的一起沉淀(MDC)的方法作为降水代理人用氨答案综合。为煤烟氧化的催化剂的活动被规划温度的氧化(TPO)评估反应。基于Ce的氧化物在这准备了学习为在在煤烟粒子和催化剂之间的松开的接触的条件下面的煤烟氧化的展出高催化的活动,和为煤烟燃烧的极其细小的Ce0.9Zr0.1O2nanoparticle的催化活动最高,364是其T10,T50和SCO2m,442???‰眠?ㄥ‵瑷吗?

  • 标签: 纳米颗粒 催化性能 碳烟氧化 氧化物 超细 制备
  • 简介:YAG:Ce3+(Yttriumaluminumgarnet)fluorescencepowdersweresuccessfullypreparedbyco-precipitationmethodusingaluminumnitrate,yttriumnitrate,cerousnitrateasthestartingmaterialsandammoniumcarbonateasprecipitant.TheproductswerecharacterizedbyX-raypowderdiffraction,luminescencespectrometer,transmissionelectronmicroscope(TEM).TheXRDresultsshowedthattheobtainedYAG:Ce3+fluorescencepowdershadthecrystallinestructuresofYAGatcalcinationstemperatureof900oCandtheTEMresultsshowedthatthegraindiameterswereabout100nm.TheYAG:Ce3+fluorescencepowders,synthesizedbyco-precipitationmethod,hadthebestluminescencepropertywhentheCedopingamountwasx=0.06inthemolecularformulaofY3-xCexAl5O12,thecalcinationstimewas2handthecalcinationstemperaturewas1000°C.

  • 标签: YAG:Ce3+ POWDERS CO-PRECIPITATION method characterization LUMINESCENCE
  • 简介:TheCe-Fe-OmixedoxidewitharatioofCe/Fe=7:3,whichwaspreparedbycoprecipitationmethodandemployedasoxygencarrier,fordirectpartialoxidationofmethanetosyngasintheabsenceofgaseousoxygenwasexplored.ThemixedoxidewascharacterizedbyX-raydiffraction(XRD),X-rayphotoelectronspectroscopy(XPS)andscanningelectronmicroscopy(SEM),andthecatalyticperformanceswerestudiedinafixed-bedquartzreactorandathermogravimetricreactor,respectively.Approximately99.4%H2se...

  • 标签:
  • 简介:Fe/Cu/Cemodifiedcoal-basedactivatedcarbon(AC)waspreparedbythesol-gelmethod,andtheeffectofFe/Cu/CeoncatalyticpropertiesofFe/AC,Fe-Cu/ACandFe-Cu-Ce/ACwasinvestigatedinthehydrolysisofcarbonylsulfide(COS)at50°C.Theirsurfacepropertieswereevaluatedbymeansofnitrogenadsorptionandwerecharacterizedbyusingscanningelectronmicroscopy(SEM),X-raydiffracto-metry(XRD)andX-rayphotoelectronspectroscopy(XPS).ThecatalyticactivitiesresultsshowedthatadditionofCuandCe...

  • 标签:
  • 简介:InordertoinvestigatetheeffectofCe-dopingonthecatalystsderivedfromhydrotalcite-likeprecursorsforcarbonylsulfide(COS)hydrolysis,aseriesofZn-Ni-Al-Cehydrotalcite-likecompoundswerepreparedbyco-precipitationmethodandthecatalyticactivityoftheirderivedcompositeoxideswerestudiedat50oC.TheeffectonthestructuralpropertiescausedbyCedopingwasstudiedbytheX-raydiffractometer(XRD),scanningelectronmicroscopy(SEM)andenergydispersivespectrometer(EDS).ThecatalyticactivitiesresultsshowedthatadditionofCeenhancedthecatalyticactivitiessignificantly,butexcessiveCe-dopinghadanegativeeffectonCOShydrolysis.XRD,SEMandEDSresultsillustratedthat,comparedwiththeCe-freesample,theparticlesizeofoxidesolidsdecreasedandthedegreeofdispersionincreasedduetoCedoping.

  • 标签: Ce-doping hydrotalcite-like compounds CARBONYL SULFIDE HYDROLYSIS
  • 简介:Y3Al5O12:Ce3+isthemostfamousphosphormaterialduetoitsexcellentphotolumincentproperties.Here,throughfirst-principlescalculation,theeffectofcarboninterstitialdefectsonY3Al5O12:Ce3+phosphorwasinvestigated.Itisfoundthatthecarboninterstitialstendtooccupythenext-nearestsitesofCe3+ioninY3Al5O12:Ce3+lattice.Specially,theseinterstitialdefectscanshortentheCe3+-O2-bondlength,leadingtoalargercrystalfieldsplittingof5dorbitaloftheCe3+atomandbigger5dcentroidshift.ThesetwofactorscausetheemissionspectrumofY3Al5O12(C):Ce3+redshiftcomparedwiththatofY3Al5O12:Ce3+.Moreover,withourcomparisonexperiment,wefindthattheY3Al5O12(C):Ce3+hasanobviousredshiftcomparedwiththatofY3Al5O12:Ce3+system,whichisinaccordwithourfirstprinciplescalculation.OurworksystematicallyinvestigatestheimpactofthecarboninterstitialdefectonY3Al5O12:Ce3+,andprovidesanewroutetotunetheemissionspectruminY3Al5O12:Ce3+.

  • 标签:
  • 简介:将变形AZ31镁合金作为研究对象,研究了将不同含量的元素Gd和Ce加入该合金模型之后形成的AZ31-8Re镁合金的力学性能和铸态组织等特性以及镁合金的金相微观组织和力学性能,系统地比较了不同含量的稀土元素对镁合金力学性能的影响,探讨了稀土元素Gd和Ce对AZ31变形镁合金的金相组织的影响以及对其的时效硬化行为。

  • 标签: AZ31镁合金 稀土元素Gd CE 显微组织 显微硬度
  • 简介:TheeffectsofUVAphotoirradiatedCe(Ⅳ)dopedTiO2nanoparticle(CDTP)onratcoloncarcinomacellline(C26)growth,cellcycledistribution,andmorphologywerestudiedbyMTTassay,FlowCytometry,andfluorescentstaining.Theresultsindicatethatabout64.6%cellsarekilledafter24hby180μg·ml-1CDTPwhen8minexposedtoUVA,over90%deadfor30mingroup,relativeto18.7%,41.5%ofTiO2atthesameconditionrespectively.Hoe33258stainingofthefixedcellsrevealstypicalapoptoticstructures(apoptoticbodies),andcellsarearrestedinG0/G1phase.

  • 标签: CERIUM DOPING TiO2 NANOPARTICLE TUMOR cell