学科分类
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3 个结果
  • 简介:聚苯乙烯(PS)/triphenyl磷酸盐(TPP)composites被暂停聚合准备并且融化挤出,和火焰retardance和机械性质的比较研究被执行。结果比为获得PS/TPP的好dispersity融化挤出证明暂停聚合是一种更好的技术合成。TPPnanoparticles,是在尺寸的约50nm,被暂停聚合同质地并且一致地在一步舞在PS矩阵驱散。然而,PS/TPP合成部分被聚结,不规则地展出塑造了微米规模粒子由于融化挤出。与melt挤出相对照,由从21.8%增加到22.6%的暂停聚合的PS/TPPnanocomposite的有限的氧索引(LOI),和点火(TTI)的时间增加了12.3%,山峰热版本率(PHRR)在8.5%减少了,并且全部的热版本(THR)在11.0%减少了。由暂停聚合的PS/TPPnanocomposite的机械性质也增加了。张力的力量,在裂缝的延伸,和曲折力量分别地增加了36.4%,8.5%,和108%。

  • 标签: PP复合材料 悬浮聚合法 磷酸三苯酯 熔融挤出 制备方法 聚苯乙烯
  • 简介:Polyvinylidenefluoride(PVDF)hollowfibermembranespreparedfromspinningsolutionswithdifferentpolyvinylpyrrolidone(PVP)contents(1%and5%)atdifferentextrusionrateswereobtainedbywet/dryphaseprocesskeepingallotherspinningparametersconstant.InspinningthesePVDFhollowfibers,dimethylacetamide(DMAc)andPVPwereusedasasolventandanadditive,respectively.Waterwasusedastheinnercoagulant.Dimethylformamide(DMF)andwater(30/70)wereusedastheexternalcoagulant.Theperformancesofmembraneswerecharacterizedintermsofwaterflux,soluterejectionforthewetmembranes.ThestructureandmorphologyofPVDFhollowfiberwereexaminedbyBETadsorption,dry/wetweightmethodandscanningelectronmicroscopy(SEM).ItisfoundthattheincreaseinPVPcontentandextrusionrateofspinningsolutioncanresultintheincreaseofwaterfluxanddecreaseofsoluterejection.Theimprovementsofinterconnectedporousstructureandporesizeareinducedbyshear-thinningbehaviorofspinningsolutionathighextrusionrates,whichcouldresultintheincreaseofwaterfluxofhollowfibermembranes.Theincreaseofextrusionratealsoleadstotheincreaseofmembranethicknessduetotherecoveryeffectofelasticpropertyofpolymerchains.

  • 标签: 聚乙烯吡咯烷酮 中空纤维膜 聚偏氟乙烯 弹性性能 挤出速率 纤维形态
  • 简介:Opticalcouplingbehaviorandassociatedeffectsintwo-dimensionalimplant-definedcoherentlycoupledverticalcavitysurface-emittinglaser(VCSEL)arraysarestudiedviabothexperimentsandtheoreticalcalculations.Experimentsshowthatopticalcouplingbetweenarrayelementscanenhancethearray’soutputpower.Additionally,opticalcouplingvialeakyopticalfieldscanprovideextraopticalgainforthearrayelements,whichcanthenreducethethresholdsoftheseelements.Elementscanevenbepumpedwithoutcurrentinjectiontoemitlightbyreceivingastrongleakyopticalfieldfromotherarrayelements.Opticalcouplingcanalsocauseunusualphenomena:thecentralelementsinlarge-areacoherentlycoupledVCSELarraysthatlasepriortotheouterelementswhenthearraysarebiased,ortheaverageinjectioncurrentrequiredforeachelementtolase,whichismuchlowerthanthethresholdforasingleVCSEL.Theoreticalcalculationsareperformedtoexplaintheexperimentalresults.

  • 标签: VCSEL implant-defined VERTICAL-CAVITY SURFACE-EMITTING laser