简介：TheeffectofacidcomponentincludingvariousconventionalacidsandtungsticcompoundsonglucosehydrogenationoveraseriesofbinarycatalystsystemcontainingRu/Ccatalystwasinvestigated.TheresultsshowedthatHCl,H2SO4,H3BO3,H3PO4,andHNO3hadnegligibleeffect,whileallthetungsticcompoundsimposedinhibitingeffectsonthehydrogenationofglucoseoverRu/Ccatalyst,andthesuppressingeffectfollowedtheorderofH2WO4>HPW>WO3>AMT>HSiW.Thisorderisthesameastheorderofethyleneglycol(EG)yieldsintheone-potconversionofglucosetoEG,suggestingtheimportantroleofcompetitionbetweenglucosehydrogenationandretro-aldolcondensationincontrollingtheselectivityofEG.

简介：Thewell-distributionspindleLiFePO4(LFP)nanoparticlesascathodeoflithiumsecondarybatteriesweresynthesizedbyasolvothermalreactionrouteatlowtemperature(180°C)inwhichtheascorbicacidwasusedasreducingagent.InordertoguaranteethatthepHvaluesofthermalsystemswerenotaffectedtoomuchandthereducibilityofthesystemwasenhancedatthesametime,glucosewaschosenasanauxiliaryreductantinthisreaction.TheobtainedpowderswerecharacterizedbyX-raydiffraction(XRD),scanningelectronmicroscopy(SEM),andlaserparticleanalyzer.Theresultsshowthatthecarbon-coateduniformspindleolivineLiFePO4/C-glucoseparticles(glucoseasauxiliaryreductant,LFP/C-G)arepreparedwiththesize500–600nmandwithoutanyimpurityphases.Theirelectrochemicalpropertieswereevaluatedbyelectrochemicalimpedancespectroscopy,cyclicvoltammetry,andgalvanostaticcharge/dischargetests.LFP/C-Ghasahigherconductivityandbetterreversiblecapabilitythancarbon-coatedLFP(LFP/C).ThehighestdischargecapacityofLFP/C-Gis161.3mAh·g-1at0.1Cand108.6mAh·g-1at5.0C,respectively.TheresultsimplythattheneatcrystalnanostructureofLFP/C-Ghasexcellentcapacityretentionandcyclingstability.Theaddingofglucoseisthekeyfactorforthewelldistributionandneatcrystalstructureofnanoparticles,thustheelectrochemicalperformancesofmaterialsareimproved.

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