学科分类
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491 个结果
  • 简介:Aconvenient,environmentallybenign,andhighlyefficientprotocolforthepreparationofN-aryl-hydroxylaminesfromthecorrespondingnitroarenesinaZn/HCOONH4/CH3CNsystemunderultrasoundisdescribed.Theadvantagesofthepresentmethodincludehighchemoselectivity,simpleandpracticalwork-upprocedureandhighyield.

  • 标签: 超声波 化学选择性 环境友好 议定书
  • 简介:WesuggesttwoschemestogeneratetheWstateofNA-typethree-levelatoms.Intheschemes,identicalNthree-levelatomsaretrappedinacavityorNdistantcavities.ThesuccessorfailureofthegenerationoftheWstatecanbedeterminedbydetectingthepolarizationofphotonleakingoutofthecavity.TheresultdemonstratesthattheWstateisfreefromboththecavitylossandthespontaneousemissionduetothefactthatthetwogroundstates(leftandright)ofthethree-levelatomsarestablestates(ormetastablestates).

  • 标签: 原子物理学 ∧型三层原子结构 光子干涉 W态 单腔 量子纠缠态
  • 简介:AnovelacrylicmonomerbearingaromaticetherealitygroupN-(p-phenoxy-phenyl)methacrylamide(MAPOA)wassynthesizedandpolymerized.ThefluorescencespectraofMAPOAanditspolymerwerestudied,showingthatthepolymerdisplaysastrongerfluorescencethanitsmonomeratthesamechromophoreconcentration.ThefluorescenceofP(MAPOA)wasquenchedbyaddingelectrondeficiencymonomerssuchasMMA,ANetc..Itisanotherexampleofshowingthe"fluorescencestructuralself-quenchingeffect"aswereportedpreviously,fromwhichitisdemonstratedagainthatthisphenomenonisnotanaccidentalonebutacommoneffectforacrylicmonomersbearingelecton-donatingchromophores.ThephotopolymerizationofANsensitizedbyMAPOAandP(MAPOA)wasstudied.Thekineticequationofthepolymerizationwasobtainedandrepresentedasfollows:Rp∝[MAPOA]0.38×[AN]0.78,Rp∝[P(MAPOA)]0.33×[AN]0.71TheoverallactivationenergiesweredeterminedtobeEa=24.22kJ/mol(MAPOA)andEa=26.31kJ/mol[P(MAPOA)]respectively.ThefluorescenceanalysisoftheresultedP(AN)showedthatthesensitizeralsoenteredintotheP(AN)chains.AmechanismoftheformationofachargetransfercomplexandfreeradicalinitiationwassuggestedforthephotopolymerizationofANsensitizedbyMAPOAandP(MAPOA).

  • 标签: N-(p-Phenoxy-phenyl)methacrylamide Fluorescence Structural self-quenching effect Acrylonitrile
  • 简介:n人合作博弈的效益分配为主要研究对象,从最大熵原理出发,将数学与物理学原理结合,采用概率论的方法,在只知道n-1方信息的情况下提出新的利益分配方法,克服了Shapley值法所需信息量大的弊端。实例表明,该方法能够用较少的信息得到和Shapley值法接近的结果,具有很好的科学性和实用性,为合作博弈的效益分配问题提供了新的思路。

  • 标签: 合作博弈 信息不完全 利益分配 SHAPLEY值法 最大熵 平均信息熵
  • 简介:Thebaryonspectrumandthebaryoncouplingsaretwoofthemostimportantissuesinhadronicphysicsandtheyareattractingmuchattention.Bothontheexperimentalandtheoreticalsides,thenucleonexcitedstatesbelow2.0GeVhavebeenextensivelystudied[1].However,thecurrentinformationforthepropertiesofstatesaroundorabove2.0GeVisscarce.Ontheotherhand,inthisenergyregion,manytheoreticalapproacheshavepredictedmissingNstates,whichhavenotbeensofarobserved.Hence,thestudyofthepossibleroleplayedbythe2.0GeVregionnucleonresonancesintheavailableaccuratedataistimelyandcouldshedlightintothecomplicateddynamicsthatgovernsthehighexcitednucleonspectrum.

  • 标签: PHOTON HADRONIC Productions
  • 简介:Acrylateterpolymer-boundSe,Nbidentateligandwassynthesizedfromthesidechainchlorineofcopolymerandβ-dimethylamino-β′-hydroxyl-diethylselenoether.Thepolymer-supportedplatinumcomplexexhibitedhighcatalyticactivityinthehydrosilylationofolefinswithtriethoxysilane.

  • 标签: 合成 催化活性 铂络合物 双配位基
  • 简介:Inthispaperbyvirtueofthetechniqueofintegrationwithinanorderedproduct(IWOP)ofoperatorsandtheintermediatecoordinate-momentumrepresentationinquantumoptics,wederivethenormalorderingandantinormalorderingproductsoftheoperator(fQ+gP)nwhennisanarbitraryinteger.Theseproductsareveryusefulincalculatingtheirmatrixelementsandexpectationvaluesandobtainingsomeusefulmathematicalformulae.Finally,theapplicationsofsomenewidentitiesaregiven.

