简介：Anenvironmentallyfriendlyprecursor,adenosine,hasbeenusedasadualsourceofCandNtosynthesizenitrogen-dopedcarboncatalystwith/withoutFe.Ahydrothermalcarbonizationmethodhasbeenusedandwateristhecarbonizationmedia.Themorphologyofsampleswith/withoutFecomponenthasbeencomparedbyHRTEM,andtheresultshowsthatFecanpromotethegraphitizationofcarbon.Furtherelectro-chemicaltestshowsthattheoxygenreductionreaction(ORR)catalyticactivityofFe-containingsample(C–FeN)ismuchhigherthanthatoftheFe-freesample(C–N).Additionally,theintermediatesofC–FeNformedduringeachsyntheticprocedurehavebeenthoroughlycharacterizedbymultiplemethods,andthefunctionofeachprocedurehasbeendiscussed.TheC–FeNsampleexhibitshighelectro-catalyticstabilityandsuperiorelectro-catalyticactivitytowardORRinalkalinemedia,withitshalf-wavepotential20mVlowerthanthatofcommercialPt/C(40wt%).Itisfurtherincorporatedintoalkalinepolymerelectrolytefuelcell(APEFC)asthecathodematerialandledtoapowerdensityof100mW/cm~2.

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简介：ThisworkstudiesTedopingeffectsonthedirectbandgapphotoluminescence（PL）ofindirectGaxIn1-xPalloys（0.72≤x≤0.74）.Thetemperature-dependentPLshowsthattheenergydifferencebetweendirectΓvalleyandindirectXvalleysisreducedduetothebandgapnarrowing（BGN）effect,andthedirectbandtransitiongraduallydominatesthePLspectraastemperatureincreases.CarrierthermalizationhasbeenobservedforTe-dopedGaxIn1-xPsamples,asintegratedPLintensityincreaseswithincreasingtemperaturefrom175to300K.Theactivationenergyforcarrierthermalizationisreducedasdopingconcentrationincreases.BothBGNeffectandcarrierthermalizationcontributetothecarrierinjectionintotheΓvalley.Asaresult,thedirectbandtransitionisenhancedintheTe-dopedindirectGaxIn1-xPalloys.Therefore,thePLintensityoftheGa0.74In0.26Psamplewithactivedopingconcentrationof9×1017cm-3isincreasedbyfivetimescomparedwiththatofanominallyundopedsample.ItisalsofoundthatthePLintensityisdegradedsignificantlywhenthedopingconcentrationisincreasedto5×1018cm-3.Fromcross-sectiontransmissionelectronmicroscopy,nolargedopantclustersorotherextendeddefectswerefoundcontributingtothisdegradation.

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简介：Accordingtothegoodchargetransportingpropertyofperovskite,wedesignandsimulateap–i–n-typeall-perovskitesolarcellbyusingone-dimensionaldevicesimulator.Theperovskitechargetransportinglayersandtheperovskiteabsorberconstitutetheall-perovskitecell.Bymodulatingthecellparameters,suchaslayerthicknessvalues,dopingconcentrationsandenergybandsofn-,i-,andp-typeperovskitelayers,theall-perovskitesolarcellobtainsahighpowerconversionefficiencyof25.84%.Thebandmatchedcellshowsappreciablyimprovedperformancewithwidenabsorptionspectrumandloweredrecombinationrate,soweobtainahighJ_(sc)of32.47mA/cm~2.Thesmallseriesresistanceoftheall-perovskitesolarcellalsobenefitsthehighJ_(sc).Thesimulationprovidesanovelthoughtofdesigningperovskitesolarcellswithsimpleproducingprocess,lowproductioncostandhighefficientstructuretosolvetheenergyproblem.

简介：利用TCAD仿真技术,研究了电离总剂量辐射陷阱电荷对0.18μmN沟道MOSFET转移特性的影响.构建了0.18μmN沟道MOSFET的三维仿真结构,获得了在电离总剂量（totalionizingdose,TID）效应影响下,负栅压偏置时器件中电流密度的分布情况.分析了器件浅槽隔离层（shallowtrenchisolation,STI）中氧化物陷阱电荷和界面态陷阱电荷对器件泄漏电流的影响.仿真计算了N-MOSFET的转移特性,仿真结果与辐照试验结果受辐照影响的趋势基本一致,为深亚微米MOS器件的总剂量辐射效应的损伤机制提供了一种分析手段.

