简介:Beforeintruding,primarymagmashaveundergoneliquationandpartialcrystallizationatdepth;asaresultthemagmasarepartitionedintobarrenmagma,ore-bearingmagma,ore-richmagmaandoremagma,whichthenascendandareinjectedintothepresentlocationsonceormultipletimes,thusformingoredeposits.Theabove-mentionedmineralizingprocessisknownasdeep-seatedmagmaticliquation-injectionmineralization.Thevolumeofthebarrenmagmaisgenerallymuchlargerthanthoseoftheore-bearingmagma,ore-richmagmaandoremagma.Intheascendingprocess,mostofthebarrenmagmaintrudesintodifferentlocationsoroutpoursontothegroundsurface,formingintrusionsorlavaflows.Therestbarrenmagma,ore-bearingmagma,ore-richmagmaandoremagmamayeithermultipletimesinjectintothesamespaceinwhichrocksandoresareformedorseparatelyinjectintodifferentspacesinwhichrocksandoresareformed.Theintrusionscontainingsuchdeep-seatedmagmaticliquation-injectiondepositshaveamuchsmallervolume,greaterorepotentialandhigheroregradethanthatofin-situmagmaticliquationdeposits.Consequentlythismineralizingprocessresultsintheformationoflargedepositsinsmallintrusions.
简介:Afacileandefficientstrategywasreportedforthepreparationofgraphenenanosheets-Ag2Shybridbyasimplehydrothermalprocess.First,Ag2Sparticlesdepositedonthesurfaceofgrapheneoxide(GO)sheet.GOwasthenreducedbyhydrazinehydratetographene.TheresultsofX-raydiffraction(XRD)andFouriertransforminfrared(FTIR)demonstratedtheefficientreductionofGOtographene.Transmissionelectronmicroscopy(TEM)imageofthesamplerevealsthemorphologyofthearchitectureofgraphene-Ag2Shybrid.Ultraviolet-visiblespectroscopy(UV-Vis)andphotoluminescence(PL)measurementwerefurtheremployedtostudytheopticalpropertiesoftheobtainednanocomposite.Thisworkcanbeextendedtodesignothergraphene-basedhybridnanomaterials,andtheas-grownarchitecturesmayholdpromiseformanyapplications.
简介:ApreliminaryorganicgeochemicalstudyshowsthatthesulphideoresfromthehydrothermaldepositoftheOkinawaTrougharegenerallylowinthetotalorganiccarbonandextremelylowinthesolubleorganicmatter.Inthealiphatichydrocarbonfraction,then-alkanesrangefromC15toC35,withusualmaximainthemiddlen-C20regionandstrongodd-carbonnumberpredominancewhenn>C25(CPI=1.2).Thedominantanaloginthearomaticfractionisphenanthrene,apolynucleararomatichydrocarbon,whichprovidesevidenceforhydrothermalactivity.Theorganicmatterderivedmainlyfrommarineplanktonicandterrigenousvascularplantsisentrappedinahigh-temperatureregimesuchasanactivechimneyandcooledquicklyinthesulphideoresontheseafloor.Organicmatterandsulphidesaredefinitelyproductsofahigh-temperaturealteration.ThebiomarkercompoundsindicatethattheoresareformedunderlowEhandpHconditions梐reducingtoanoxicenvironment,whichisfavourableforsulphatestobereducedintosulphidesbybiogenic(bacterial)orabiogenicactivity.
简介:Akindofsulphide,CaS:Eu2+,activatedbyeuropiumionforwhiteLEDlightingwassynthesizedviasolid-statereactionrouteinreducingatmospheres.Thephosphorswerethenencapsulatedwithsiliconeresin.Moreover,chemicalstructureofthephosphorswascharacterizedbyXRD.MicrostructureofthepowderswasobservedbySEM.Spectraofexcitationandemissionforthephosphorswerealsoobtainedbyaspectrophotometer.Effectofprocessingparametersontheluminescentpropertiesofthepowderswassystematicallystudiedtoresultinthephosphorswithgoodchemicalstabilityandmaximalrelativeluminescentintensity.