  • 标签: 荧光蛋白 运营商 订购 应用 量子光学 矩阵元素
  • 简介:§0.IntroductionOriginally,thedefinitionofexpansivehomeomorphismwasproposedin[9]asaconceptintopologicaldynamics.Sincethen,ithasbeeninvolvedinsomeimportanttopicsindifferentiatedynamics.Forinstance,thewell-knownAnosovdiffeomorphismandtherestrictionofSmale’shorseshoemaponitsfl-setaretypicalexamplesofexpansivehomeomorphisms.Thisconcepthasalsobeenapplied,forexample,inergodictheory110-1andthetheoryofstructuralstability1-43.Inthemathematicaldescriptionofthestrangeattractorgcs:i,expansivenessisoneofthe

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  • 简介:Themagnetoresistanceeffectofap–njunctionunderanelectricfieldwhichisintroducedbythegatevoltageatroomtemperatureisinvestigatedbysimulation.Asauxiliarymodels,theLombardiCVTmodelandcarriergenerationrecombinationmodelareintroducedintoadrift-diffusiontransportmodelandcarriercontinuityequations.Alltheequationsarediscretizedbythefinite-differencemethodandtheboxintegrationmethodandthensolvedbyNewtoniteration.Takingadvantageofthosemodelsandmethods,anabruptjunctionwithuniformdopingisstudiedsystematically,andthemagnetoresistanceasafunctionofdopingconcentration,SiO_2thicknessandgeometricalsizeisalsoinvestigated.Thesimulationresultsshowthatthemagnetoresistance(MR)canbecontrolledsubstantiallybythegateandisdependentonthepolarityofthemagneticfield.

  • 标签: 磁电阻效应 电场控制 数值模拟 P-N结 连续性方程 栅极电压
  • 简介:TheadsorptionanddiffusionofNatomsonthethreelow-indexCuplaneswerestudiedusing5-parameterMorsepotential(5-MP)method,andthebesttheory-experimentagreementwasobtained.NatomsofCu(100)surfacesitonthefourfoldhollowsitewiththeverticalheightof0.018nmcloselycoplanarwiththetopmostcopperlayer,andthefourCu-Nbondlengthsare0.182nmandthefifthCu-Ndistanceis0.199nm.ForCu(111)system,theexistenceofaberrantCu(100)reconstructedstructureisapprovedathighercoverage,andatlowcoveragethestructureisalmostanidealCu(111)surfacestructure.WithrespecttoCu(110)system,theNatomsareadsorbedatLBandH3sites,notatSBsite.ThediffusionpassageanddiffusionbarrierofadsorbedNatomswerealsostudied.

  • 标签: 氮原子 铜低指数表面 吸附理论 扩散理论 势能面
  • 简介:ThispaperstudiestheasymptoticpropertiesoftherandomiterationsofboththeformGn=f1of2o……ofnandtheformFn=fnofn-1o…of1,where{fn}(包含于)H(Ω,Ω)andΩ(包含于)C^Nisahoundeddomain.Itisfoundthat,undersomeconditions.GnorFntendstoapointinΩasn→∞.Someexamplesarealsogiventoshowthattheconditionsthatwehavegivencannotbedroppedingeneral,Moreover,acompletedescriptionisgivenforFnorGntotendtoapointinΩundertheconditionfn→f.

  • 标签: 随机迭代 全纯映射 复变量 有界序列
  • 简介:Letp(z)=beapolynomialdegreenandletThenaccord-ingtoBernstein’sinequality||p’||<n||p||.ItisawellknownopenproblemtoobtaininequalityanalogoustoBernstein’sinequalityfortheclassIInofpolynomialssatisfyingp(z)≡znp(1/z)HereweobtainaninequalityanalogoustoBernstein’sinequalityforasubclassofIInOurresultsincludeseveraloftheknownresultsasspecialcases.

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  • 简介:分析了带有修理设备和多重致命及非致命操作故障的k/N(G)冗余表决系统的渐近稳定性.用该系统算子生成的正定C0-半群证明了系统非负时间依赖解的存在唯一性.同时通过对系统算子谱点分布的分析,证明了本征值0对应的本征向量恰好是系统的静态解,并且,0是虚轴上系统算子唯一的谱点,从而证明了系统的渐近稳定性.

  • 标签: 渐近稳定性 证明 C-半群 解的存在唯一性 算子谱 表决系统
  • 简介:CrosslinkedN,O-carboxymethylchitosanresinswhichcanselectivelyadsorbtriglyceride,werepreparedbythereactionofN,O-carboxymethylchitosanwithglutaraldehydesolution.Adsorptionexperimentswereperformedbyaddingtheresinstotheserum.Theresultsshowedthatthistypeofadsoirbentcouldcutdowntheconcentrationoftriglycerideinserumby56.4%(3.35mg/gresin)atmost,whileconcentrationofthetotalprotein(TP)decreasedonlyby10.9%atleast,sothisnoveladsorbentcanbeusedtocurehypertriglyceridemiabyhemoperfusioninthefuture.

  • 标签: 合成树酯 甘油三酯 吸附特性