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80 个结果
  • 简介:磁铁矿(Fe3有不同尺寸和形状的O4)nanoparticles被热分解方法综合。二条途径,非注射一个壶和热注射的方法,被设计详细调查生长机制。nanoparticles的尺寸和形状被调整先锋集中和持续时间时间决定,这被发现,它能好在我们的合成系统基于LaMer模型由机制解释了。monodisperseFe3O4nanoparticles从5nm有一条吝啬的直径到16nm,和形状进化从对球形三角形、立方。磁性是尺寸依赖者,和Fe3在关于在房间温度和最大的浸透磁化的5nm展览superparamagnetic性质的小尺寸的O4nanoparticles来临到78emu/g,而Fe3O4nanoparticles当直径增加到大约16nm时,开发铁磁性的性质。

  • 标签: 纳米FE3O4 磁性纳米粒子 合成系统 单分散 FE3O4纳米粒子 可控
  • 简介:Fe_(3–x)O_4raspberryshapednanostructures/graphenenanocompositesweresynthesizedbyaone-steppolyol-solvothermalmethodtobetestedaselectrodematerialsforLi-ionbattery(LIB).Indeed,Fe_(3–x)O_4raspberryshapednanostructuresconsistoforiginalorientedaggregatesofFe_(3–x)O_4magnetitenanocrystals,ensuringalowoxidationstateofmagnetiteandahollowandporousstructure,whichhasbeeneasilycombinedwithgraphenesheets.TheresultingnanocompositepowderdisplaysaveryhomogeneousspatialdistributionofFe_(3–x)O_4nanostructuresatthesurfaceofthegraphenesheets.TheseoriginalnanostructuresandtheirstronginteractionwiththegraphenesheetsresultedinverysmallcapacityfadinguponLi+ionintercalation.Reversiblecapacity,ashighas660mAh/g,makesthismaterialpromisingforanodeinLi-ionbatteriesapplication.

  • 标签: 纳米复合材料 锂离子电池 覆盆子 石墨 FE 性能
  • 简介:采用一步法合成了氨基化四氧化三铁(NH2-Fe3O4)磁性纳米材料,并以XRD,IR等手段对其进行了表征.将NH2-Fe3O4组装到磁性玻碳电极表面,得了NH2-Fe3O4修饰的磁玻碳电极,并以该修饰电极为工作电极,研究了其电化学性能.利用差分脉冲溶出伏安法研究了铅(Ⅱ)离子和铜(Ⅱ)离子在该修饰电极上的电化学行为.结果表明:NH2-Fe3O4纳米粒子可显著提高Pb2+和Cu2+在电极表面的富集量,提高溶出峰电流.由于差分脉冲溶出伏安曲线中Pb2+和Cu2+的溶出峰电位差较大,且没有相互干扰,所以该电极可用于Pb2+和Cu2+的同时测定.

  • 标签: 氨基化Fe3O4 磁性玻碳电极 PB2+ Cu2+
  • 简介:Weexperimentallydemonstratea4×4nonblockingsiliconthermo-optic(TO)switchfabricconsistingofthreestagesoftunablegeneralizedMach–Zehnderinterferometers.All24routingstatesfornonblockingswitchingarecharacterized.Thedevice’sfootprintis4.6mm×1.0mm.Measurementsshowthattheworstcrosstalkofallswitchingstatesis-7.2dB.Theon-chipinsertionlossisintherangeof3.7–13.1dB.TheaverageTOswitchingpowerconsumptionis104.8mW.