简介:AsymplectiteofpyriteandmagnetiteinthemassivesulphideoreoftheMashanmine,AnhuiProvince,isinterpretedtohavebeenformedbytheirreplacingearlierpyrrhotite.Thecompositionsofpyrrhotite,pyriteandmagnetiterelatedtothistexturearegivenbyelectronmicroprobeanalysis.Suchatextureislikelytobeformedwhentheore-formingsystemreachesthethree-phasepointofpyrrhotite,pyriteandmagnetitefromthepyrrhotitestabilityfield.Theverysmallprobabilityforthesystemtoreachthispointcouldbeusedtoaccountfortherareoccurrenceofsuchsymplectiteinnaturalores.
简介:Adistinctred-shiftto660nm-featuredlongerwavelengthofeuropiumdopedcalciumsulphidenanocrystalswasobservedinamicrowave(MW)-assistedsolvothermalsynthesisprocedure.Thisred-shiftwasprobablyduetoacombinedeffectfromMg2+codopingandstrainaccumulationatgrainboundaries.Thelatteroriginatedfromtheformationofsmallgrainswithanaveragesizeofaround200nminmicrometersizedcrystalsuponMg2+codoping.Inparticular,MWelectromagneticfieldsuppressedgraingrowthandenabledareconstructionofatomsattheinnergrainboundaryatwhichthefieldstrengthwasintensifiedaroundrareearthionsinhostlattices.ThisMWsynthesisrouteprovidedanoptiontoprepareluminescentcrystalswiththedesiredblue-excitablelongerwavelengthemission.
简介:Pressuresolutionisacommonphenomenoninmassivesulphidezinc-leaddepositsofwesternCanadaandmayhavebeenanimportantfactorleadingtothemobilizationofore-formingmaterialsduringdiagenesis,deformationandmetamorphismofsedimentaryores.Thecontrolofductileshearzonesovergoldmineralizationcouldbeexplainedinviewofpressuresolutionofgold-bearingminer-alsundershearingstressandthetesultantmobilizationofthismetal.
简介:Voluminousplatinum-groupmineral(PGM)inclusionsincludingerlichmanite(Os,Ru)S2,laurite(Ru,Os)S2,andirarsite(Ir,Os,Ru,Rh)AsS,aswellasnativeosmiumOs(Ir)andinclusionsofbasemetalsulphides(BMS),includingmillerite(NiS),heazlewoodite(Ni3S2),covellite(CuS)anddigenite(Cu3S2),accompaniedbynativeiron,havebeenidentifiedinchromititesoftheZedangophiolite,Tibet.ThePGMsoccurasbothinclusionsinmagnesiochromitegrainsandassmallinterstitialgranulesbetweenthem;mostarelessthan10μminsizeandvaryinshapefromeuhedraltoanhedral.Theyoccureitherassingleorcomposite(biphaseorpolyphase)grainscomposedsolelyofPGM,orPGMassociatedwithsilicategrains.Os-,Ir-,andRu-richPGMsarethecommonspeciesandPt-,Pd-,andRh-richvarietieshavenotbeenidentified.SulfurfugacityandtemperatureappeartobethemainfactorsthatcontrolledthePGEmineralogyduringcrystallizationofthehostchromititeintheuppermantle.Iftheactivityofchalcogenides(suchasS,andAs)islow,PGEclusterswillremainsuspendedinthesilicatemeltuntiltheycancoalescetoformalloys.Underappropriateconditionsof?S2and?O2,PGEalloysmightreactwiththemelttoformsulfides-sulfarsenides.Thus,wesuggestthattheOs,IrandRumetallicclustersandalloysintheZedangchromititescrystallizedfirstunderhightemperatureandlow?S2,followedbycrystallizationofsulphidesofthelaurite-erlichmanite,solid-solutionseriesasthemagmacooledand?S2increased.TheabundanceofprimaryBMSinthechromititessuggeststhat?S2reachedrelativelyhighvaluesduringthefinalstagesofmagnesiochromitecrystallization.ThediversityofthePGEminerals,incombinationwithdifferencesinthepetrologicalcharacteristicsofthemagnesiochromites,suggestdifferentdegreesofpartialmelting,perhapsatdifferentdepthsinthemantle.Theestimatedparentalmagmacompositionsuggestsformationinasuprasubductionzone