简介：在这份报纸，作者证明吉本斯的类似物推测为象在一个给定的方向在无穷收敛到一样的价值的一些答案的Liouville类型结果一样在N,扩大了第四个顺序Allen-Cahn方程。作者也证明priori跳并且为semilinear推进一个维的对称和刚硬结果第四份订单有更一般的非线性的椭圆形的方程。

简介：Inthispaper,normalincidenceverticalp-i-nphotodetectorsonagermanium-on-insulator(GOI)platformweredemonstrated.Theverticalp-i-nstructurewasrealizedbyion-implantingboronandarsenicatthebottomandtopoftheGelayer,respectively,duringtheGOIfabrication.Abruptdopingprofileswereverifiedinthetransferredhigh-qualityGelayer.Thephotodetectorsexhibitadarkcurrentdensityof~47mA∕cm~2at-1Vandanopticalresponsivityof0.39A/Wat1550nm,whichareimprovedcomparedwithstate-of-the-artdemonstratedGOIphotodetectors.Aninternalquantumefficiencyof~97%indicatesexcellentcarriercollectionefficiencyofthedevice.Thephotodetectorswithmesadiameterof60μmexhibita3dBbandwidthof~1GHz,whichagreeswellwiththeoreticalcalculations.Thebandwidthisexpectedtoimproveto~32GHzwithmesadiameterof10μm.ThisworkcouldbesimilarlyextendedtoGOIplatformswithotherintermediatelayersandpotentiallyenrichthefunctionaldiversityofGOIfornear-infraredsensingandcommunicationintegratedwithGeCMOSandmid-infraredphotonics.

简介：我们证明认识到量重叠是可能的切换上并且离开在一个单个量点的强壮的轻事的相互作用--半导体microcavity系统。如此的重叠启用有条件的动力学完成的违反直觉的量的观察。状况是可能的象emitter光一样的洞光子显示指数的腐烂的地方，但是他们的联合察觉概率展出真空Rabi摆动。显著地，这些量关联也是在nonequilibrium的现在如此的协调地驾驶的消散的量系统的稳定的州的系列。

简介：Two-dimensional（2D）graphitecarbonnitride（g-C3N4）nanosheetshavebeensuccessfullyusedasasaturableabsorber（SA）inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles（g-C3N4-NPs）andthree-dimensionalorderedmesoporousg-C3N4（mpg-C3N4）werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.

简介：DirectC—HfunctionalizationofquinolineN-oxideswitharylboronicacidsisachievedusingKMnO_4asthesoleandefficientoxidativesystem.Thismethodprovidesanefficientprotocoltoconstructregioselectively2-arylquinolineN-oxidesviaradicalcross-couplingreactioninmoderatedtogoodyieldsundermildconditions.

简介：Theneworganic-inorganiccompound,[C_6H_7N_2O_2]_3TeCl_5·2Clwassynthesizedanditsstructurewasdeterminedatroomtemperatureinthetriclinicsystem(P~-1)withthefollowingparameters:a=10.5330(11)?,b=10.6663(11)?,c=15.9751(16)?,α=82.090(2)°,β=71.193(2)°,γ=68.284(2)°andZ=2.ThefinalcycleofrefinementledtoR=0.057andRw=0.149.ThecrystalstructurewasstabilizedbyanextensivenetworkofN--H···Clandnon-classicalC--H···Clhydrogenbondsbetweenthecationandtheanionicgroup.Severalthermalanalysistechniquessuchasthermogravimetricanalysis,differentialscanningcalorimetricanalysisandevolvedgasanalysiswereused.Weusedisoconversionalkineticsmethodstodeterminethekineticsparameters.Weobservethatthedecompositionof[C_6H_7N_2O_2]_3TeCl_5·2Clentailstheformationhydrochloricacidofnitroanilineasvolatiles.Theinfraredspectrawererecordedinthe4000–400cm~(-1)frequencyregion.TheRamanspectrawererecordedintheexternalregionoftheanionicsublatticevibration50–1500cm~(-1).TheopticalbandgapwascalculatedfromtheUV-VisabsorbancespectrausingclassicalTaucrelationwhichwasfoundtobe3.12and3.67eV.