简介:ResultsofinelasticneutronscatteringexperinientsandabinitiomoleculardynamicssimulationsforGeTe一theparentcompoundofphase-changematerialsarereported.TheinelasticneutronspectraofGeTepowdersampleshavebeendeterminedinthetemperaturerangeextendingfrom300to700K.Thephononpeaksundergothermalshiftsresultingfromanharmoniceffectsbeingweakerforacousticthanopticmodes.AsmallconcentrationoffreechargecarriesarisingfromthepresenceofGe-vacancieswasfoundnottoaffectsignificantlytheneutronweightedphonondensitiesofstatesofGeTe.Thespectralpatternchangesqualitativelyacrossthestructuralphasetransition,butthelocalstructureofGeTeremainshardlyaffected,asconfirmedbytheanalysisoftemperaturedependenceofthepairdistributionfunctionobtainedfromabinitiomoleculardynamicsinvestigations.Thepresenttheoreticalstudiessupportinawideextentourexperimentalobservationsandalsothoseprovidedbylocalprobemethods.
简介:Atunableplasmonicperfectabsorberwithatuningrangeof650nmisrealizedbyintroducinga20nmthickphase-changematerialGe2Sb2Te5layerintothemetal–dielectric–metalconfiguration.Theabsorptionattheplasmonicresonanceiskeptabove0.96acrossthewholetuningrange.Inthisworkwestudythisextraordinaryopticalresponsenumericallyandrevealthegeometricconditionswhichsupportthisphenomenon.Thisworkshowsapromisingroutetoachievetunableplasmonicdevicesformulti-bandopticalmodulation,communication,andthermalimaging.
简介:Wenumericallydemonstrateanovelultra-broadbandpolarization-independentmetamaterialperfectabsorberinthevisibleandnear-infraredregioninvolvingthephase-changematerialGe2Sb2Te5(GST).Thenovelperfectabsorberschemeconsistsofanarrayofhigh-indexstrong-absorbanceGSTsquareresonatorsseparatedfromacontinuousAusubstratebyalow-indexlosslessdielectriclayer(silica)andahigh-indexGSTplanarcavity.Threeabsorptionpeakswiththemaximalabsorbanceupto99.94%areachieved,owingtotheexcitationofplasmon-likedipolarorquadrupoleresonancesfromthehigh-indexGSTresonatorsandcavityresonancesgeneratedbytheGSTplanarcavity.Theintensitiesandpositionsoftheabsorptionpeaksshowstrongdependenceonstructuralparameters.AheattransfermodelisusedtoinvestigatethetemporalvariationoftemperaturewithintheGSTregion.TheresultsshowthatthetemperatureofamorphousGSTcanreachupto433Kofthephasetransitiontemperaturefromroomtemperatureinjust0.37nswitharelativelylowincidentlightintensityof1.11×108W∕m2,duetotheenhancedultra-broadbandlightabsorbancethroughstrongplasmonresonancesandcavityresonanceintheabsorber.Thestudysuggestsafeasiblemeanstolowerthepowerrequirementsforphotonicdevicesbasedonathermalphasechangeviaengineeringultra-broadbandlightabsorbers.
简介:做Si的Ge(2)sb(2)Te(5)电影被dc劈啪作响magnetronco与Ge2Sb2Te5和Si目标准备了。在在两结晶化温度和阶段转变温度fromface-centred-cubic(fcc)的增加的Te(5)电影结果分阶段执行到的Ge(2)sb(2)的Si的增加六角形(十六进制)阶段。Ge2Sb2Te5电影的抵抗力显示出重要增加,Si做。当在这部电影做Si的11.8at.%时,在退火的460度C以后的抵抗力与undopedGe2Sb2Te5电影相比从64~99终止从1~11m终止(.)厘米和动态抵抗增加增加。这对写阶段变化随机存取记忆的当前的减小很有用。
简介:Thisworkbrieflysummarizedtherecentresearcheffortsmadeonthephaseheattransferprocessesinvolvingbiologicalaggregates,withparticularattentiononthecorrelationofaggregatestructureandstateofwaterwiththeprocessefficiency.Thephasechangeprocessesincludeboiling,drying,freezing,sintering,pyrolysis,andsupercriticalextraction,whiletheformerthreewerediscussedinsomedetail.