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  • 简介:Afacilestep-by-stepapproachisdevelopedforsynthesizingthehigh-efficiencyandmagneticrecyclableFe_3O_4@SiO_2@Ag@Nitrepang-likenanocomposites.ThismethodinvolvescoatingFe_2O_3nanorodswithauniformsilicalayer,reductionin10%H_2/AratmospheretotransformtheFe_2O_3intomagneticFe_3O_4,andfinallydepositingAg@Nicore-shellnanoparticlesontheL-lysinemodifiedsurfaceofFe_3O_4@SiO_2nanorods.Thefabricatednanocompositesarefurthercharacterizedbyx-raydiffraction,transmissionelectronmicroscopy,scanningelectronmicroscope,Fouriertransforminfraredspectroscopy,andinductivelycoupledplasmamassspectroscopy.TheFe_3O_4@SiO_2@Ag@Nitrepang-likenanocompositesexhibitremarkablyhighercatalyticefficiencythanmonometallicFe_3O_4@SiO_2@AgnanocompositestowardthedegradationofRhodamineB(RhB)atroomtemperature,andmaintainsuperiorcatalyticactivityevenaftersixcycles.Inaddition,thesesamplescouldbeeasilyseparatedfromthecatalyticsystembyanexternalmagnetandreused,whichshowsgreatpotentialapplicationsintreatingwastewater.

  • 标签: 纳米复合材料 降解效率 催化剂 可回收 有机染料 海参
  • 简介:Wegiveanestimateoftypesup×infonRiemannianmanifoldofdimension4foraYamabetypeequation.

  • 标签: 估计 流形 方程
  • 简介:Vanadiumalloys(V-Cr-Tiseries)areimportantcandidatematerialsforblanketcomponentsoffusionreactorsduetotheirlowactivationandhighstrengthatelevatedtemperatures.Low-temperatureirradiationembrittlementdeterminestheoperationtemperaturelimitofVanadiumalloysfortheapplicationtostructuralmaterialsoffusionreactorsirradiationresponseofvanadiumalloysneedstobeclarifiedfortheirapplication.Inthepresentstudy,specimensoftwoalloys(V-4Cr-4TiandV-5Cr-5Ti)wereirradiatedwithenergeticHeionsandheavyionstounderstandhardeningofthealloysduetoheliumaccumulationandcascadedamageproduction.

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  • 简介:利用L-脯氨酸催化的5-氯水杨醛(1)与6-甲基-4-羟基吡喃酮(2)的缩合反应及硫酸铜催化下与1,3-二甲基-5-氨基吡唑(3)的串联反应,合成得到了10-氯-1,3-二甲基-5-(2-氧代丙基)色烯并[4,3-d]吡唑并[3,4-b]吡啶-6(3H)-酮(4)和10-氯-5-二乙氧基甲基-1,3-二甲基色烯并[4,3-d]吡唑并[3,4-b]吡啶-6(3H)-酮(5).化合物5的结构通过单晶X射线衍射法确定:晶体属于三斜晶系,空间群P-1;相对分子质量Mr=803.68;晶胞参数a=1.03160(10)nm,b=1.42900(13)nm,c=1.44268(15)nm;V=1.9448(3)nm~3;Z=2;晶胞密度Dc=1.372g/cm~3;吸收系数μ=0.228mm-1;单胞中电子的数目F(000)=840.晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子为R=0.0681,wR=0.2051.在晶体结构中色烯环与吡啶环及吡唑环近似于共平面.

  • 标签: 吡唑并[3 4-b]吡啶 合成 晶体结构
  • 简介:Multilayerblackphosphorus(BP)nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers(SAs).Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.

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  • 简介:Highlyefficientsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitehadbeensuccessfullysynthesizedbyastandardhydrothermalmethod.Theadditionofassistantreagentinthehydrothermalsystemispromisingtoobtainspecialmorphology.Theassistantreagent(EDTA)actsasagrowthmodifierofcrystal.Thepossibleformationmechanismsofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitewereschematicallydiscussed.Adetailedstudyofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeoliteimpactedonthephotodecolorationmethyleneblue(MB)solutionshowedthatthecompositehadahighlyreusableandstablepropertyforlong-runphotocatalyticapplication.

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  • 简介:TheGroupofEnergyMaterials(GEM)inIMPisengagedintheirradiationresponseofmaterialscandidatetoadvancednuclearenergysystems(GenIV,fusionreactors).Themajorprogressofresearchinourgroupin2016isintheirradiationhardening/embrittlementofoxide-dispersion-strengthened(ODS)ferriticsteelsandVanadiumalloys,andinthemechanismsunderlyingdamageproductioninsiliconcarbide(SiC)fibers.Abriefdescriptionisgivenasfollows.1.EffectoftheoxidenanoparticlesontheirradiationhardeningofODSferriticsteelsTheinfluenceofoxidenanoparticlesontheirradiationresistanceofODSferriticsteelsisacrucialissuefortheupgradeofODSsteels.

