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199 个结果
  • 简介:SupposethatCisthecomplexplaneandkisanon-negativeinteger.DefinefunctionsNk-(x)=|x|kifkisevenandNk(x)=x|x|k-1ifkisodd.SomeapproximationpropertiesofNk-(x)’sisdiscussedandanewexampleofaTchebycheffsystemisgivenout.

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  • 简介:Polystyrenemacromonomerswithdifferentmolecularweightwerepreparedbyradicalpolymerizationofstyrene(St)inbenzeneusingβ-methacryloxylethyl2-N,N-diethyldithiocarbamylacetate(MAEDCA)asamonomer-iniferter.Characterizationofthemacromonomerby~1H-NMRshowedthattheendgroupswereα-methacrylyoxylethyloxycarbonyl-methylandω-(N,N-diethyldithiocarbamyl).Themacromonomerwasdifficulttohomopolymerize,butitwaseasilycopolymerizedwithmethylmethacrylate(MMA)initiatedbyAIBNtoformgraftcopolymers(PMMA-g-PSt)withPStbranchesrandomlydistributedalongthePMMAbackbone.CopolymerizationreactionandthestructureofthegraftcopolymerswerestronglyaffectedbyM_nandconcentrationofthemacromonomer.ThecompositionandM_nofthepurifiedgraftcopolymerweredeterminedby~1H-NMRandGPCanalysis.

  • 标签: Monomer-iniferter Photoiniferter MACROMONOMER Living radical POLYMERIZATION
  • 简介:AnewkindofpolysiloxanecontainingN,N’-bis(diphenylsilyl)tetraphenylcyclodisilazanewaspreparedbyanionicnon-equilibriumpolymerizationwitha"seedsolution"asinitiator.Themonomer,N,N’-bis(hydroxydiphenylsilyl)-tetraphenyl-cyclodisilazane(BHPTPC),wassynthesizedviathehydrolysisofN,N’-bis(chlorodiphenylsilyl)tetraphenyl-cyclodisilazane(BCPTPC).AnewmethodforthepreparationofBCPTPCisalsoreportedherewithhighyieldandsimplermanipulation.ThesynthesizedpolysiloxanecontainingN,N’-bis(diphenylsilyl)tetraphenylcyclodisilazanewascharacterizedby1H-NMR,29Si-NMR,gelpermeationchromatography(GPC)andintrinsicviscosity.

  • 标签: POLYSILOXANE N N’-Bis(diphenylsilyl)tetraphenylcyclodisilazane SYNTHESIS
  • 简介:ReactionsofCuSCNwithtetramethylthiuramdisulfideinCH3CNinthepresenceofstyreneandN,N,N',N',N'-pentamethyldiethylenetriaminegaverisetoanewcopper(Ⅰ)complexofN,N'-dimethyldithio-cabamate{[Cu(S2CNMe2)]2}n.ThetitlecompoundcrystallizedinthetriclinicP-1spacegroupwithlatticeparametersα=0.7610(4)nm,b=0.8911(4)nm,c=0.9268(5)nm,α=68.66(1)°,β=83.88(2)°,γ=79.31(2)°,V=0.5748(5)nm^3,Z=2.Thecompoundhasaunique1DchainstructurecomposedofCuSCSCuSCSeight-memberedringsandapairofCu-Sbonds,thestructureofwhichhasbeendeterminedbysingle-crystalX-raycrystallography.Theisolationofthiscompoundmayprovidesomehelpfulinformationforthecauseoftheinductionperiodsofthereverseatomtransferradicalpolymerization.

  • 标签: 合成 晶体结构 N N'-二甲基二硫代铜 反向原子转移聚合 硫氰酸铜
  • 简介:Aseriesofaromaticimineswerereducedtocorrespondingaminesinexcellentyieldsby2-phenyl-N,N-dimethylbenzimidazoline(PDMBI)photochemicallyinthepresenceofmagnesiumperchloride(Mg(ClO4)2).AMg2+mediatedphotoinducedelectrontransfermechanismwasproposed.

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  • 简介:Thetwocompounds,2,2-dimethyl-4-S-(N,N-dimethyldithiocarbamato)-5-(1,2,4-triazol-l-yl)-propione(1)and2,2-dimethyl-4-S-(N,N-diethyldithiocarbamato)-5-(1,2,4-triazol-1-yl)-3-propione(2),werepreparedbyreactingN,N-dialkyldithiocarbamatesodiumwith2,2-dimethyl-4-bromo-5-(1,2,4-triazol-1-yl)-propione.Theirstructureswereidentifiedbyelementalanalysis,IRand^1HNMRspectroscopy.Thestructureof1hasbeendeterminedbyX-raysinglecrystalstructureanalysis.ItcrystallizesinmonoclinicsystemwithspacegroupP21/c,a=1.2315(3)nm,b=1.2057(2)nm,c=1.2532(3)nm,β=118.55(3)°,Z=4,V=1.6345(6)nm^3,Dc=1.221g/cm^3,μ=0.324mm^-1,F(000)=640,finalR1=0.0449.ThereisobviouspotentiallyweakC—H...Nintermolecularinteractioninthecrystal,whichstabilizesthecrystalstructure.Theresultofthebiologicaltestshowedthatthetwocompoundshavefungistasisandplantgrowthregulatingactivities.