简介:Anewcompositioncontentquaternary-alloy-basedphasechangethinfilm,Sb-richAglnSbTe,hasbeenpreparedbyDC-magnetronsputteringonaK9glasssubstrate.Afterthefilmhasbeensubsequentlyannealedat200℃for30min,itbecomesacrystallinethinfilm.Thediffractionpeakofantimony(Sb)areobservedbyshallow(0.5degree)x-raydiffractioninthequaternaryalloythinfilm.Theanalysesofthemeasurementfromdifferentialscanningcalorimetry(DSC)showthatthecrystallizationtemperatureofthephasechangethinfilmisabout190℃andincreaseswiththeheatingrate.ByKissingerplot,theactivationenergyforcrystallizationisdeterminedtobe3.05eV.Thereflectivity,refractiveindexandextinctioncoefficientofthecrystallineandamorphousphasechangethinfilmsarepresented.Theopticalabsorptioncoefficientofthephasechangethinfilmsasafunctionofphotonenergyisobtainedfromtheextinctioncoefficient.Theopticalbandgapsoftheamorphousandcrystallizationphasechangethinfilmsare0.265eVand1.127eV,respectively.
简介:ZrO2nanopowdersbasedstearicacidphasechangematerials(PCMs)werepreparedbyhigh-energymilling.Theconceptofheatcapacityfactor(HCF)wasusedtoanalyzethethermalpropertiesofthematerials.TheheatstoragepropertyofPCMs,containingthesamecontentofstearicacid(23%bymass)inthestartingmaterialsbutsynthesizedbydifferenttechnicalprocesses,wasinvestigatedbyusingHCF.Itwasfoundthattherewerevastinfluencesofdifferentdispersantsontheheatcapacity.Thesamplespreparedwithchloroformprovidedthebestheatstorageabilityinallsamplestested.
简介:High-temperaturePhaseChangeMaterial(PCM)isusedasathermalstoragemediumofaheat-pipereceiverinanadvancedsolardynamicsystem.Withbothvoidcavityandnaturalconvectionconsidered,thermalperformanceoftheheat-pipereceiverisnumericallyanalyzedundergravity.TheresultsindicatethatthePCMcontainedintheintegratedheatpipeperformsanaveragingfunctionofheatloadings.Thethermalperformanceoftheheat-pipereceiverisstableandreliable.Whenaheatingcycleisstable,thetemperaturefluctuationsbothonheat-pipewallandinPCMcanisterremainlessthan13Kthroughoutasunlightandeclipsecycle.TheutilityofPCMisessentiallyimproved.ThemaximummeltingratioofPCMis92%.Undergravity,PCMmeltsmorequicklywiththeeffectofnaturalconvection.Naturalconvectionacceleratestheprocessofphasechanges.Numericalresultsarecomparedwiththeexperimentalresultsconcerned.Theaccuracyofnumericalmodelundergravityisverified.TheexperimentforthePCMcanisteronthegroundcanbewellpreparedwithournumericalsimulation.
