简介:Highlyefficientsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitehadbeensuccessfullysynthesizedbyastandardhydrothermalmethod.Theadditionofassistantreagentinthehydrothermalsystemispromisingtoobtainspecialmorphology.Theassistantreagent(EDTA)actsasagrowthmodifierofcrystal.Thepossibleformationmechanismsofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeolitewereschematicallydiscussed.Adetailedstudyofsheet-likeBiPO4/zeoliteandball-flower-likeBiPO4/zeoliteimpactedonthephotodecolorationmethyleneblue(MB)solutionshowedthatthecompositehadahighlyreusableandstablepropertyforlong-runphotocatalyticapplication.
简介:TheGroupofEnergyMaterials(GEM)inIMPisengagedintheirradiationresponseofmaterialscandidatetoadvancednuclearenergysystems(GenIV,fusionreactors).Themajorprogressofresearchinourgroupin2016isintheirradiationhardening/embrittlementofoxide-dispersion-strengthened(ODS)ferriticsteelsandVanadiumalloys,andinthemechanismsunderlyingdamageproductioninsiliconcarbide(SiC)fibers.Abriefdescriptionisgivenasfollows.1.EffectoftheoxidenanoparticlesontheirradiationhardeningofODSferriticsteelsTheinfluenceofoxidenanoparticlesontheirradiationresistanceofODSferriticsteelsisacrucialissuefortheupgradeofODSsteels.
简介:Asafundamentalpropertyofnuclei,atomicmassesarewidelyusedinmanydomainsofscienceandengineering.Areliableatomicmasstablederivedfromtheexperimentaldata,wheretheatomicmassesandtherelevantexperi-mentalinformationcanbefoundconveniently,isinhighdemandbytheresearchcommunity.Tomeetthedemands,theAtomicMassEvaluation(AME)wasinitiatedin1950'sandaseriesofAMEmasstableshavebeenpublishedeversince.CurrentlytheAMEservestheresearchcommunitybyprovidingthemostreliableandcomprehensiveinformationrelatedtotheatomicmasses.ThenewatomicmassevaluationAME2016waspublishedintheMarchissueofChinesePhysicsCastwocom-plementarypapers[1;2].
简介:Poly(β-carboxyethylmethylsiloxane)-LiClO4andpoly(β-alkoxylethylmethylsiloxane)-LiClO4crosslinkedfllmshavebeenprepared.Theionicconductivityofthefilmsdependsonthepolymerspecies,concentrationoflithiumperchlorate,temperatureandcontentofcrosslinkingagent.Theeffectofhighpolarorganicsolvent1,4-butyrolactoneontheionicconductivityandmechanicalpropertiesofpoly(β-carhoxyethylmethylsiloxane)-LiClO4systemwasalsoinvestignied.
简介:Ionicconductivityvaluesforsegmentedpolyetherpolyurethaneurea(PEUU)complexeswithLiClO4weredeterminedandvaluesashighas~1.1×10-4S·cm-1at353Kand~1.0×10-5S·cm-1at306Kwereachieved.TheionicconductivitydatawereanalyzedusingtheVTF(Vogel-Tamman-Fulcher)equationandWLF(Williams-Landel-Ferry)typeequation.Valueshavebeenestimatedforthe"apparent"activationenergiesofiontransportfromVTFequationandtheylieintherange2.70—5.53kJ·mol-1.
简介:Anovelseriesofcalix[4]azacrownderivativeswiththereactionbetweencalix[4]azacrownandthedifferentfluorophorederivatives,whichmaybeusefulfluorescentreceptors,havebeensynthesizedandstructurallycharacterizedbyIR,~1HNMR,~(13)CNMRandMS.Fromtheiranalysisdata,itwasfoundthosecompoundsadoptedaconeconformation.
简介:Anovelquaternarymetalselenide,K_2CdSnSe_4,wassynthesizedviaamolten-saltreactionat550℃.Thecompoundhasaone-dimensionalstructurecontainingachainof_∞~1[CdSnSe_4]~(2-)anionsseparatedbyK~+cations.ThecrystalbelongstothespacegroupI-42m,withtheunitcellparametersa=0.80298(11)nm,b=0.80298(11)nm,c=0.69217(14)nm,α=β=γ=90°.Areflectancespectroscopystudyrevealsthenatureofthesemiconductorwithanenergygapof1.7eVforthecompoundandithasastrongopticalabsorptioninarangeof2—5eV.