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  • 简介:Asafundamentalpropertyofnuclei,atomicmassesarewidelyusedinmanydomainsofscienceandengineering.Areliableatomicmasstablederivedfromtheexperimentaldata,wheretheatomicmassesandtherelevantexperi-mentalinformationcanbefoundconveniently,isinhighdemandbytheresearchcommunity.Tomeetthedemands,theAtomicMassEvaluation(AME)wasinitiatedin1950'sandaseriesofAMEmasstableshavebeenpublishedeversince.CurrentlytheAMEservestheresearchcommunitybyprovidingthemostreliableandcomprehensiveinformationrelatedtotheatomicmasses.ThenewatomicmassevaluationAME2016waspublishedintheMarchissueofChinesePhysicsCastwocom-plementarypapers[1;2].

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  • 简介:采用CBS-QB3方法构建了丙烯酸甲酯(CH_2=CHCOOCH_3)与O_3反应体系的势能剖面并在此基础上利用经典过渡态理论(TST)和Wigner矫正模型计算了标题反应在200K~1200K温度区间内的速率常数kTST/W.研究结果表明,CH_2=CHCOOCH)3与O)3反应首先经过渡态生成一个稳定的五元环中间体,然后按断键位置不同,分别生成产物P1(CH_3OCOCHO+CH_2O_2)和P2(CH)3OCOCHOO+HCHO).此外,速率常数结果显示,在计算温度范围内,标题反应速率常数呈正温度系数效应.294K时,CH_2=CHCOOCH_3与O_3反应速率常数为1.76×10^(-18)cm^3·molecule^(-1)·s^(-1),与所测实验值(0.95±0.07)×10^(-18)cm^3·molecule^(-1)·s^(-1)非常接近.

  • 标签: CH2=CHCOOCH3 O3 Criegee机理 反应机理 速率常数
  • 简介:Themainworkoftheirradiationtechniquegroupfocusesonthefollowingtwoaspectsin2016:1.TechniquesupportWehavehadabout772.5hbeamtimefor39roundsofsingleeventeffect(SEE)tests,whichiscooperatingwithvariousinstitutes,universities,andcompanies.Thetestsarethebasicsafeguardforthespacecraftandsatellite.InordertoguaranteethetestefficiencyoftheTerminal5,themaintenanceandimprovementforthevacuum,thesampletransferandbeammonitorsystemhavebeenachieved.

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  • 简介:β-glucanisoneofthemostimportantsourcesofcellwallinyeaststrains(Saccharomycescerevisiae).Itisnowknownthatβ-glucannotonlyexhibitsabroadspectrumofbiologicalactivitiesincludingimmune-modulating,anti-inflammatory,anti-cancer,andanti-agingproperties,butalsocanbeusedinfoodproductionasmoisturizer,dietaryfibers(DF)[1].Therefore,itisimperativetobreedyeaststrainswithhigherbiomassproductionandoptimizethefermentationprocess.Saccharomycescerevisiaeneedscarbonsourcesinbiomassaccumulation,butglucoseisexpensiveinindustrialfermentation[2].TheaimofthisstudyistoevaluatethedifferentcarbonsourcesonthegrowthofSaccharomycescerevisiae.