  • 标签: 合成 晶体结构 生物活性 三唑化合物 N N-烷基二硫代氨基甲酸酯 杀菌剂
  • 简介:<正>WeintroducecertainCalderón-Zygmund-typeoperatorsanddiscusstheirboundednessonspacessuchasweightedLebesguespaces,weightedweakLebesguespaces,weightedHardyspacesandweightedweakHardyspaces.Thesharpnessofsomeresultsisalsoinvestigated.

  • 标签: Calderón-Zygmund operator LEBESGUE SPACE WEAK LEBESGUE
  • 简介:Letr,1p={f:fr-1isabs.cont.onI=[a,b],fisperiodiewithperiodH(=b-a),f(x1)=0,‖f(r)‖p≤0},wherex1isanyfixedpointin[a,b].TheauthorfindstheKolmogorov,Gel’land,linear,andBerusteinn-widthsofr,1pinLp(I)fornodd,∞>p>1.Theoptimalsubspacesandoperatorsarealsofound.

  • 标签: operators KOLMOGOROV proof hereby VALUED 加名
  • 简介:ThepresentpaperdealswithfindingofconstantoccurringintheorderofapproximationofthefunctionofLipα(O<α<1)classbyusing(N,p)operator.Obviouslythefactor1/(1-α)becomeslargewhenαiscloseto1.Wehaveshowntheroleofthisfactorintheconstantofapproximation.

  • 标签: deals operators finding INTEGRABLE proof N p)OPERATOR
  • 简介:Inthispaper,alargeclassofndimensionalorthogonalandbiorthognalwaveletfilters(lowpassandhighpass)arepresentedinexplicitexpression.Wealsocharacterizeorthogonalfilterswithlinearphaseinthiscase.Someexamplesarealsogiven,includingnonseparableorhogonalandbiorthogonalfilterswithlinearphase.

  • 标签: 有限小波滤子 显式表示 正交滤子 线性相 双正交滤子
  • 简介:Wetrytoapplyaconstituentquarkmodel(avarietychiralconstituentquarkmodel)andtheresonatinggroupapproachforthemulti-quarkproblemstocomputetheeffectivepotentialbetweentheNN-inS-wave(thequarksinthenucleonsNandN-,andthetwonucleonsrelativelyaswell,areinSwave)soastoseethepossibilityiftheremaybeatightboundstateofsixquarksasindicatedbyastrongenhancementatthresholdofpp-inJ/ψandBdecays.TheeffectivepotentialwhichweobtainintermsofthemodelandapproachshowsiftheexperimentalenhancementisreallycausedbyatightS-waveboundstateofsixquarks,thenthequantumnumberoftheboundstateisverylikelytobeI=1,JPC=0-+.

  • 标签: 核子-反核子效应 多夸克系统 夸克成分模型 BES 高能物理学
  • 简介:Itisknownfromclassicaldifferentialgeometrythatonecanreconstructacurvewith(n-1)prescribedcurvaturefunctions,ifthesefunctionscanbedifferentiatedacertainnumberoftimesintheusualsenseandifthefirst(n-2)functionsarestrictlypositive.ItisestablishedherethatthisresultstillholdsundertheassumptionthatthecurvaturefunctionsbelongtosomeSobolevspaces,byusingthenotionofderivativeinthedistributionalsense.ItisalsoshownthatthemappingwhichassociateswithsuchprescribedcurvaturefunctionsthereconstructedcurveisofclassC∞.

  • 标签: 微分几何 非线性弹性 欧几里德空间 曲线 弱导出 Frenet方程
  • 简介:方案1:“窝里K”成本:一部CD机,一副嗓子总需经费:CD机+唱片卡担是条狗,当钱包开始瘪的时候,我们开始强烈赞同冯大导演这句话。个人演唱会不是明星的专利啊,

  • 标签: 穷开心方法
  • 简介:SOMEINTEGRALINEQUALITIESINNINDEPENDENTVARIABLESYANGENHAO(杨恩浩)(DepartmentofMathemattcs,JinanUniversity,Gnangzhou51O632,China)A...

  • 标签: INTEGRAL INEQUALITY volterra-type wendroff-type N-variable
  • 简介:Aggregationofsomenitrogen-containingheterocycliccompoundshavebeeninvestigatedbymeansoffluorescencespec-troscopyinaqueousoraquiorganobinarymixturesofdifferentΦvaluesforthefirsttime.TheaggregatorsstudiedareN-butylcarbazole(CBZ-4),N-octylcarbazole(CBZ-8),N-do-decylcarbazole(CBZ-12),andN-hexadecylcarbazole(CBZ-16).Theiraggregatingtendencieshavebeenevaluatedbymeasuringtheircriticalaggregateconcentrationvalues(CAgC’s).OurresultsindicatethattheN-alkylcarbazoles,justliketheanthracenederivativeswithdifferentchain-lengths,canalsobeusedasfluorescenceprobesforevaluatingaggregatingtendenciesorCAgCvalues.

  • 标签: AGGREGATION hydrophobic-lipophilic INTERACTION N- alkylcarbazoles