简介:Assumethatm≥2,pisaprimenumber,(m,p(p-1))=1,-1(Z/mZ)~*and[(Z/mZ)~*:]=4.Inthispaper,wecalculatethevalueofGausssumG(X)=Σ_(x∈F_q~*)x(x)ζ_p~(T(x))overF_q,whereq=p~f,f=((m))/4xisamultiplicativecharacterofF_qandTisthetracemapfromF_qtoF_p.Underourassumptions,G(x)belongstothedecompositionfieldKofpinQ(ζm)andKisanimaginaryquarticabeliannumberfield.WhentheGaloisgroupGal(K/Q)iscyclic,wehavestudiedthiscycliceaseinanotherpaper:'Gausssumsofindexfour:(1)cycliccase'(acceptedbyActaMathematicaSinica,2003).Inthispaperwedealwiththenon-cycliccase.
简介:At-hyperwheel(t≥3)oflengthl(orW(t)lforbrevity)isat-uniformhypergraph(V,E),whereE={e1,e2,...,el}andv1,v2,...,vlaredistinctverticesofV=∪eii=1lsuchthatfori=1,...,l,vi,vi+1∈eiandei∩ej=P,j∈/{i1,i,i+1},wheretheoperationonthesubscriptsismodulolandPisavertexofVwhichisdifferentfromvi,1≤i≤l.Inthispaper,theminimumcoveringproblemofMCλ(3,W(3)4,v)isinvestigated.DirectandrecursiveconstructionsonMCλ(3,W(3)4,v)arepresented.Thecoveringnumbercλ(3,W(3)4,v)isfinallydeterminedforanypositiveintegersv≥5andλ.
简介:SYNTHESIS AND 183W NMR CHARACTERIZATION OF P4W30Al4(H2O)2O11220- HETEROPOLYANIONSYNTHESISAND183WNMRCHARACTERIZ?..
简介:Tostudytheelectromagnetic(EM)backscattercharacteristicsoffreakwavesatmoderateincidenceangles,weestablishanEMbackscatteringmodelforfreakwavesin(1+1)-dimensionaldeepwater.ThenonlinearinteractionbetweenfreakwavesandBraggshortwavesisconsideredtobethebasichydrodynamicspectramodulationmechanisminthemodel.NumericalresultssuggestthattheEMbackscatteringintensitiesoffreakwavesarelessthanthosefromthebackgroundseasurfaceatmoderateincidenceangles.Thenormalisedradarcrosssections(NRCSs)fromfreakwavesarehighlypolarisationdependent,evenatlowincidenceangles,whichisdifferentfromthesituationfornormalseawaves;moreover,theNRCSoffreakwavesismorepolarisationdependentthanthebackgroundseasurface.NRCSdiscrepanciesbetweenfreakwavesandthebackgroundseasurfacewithusinghorizontaltransmittinghorizomtal(HH)polarisationarelargerthanthoseusingverticaltransmittingvertical(VV)polarisation,atmoderateincidentangles.NRCSdiscrepanciesbetweenfreakwavesandbackgroundseasurfacedecreaseswiththeincreaseofincidenceangle,inbothHHandVVpolarisationradars.Asanapplication,inthesynthetic-apertureradar(SAR)imagingoffreakwaves,wesuggestthatfreakwavesshouldhaveextremelylowbackscatterNRCSsforthefreakwavefacetwiththestrongestslope.Comparedwiththebackgroundseasurface,thefreakwavesshouldbedarkerinHHpolarisationechoimagesthaninVVechoimages,inSARimages.FreakwavescanbemoreeasilydetectedfromthebackgroundseasurfaceinHHpolarisationimagesthaninVVpolarisationimages.Thepossibilityofdetectionoffreakwavesatlowincidenceanglesismuchhigherthanathighincidenceangles.
简介:Wehavesuccessfullysynthesized1-(2′-Phenyl)cycloproply1-2,3-epoxypropan-1-ol3,whichwillbeappliedtothekineticsstudyofoxiranylcarbinylradical.
简介:SINGULARITYANDQUADRATUREREGULARITYOF(0,1,...,m-2,m)─INTERPOLATIONONTHEZEROSOF(1-x)Pn-1αβ(x)ShiYingguang(史应光)(ComputingCe...
简介:ThesplittingofpotentialenergylevelsforgroundstateX2ΠgofOx2(x=+1,1)underspin–orbitcoupling(SOC)hasbeencalculatedbyusingthespin–orbit(SO)multi-configurationquasi-degenerateperturbationtheory(SO-MCQDPT).TheirMurrell–Sorbie(M–S)potentialfunctionsaregained,andthenthespectroscopicconstantsforelectronicstates2Π1/2and2Π3/2arederivedfromtheM–Sfunction.TheverticalexcitationenergiesforOx2(x=+1,1)areν[O+12(2Π3/2→X2Π1/2)]=195.652cm1,andν[O12(2Π1/2→X2Π3/2)]=182.568cm1,respectively.Allthespectroscopicdataforelectronicstates2Π1/2and2Π3/2aregivenforthefirsttime.