简介:Inthefarfieldoftheintensitydistributionofthebeamdeliveredbyatwo-stagetransient–collisionalexcitationX-raylaser(XRL),anon-expectedinterferencepatternthatisstablefromshottoshothasbeendiscovered.Itisdemonstratedthattheinterferenceiscausedbytheemergenceofanimaginarysourceintheamplifyingplasma,whichisphasematchedtotheradiationofthegenerator.TheobservedphenomenoniscalledanX-raycoherentmirage.Toexplaintheobtainedresults,anewtheoreticalapproachisdeveloped.ThebasicessentialconditionsforformationoftheX-raymirageareformulated,andpossibleapplicationsarediscussed.Thispaperdetailstheexperiments,includingtheformulationofthenecessaryandsufficientconditionsforformationoftheX-raymirage,andpossibleapplicationsarediscussed.
简介:QuantumdynamicscalculationsforthetitlereactionH(2S)+S2(X3-Σg)→SH(X2Π)+S(3P)areperformedbyusingagloballyaccuratedoublemany-bodyexpansionpotentialenergysurface[J.Phys.Chem.A1155274(2011)].TheChebyshevrealwavepacketpropagationmethodisemployedtoobtainthedynamicalinformation,suchasreactionprobability,initialstate-specifiedintegralcrosssection,andthermalrateconstant.Itisfoundnotonlythatthereisareactionthresholdnear0.7eVinbothreactionprobabilitiesandintegralcrosssectioncurves,butalsothatboththeprobabilityandcrosssectionincreasefirstlyandthendecreaseasthecollisionenergyincreases.Theexistenceoftheresonancestructureinboththeprobabilityandcrosssectioncurvesisascribedtothedeeppotentialwell.Thecalculationoftherateconstantrevealsthatthereactionoccurringonthepotentialenergysurfaceoftheground-stateHS2isslowtotakeplace.
简介:Veryrecently,BelleannouncedtheirobservationofΥ(5S)!bJ!(J=0;1;2),indicatingthattheΥ(5S)!bJ!decaysalsohavelargedecaywidths,i.e.,themeasuredbranchratiosofΥ(5S)!bJ!are<3:410??3,(1:640:23+0:30??0:22)10??3,and(0:570:220:07)10??3withJ=0;1;2,respectively[1].ItshouldbenoticedthateventhoughthetreelevelcontributionstoΥ(5S)!bJ!(J=0;1;2)shouldbestronglysuppressedduetotheOkubo-Zweig-Iizuka(OZI)rule,suchlargedecaywidthsareobserved,whichagaininspiresourinterestinunderstandingsuchquantities.Inthiswork,weproposethatthecontributionfromthehadronicloopshouldbeconsideredinstudyingΥ(5S)!bJ!.
简介:Zr1-xTixCo(x=0,0.1,0.2,0.3)alloyswerepreparedbyarc-meltingmethodandtheeffectofTisubstitutiononhydrogenstoragepropertieswasstudiedsystematically.Hydrogendesorptionpressure-composition-temperature(PCT)measurementswerecarriedoutusingSievert’stypevolumetricapparatusforZrCo(at473K,573Kand673K)andZr1-xTixCoalloys(at673K),respectively.ProductsafterdehydrogenationwerecharacterizedbyX-raydiffraction(XRD).Inaddition,thekineticsofZr1-xTixCohydridewasinvestigatedat473Kand673K,respectively,underhydrogenpressureof5MPa.ResultsshowedthatTisubstitutionforZrdidnotchangethecrystalstructureofZrCophase.Withtheincreaseoftemperaturefrom473Kto673K,theextentofdisproportionationforZrCoalloyincreased.WithTicontentincreasingat673K,thedesorptionequilibriumpressureofZr1-xTixCo-H2systemselevatedandthedisproportionationreactionofZr1-xTixCoalloyswasinhibitedeffectively.TisubstitutiondecreasedthekineticsrateandtheeffectivehydrogenstoragecapacityofZr1-xTixCoalloysslightly.Generallyspeaking,itwasfoundthatZr0.8Ti0.2Coalloyhadbetteranti-disproportionationpropertywithlessdecreaseofeffectivehydrogenstoragecapacitywhichwasbeneficialtotritiumapplicationintheInternationalThermonuclearExperimentalReactor(ITER).
简介:目前,国内没有关于半钢发热剂的国家标准检测方法,只能根据组分范围分别检测各个组分,不仅耗时而且使用的大量化学试剂对环境造成污染。故研究了X-射线荧光光谱法快速测定半钢发热剂中Si,P,S的方法。采用粉末压片制样,研究其制样条件,包括磨样时间、压样时间和压力对测定结果的影响。采用其它方法定值提供的检测样品,作为x-射线荧光光谱法内控标准样品,采用经验系数法进行基体校正,通过解谱拟合建立校准曲线,校准曲线建立后仪器建立漂移校正程序。实验结果精密度好,各元素的相对标准偏差在0.15%-1.3%。准确度满足生产需求,实验方法可用于快速检测半钢发热剂化学组分。
简介:利用自主开发的热管蒸汽流动计算程序SNPS-HPD对HP-STMCs堆堆芯锂热管和辐射散热器钾热管稳态运行时的性能参数进行了分析计算,得到了不同运行条件下锂热管和3类散热器钾热管内部蒸汽流动的压强、温度、速度和流动马赫数分布情况。结果表明:堆芯锂热管内部蒸汽压力和温度在蒸发段均有较大下降,在绝热段呈线性下降,而在冷凝段有一定的回升。锂热管温降主要为内部蒸汽的温降,且蒸汽温降随输出功率的增加而减小;蒸汽轴向马赫数在绝热段出口处达到最大,且随输出功率的增大而减小;辐射散热器钾热管具有良好的等温性,但热管绝热段的设计增加了热管蒸汽的温降,破坏了热管的等温性。
简介:采用熔融片制样用X射线荧光光谱法对陶瓷、色料和釉物料中Na,Mg,A1,Si,P,S,K,Ca,Ti,Mn,Fe,Ba,Zr,Zn,Hf15种元素进行了测定,用理论α系数校正基体效应.方法简便、快速、分析结果的准确度完全能满足上述物料分析的要求.还用纯化学试剂和标准样品按一定比例混合制备标准样品,弥补了色料和釉缺少标准或没有标样的困难.又对Zr和Hf元素分析线进行了选择,用ZrLα和HfLβ1作为分析线,而不采用ZrKα,不仅使制备的熔片达到ZrLα线的饱和厚度,使分析结果的准确度和重现性好,而且还消除了ZrKα的谱线对HfLβ1分析线的干扰.