简介:IntroductionInGuixiSmelter,copperanodeslimewastreatedbymeansoftechnologicalprocesofvolatilizingSeinarotarykiln,pickingcoppe...
简介:在之中无铅焊接材料,Sn-Ag-Cu合金有许多优点优异界面的性质和高度例如好弄湿的性质,爬抵抗。在这篇文章,组织和Sn-Ag-Cu材料的焊接性能被调查。二合金的表面形态学被实体镜的显微镜观察并且扫描电子显微镜(SEM)。化学宪法被X光检查精力散的光谱学(版本)检验。Sn-Ag-Cu的机械性质焊接Sn-Cu与那些相比系统地被评估焊接。结果证明Sn-Ag-Cu焊接基于不同焊接垫不同焊接性质。在接口的金属间化合的化合物(IMC)的厚度与老化时间增加。为镀金的垫,有很多IMC图,并且在焊接连接它能减少电的连接的可靠性。Sn-Ag-Cu焊接关节表演在传统的Sn-Cu上的一个优异机械性质焊接。酒窝减少和洞的数字增加因为Sn-Cu0.7合金和Sn-Ag3.0-Cu0.5合金的破裂表面有同类地分布式的许多小尺寸酒窝。
简介:ZrO2-SnO2compositenanoparticleswerepreparedbyheatingthehydrateprecursorssynthesizedbythechemicalco-precipitationreactionofZrOCl2andSnCl4.Theprecursorswereexaminedbydifferentialthermalanalysis(DTA)andthermogravimetricanalysis(TGA).ThecompositepowderwascharacterizedusingX-raydiffraction(XRD),transmissionelectronmicroscopy(TEM)anddesorptionisotherm(Barrett-Joyner-Halendamethod).Theaveragecrystalsizeofthenanoparticlerangesfrom15to30nmforthesamplecontaining5%-25%ZrO2(massfraction).MostoftheporesintheZrO2-SnO2nanoparficlesareabout10-20nmindiameter.Thecompositepowderispromisingforchemicalsensors.
简介:Zinctinoxide(ZTO)thinfilms,withzincacetateandtributyltinchlorideasrawmaterials,weredepositedonglasssubstratesbythemethodofmetalorganicchemicalvapordeposition(MOCVD).Thecrystallization,microstructureandopticalpropertieswereinvestigatedbyscanningelectronicmicroscope(SEM),X-raydiffraction(XRD)andultraviolet-visible(UV-Vis)spectrophotometer.TheresultsshowthatwiththeincreaseinSn/Znratio,thecrystalchangesfromwurtzitetorutilephase.Whentheratioreaches11:18,theintensityofZn_2SnO_4peaksappearstobethestrongestandtheopticalbandgapisabout3.27eV.Calculatedbytheenvelopemethod,thethicknessoftheZTOthinfilmsis713.24nm.MeasuredbyUV-Visspectrophotometer,thetransmittanceoftheZTOthinfilmsreachesupto80%inthewavelengthrangeof400-1000nmwhentheSn/Znratiois7:18.
简介:利用平衡合金法,采用扫描电镜-能谱仪和X射线衍射方法对Al-Fe-Sn三元系973和593K等温截面的相关系进行实验测定。实验结果表明:在此两个截面上均未检测到三元化合物;973K时液相中Fe的最大固溶度为1.6%(摩尔分数),而593K时Fe和Al在液相中的最大固溶度分别为0.6%和5.1%(摩尔分数);在973和593K等温截面上,Sn在Fe-Al化合物中的最大固溶度分别为4.2%和2.3%(摩尔分数);Fe-Al化合物均能与液相保持平衡。
简介:ThemicrostructureandtensilepropertiesofSn-9Znsolderunderdifferentcoolingandagingconditionwerestudied.Duringsolidification,thedistributionofZn-richphasesandgrainsizeinthemicrostructureofSn-9Znsolderweredecidedbythecoolingrate.TheZn-richphaseinSn-9Znsolderunderfurnacecooling,aircoolingandwatercoolingmediawasseparatelyexistedascoarsendendriticandneedlelikeshape,fineneedlelikeshapeandveryfinerod-likeshape,respectively.Afteraging,thecoarsendendriticwasbrokenandthecoarsenneedlelikeZn-richphasewaspartlychangedintofinedistributionofZn-richphaseforSn-9Znsolderwithfurnacecooling,andtherod-likeZnphaseintheSn-9ZnsolderunderwatercoolingwaschangedtoconglomeratedZnwithneedleshape.DuringtensiletestingonSn-9Znsolder,tensilestrengthandductilityreachedthebestwithwatercooling,butdecreasedwithagingeffect.Meanwhile,theductilityofsolderwithaircoolingandthestrengthofsolderwithfurnacecoolingincreasedwithaging.Thefracturemodewasductileandwasindependentofcoolingmediaandagingeffect.Thesizeanddepthofdimplesdecreasedfromwater,furnacetoaircooling.Afteraging,numberandsizeofdimplesincreasedonthesolderwithfurnacecoolingandaircooling.ThechangeonthesizeofdimplesfortheSn-9Znsolderunderdifferentcoolingconditionandwithagingeffectwasaccordancetothetensileproperties.