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  • 简介:1.ThemutationbreedingofplantsIn2016,themutationmechanismofvariousplantmutantsincludingArabidopsisthaliana,Geranium,Trades-cantiauminensis,TaraxacumkoksaghyzRodinandalgaeobtainedbyheavyionbeammutationbreedingtechniqueswereinvestigated.Thegenome-wideprofilingofanArabidopsismutantnamedcivar(CarbonionbeamsInducedVariegated)wasrevealedbyusingre-sequencingandtheroughmap-basedcloningtechniques.AphenotypescreeningofArabidopsisthalianairradiatedbycarbonionbeamsbasedonhigh-throughputimagingtechniquecombiningtheprincipalcomponentanalysisandscattermatrixclusteringanalysiswasbuiltandoptimizedwhichcanscreenthevariationofplantmutantpopulations.Thepigmentcomponentsandquantitiesandexpressionprofilesofkeygenesinvolvedinanthocyaninbiosynthesisofflower-colormutantofGeraniumandleaf-colormutantofTrades-cantiauminensiswereinvestigated.MutationbreedingofTaraxacumkoksaghyzRodininducedbycarbonionbeamirradiationswhichisnotableforitsproductionofhighqualityrubberandinulinwasstarted.Inaddition,thephotosyntheticresponseofthemutantsofScenedesmusquadricaudawithalteredpigmentfeatureswereanalyzed.

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  • 简介:Inordertoimprovethecarsalesservice4Sshopmanagementlevel,improvetheeconomicandsocialbenefitsofenterprises,incentivesareusedtoencouragetheirown4sshops.Inthispaper,throughouttherelatedanalysisofthequarterlyandannualawardsincentiveprograminlarge-scaledomesticautomobileenterprises,entropymethodwithMATLABsoftwareisappliedtoestablishthedimensionalfitfunction.Inthedataprocessing,themultiplelinearregressionfunctionintoLingosoftwareisemployedtogetthebestsolution;andClanguageisusedtorunthescreeningdataprogramthroughtheconsistencytestprograminthesensitivityanderroranalysis.Firstofall,considerthecompanytomaximizeprofitsandmaximizetheamountofcomplaintsinthestoretomaintainalowtarget;intermsofstaff,weshouldconsiderprovidingmoreincentivesforemployees;inthecustomer,theoverallsatisfaction,serviceAttitude,vehiclecleanlinessbasedshouldbeimproved.Andtwoprogramsforthemonthlyprofitandexcessprofitsofprogressiveincentivesshouldalsobeimproved.

  • 标签: ENTROPY Weight Method RELATED INDICATORS GRAY
  • 简介:TheannealingbehaviorofAgnanoparticlesinsilicawithandwithoutdefectswasinvestigatedinthisstudy.SilicasampleswithandwithoutArionpre-irradiationwereimplantedwithAgionsandthenannealedattemperaturefrom300to850℃.UV-VISspectroscopyandTEMwereusedtocharacterizetheopticalabsorbancepropertyandsizedistributionofAgnanoparticles,respectively.OpticalabsorbanceresultsshowthattheabsorbanceintensityofSPR(SurfacePlasmonResonance,SPR)peakfromAgnanoparticlesinthesamplewithpre-irradiationisstrongerthaninthesamplewithoutpre-irradiation,whichindicatesthatthedefectsproducedbypre-irradiationpromptthenucleationofAgnanoparticles.Duringannealing,theSPRpeakshiftstoshortwavelengthdirection,asshowninFig.1.

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  • 简介:Solidstatenanoporesornanochannelspreparedinpolymer[1;2]andsemiconductorfilms[3]haveshowninterestingtransportphenomena,becauseoftheirdiametersatthenanoscaleandpositiveornegativechargesontheirwalls.Grapheneisanidealmaterialfordevelopingsolidstatenanoporesnotonlyduetoitsatomicscalethickness,highmechanicalstrengthandchemicalstabilitiesbutalsobecauseoftheimpermeabilityofthepristinesinglelayergraphenetoallatomsandmoleculesexceptprotons[4].AsthesingleGraphene/PET(G/PET)nanoporeistheelementarybuildingblockfornanoporousmembrane,theunderstandingandcontrolofitsindividualionictransportpropertiesarealsocrucialinproteinseparation,waterdesalination,andbio-moleculedetectionusingarraysofidenticalnanopores.Here,thesingleG/PETnanoporewassuccessfullypreparedbyusingionirradiationtechnologyandasymmetricetchingmethod[5]andthecorrespondingionictransportpropertieswereinvestigatedindetail.

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