简介:Anewpotassiumnitrate(KNO_3)/diatomiteshape-stabilizedcompositephasechangematerial(SSCPCM)waspreparedbythemixingandsinteringmethod.KNO_3servedasthephasechangematerial(PCM)forthermalenergystorage,whilediatomiteactedasthecarriermatrixtoprovidethestructuralstrengthandpreventtheleakageofPCM.ItwasfoundthatKNO_3couldberetained65wt%intoporesandonsurfacesofdiatomitewithouttheleakageofmeltedKNO_3fromtheSS-CPCM.ThecalculatedfillingrateofmoltenKNO_3thatcouldenterintothedisc-likeshapeporeofdiatomiteverifiedthescanningelectronicmicroscopyimagesofSS-CPCM.X-raydiffractionandFouriertransforminfraredspectroscopyresultsshowedthatnoreactionoccurredbetweenKNO_3anddiatomite,performinggoodcompatibility.Accordingtothedifferentialscanningcalorimetryresults,after50thermalcycles,thephasechangetemperaturesformeltingandfreezingofSS-CPCMwith65wt%KNO_3werechangedfrom330.23°Cand332.90°Cto330.11°Cand332.84°Candcorrespondinglatentheatsvariedfrom60.52J/gand47.30J/gto54.64J/gand41.25J/g,respectively.TheKNO_3/diatomiteSS-CPCMmaybeconsideredasapotentialstoragemediainsolarpowerplantsforthermalenergystorage.
简介:ThisArticlepresentsathreedimensionalnumericalmodelinvestigatingthermalperformanceandhydrodynamicsfeaturesoftheconfinedslotjetimpingementusingslurryofNanoEncapsulatedPhaseChangeMaterial(NEPCM)asacoolant.Theslurryiscomposedofwaterasabasefluidandn-octadecaneNEPCMparticleswithmeandiameterof100nmsuspendedinit.AsinglephasefluidapproachisemployedtomodeltheNEPCMslurry.ThethermophysicalpropertiesoftheNEPCMslurryarecomputedusingmodernapproachesbeingproposedrecentlyandgoverningequationsaresolvedwithacommercialFiniteVolumebasedcode.TheeffectsofjetReynoldsnumbervaryingfrom100to600andparticlevolumefractionrangingfrom0%to28%areconsidered.ThecomputedresultsarevalidatedbycomparingNusseltnumbervaluesatstagnationpointwiththepreviouslypublishedresultswithwaterasworkingfluid.ItwasfoundthataddingNEPCMtothebasefluidresultswithconsiderableamountofheattransferenhancement.ThehighestvaluesofheattransfercoefficientsareobservedatH/W=4andC_m=0.28.However,duetothehigherviscosityofslurrycomparedwiththebasefluid,theslurrycanproducedrasticincreaseinpressuredropofthesystemthatincreaseswithNEPCMparticleloadingandjetReynoldsnumber.
简介:OnOctober1,wecelebratedour55thNationalDay.Inthepast55years,ongoingpovertyeradicationhasbeenamajoraspectofChina'ssteadydevelopment.ThisisapparentinareasasdiverseasXinjiang,ethnicautonomousregionsintheNorthwest,andFoshanCity,asmallbutdevelopedcityinGuangdongProvince,SouthChina.Bothbearwitnesstoremarkablechanges.
简介:Inthispaper,aWindDirectionChangeIndex(WI),whichcandescribefour-dimensionalspatiotemporalchangesoftheatmosphericcirculationobjectivelyandquantitatively,isdefinedtostudyitsevolutionandseasonalvariation.ThefirstfourmodescanbeobtainedbyEOFexpansionofthezonallyaveragedWI.ThefirstmoderevealsthebasicspatialdistributionoftheannuallyaveragedWI.Thesecondmodereflectsthequasi-harmonicpartsoftheWIdeviations.Tropical,subtropicalandextratropicalmonsoonareascanbeclearlyreflectedbythismode.Thethirdmodereflectsthenon-harmonicpartsoftheWIdeviations.Itshowstheso-calledFebruaryreverseinstratosphericatmosphereaswellastheasymmetricseasonalchangesfromspringtofallandfromfalltospringduetoboththeland-seadistributioncontrastbetweentheNorthernandSouthernHemispheresandthenonlineareffectofatmosphericandoceanfluids.Thefourthmoderevealsthenorthwardadvancingoftheglobalreversedwindfieldsfromspringtosummerandtheirsouthwardwithdrawalfromsummertoautumn.