简介:Chemicalreductionmethodwasemployedtopreparenano-sizedSn2SbNialloycompositesusedasanodematerialforrechargeablelithiumionbatteries.Thisstrategywasadoptedtocombinethevirtuesofbothactive/inactiveandactive/activealloystofabricateaSn2SbNialloypowderwithtwoactivecomponentsandoneinactivecomponent.Thetwoactivecomponentscanrealizethehighcapacityfeatureofelectrodeandcanmakethevolumechangeofelectrodetakeplaceinastepwisemannerduetothedifferentlithiationpotentialsoftwoactivecomponents,leadingtoastablecyclingperformance.Sn2SbNialloyprovidesareversiblespecificcapacityover640mA·h/gwithanexcellentcyclicability.TheSn-Sb-Nialloycompositematerialshowstobeagoodcandidateanodematerialforthelithiumionbatteries.
简介:研究Sb元素含量对Sn-Bi系焊料性能的影响。通过差示扫描量热法研究Sn-Bi-Sb焊料的熔化行为。采用铺展实验研究焊料在Cu基板上的润湿性。测试Sn-Bi-Sb/Cu结合界面的力学性能。结果表明:三元合金中含有包共晶反应形成的共晶组织,随着Sb含量的增加,共晶组织增多;在加热速率为5℃/min的条件下,三元合金显示出更高的熔点和更宽的熔程;添加少量Sb对Sb-Bi系焊料的铺展率有影响;在焊料铺展过程中形成反应过渡层,反应过渡层中存在Sb元素而无Bi元素,过渡层厚度随着Sb元素含量的增加而增大。Sn-Bi-Sb焊料的剪切强度随着Sb元素含量的增加而升高。
简介:IsothermalcompressionofaTi-5.6Al-4.8Sn-2.0ZralloywasconductedonaThermecmaster-Zsimulatoratthedeformationtemperaturesrangingfrom960to1060°C,thestrainratesrangingfrom0.001to10.0s-1,andthemaximumheightreductionof70.0%.Inthetwo-phaseregionoftheTi-5.6Al-4.8Sn-2.0Zralloy,thevolumefractionofαphasedecreaseswithanincreaseindeformationtemperature,butthegrainsizehasaslightvariationwithdeformationtemperature.ThestrainrateaffectsbothmorphologiesandgrainsizeoftheαphaseintheisothermalcompressionoftheTi-5.6Al-4.8Sn-2.0Zralloy.Theoptimalheightreductionalsocontributestothesmallandwell-distributedαphaseintheisothermalcompressionofTi-5.6Al-4.8Sn-2.0Zralloy.
简介:Usingorganicaquaregia,arecentlydiscoveredpowerfulorganicleachingagent,aneffectiveprocessofrecoveringPtdirectlyfromPt-Aubimetallicnanoparticleswasdemonstrated.ThepuritiesofthePtrecoveredfromamixtureofAuandPtnanoparticlesandfromPt-Aucore-shellnanoparticlecatalystareashighas(99.49±0.22)%,and(95.02±0.08)%,respectively.Thenovelrecoveryprocesspromisesapplicationsincatalysisindustry.
简介:阶段和磁电机在合金R(Co_(1-x)Sn_x)的热量的效果有x=的_20,0.025,0.050,0.075,和0.100被X光检查衍射分析和磁化测量调查。在RCo_2的Sn的替换是有限的。为RCo_2的合金的立方的MgCu_2-typestructure被X光检查粉末衍射证实,留下的合金主要由RCo_2阶段组成了,与一些RCo_3和R_5Sn_3杂质阶段一起。Theimpurity阶段随Sn内容的增加增加。合金的T_c不对为Dy(Co_(1-x)Sn_x)的Sn替换很敏感_2和Tb(Co_(1-x)Sn_x)_2inGd(Co_(1-x)Sn_x)_2,居里温度显著地增加。最大的磁性的熵在合金Dy(Co_(1-x)Sn_x)改变_2(x=0,0.025,0.050,0.075)是5.78,5.43,3.88,并且2.98J·kg~(-1)·K~(-1),分别地,并且那些在Tb(Co_(1-x)Sn_x)_2(x=0,0.025)是3.44,and2.29J·kg~(-1)·K~(-1)分别地0-2.0T在应用的地里变化。