简介:Aconvenient,environmentallybenign,andhighlyefficientprotocolforthepreparationofN-aryl-hydroxylaminesfromthecorrespondingnitroarenesinaZn/HCOONH4/CH3CNsystemunderultrasoundisdescribed.Theadvantagesofthepresentmethodincludehighchemoselectivity,simpleandpracticalwork-upprocedureandhighyield.
简介:WesuggesttwoschemestogeneratetheWstateofNA-typethree-levelatoms.Intheschemes,identicalNthree-levelatomsaretrappedinacavityorNdistantcavities.ThesuccessorfailureofthegenerationoftheWstatecanbedeterminedbydetectingthepolarizationofphotonleakingoutofthecavity.TheresultdemonstratesthattheWstateisfreefromboththecavitylossandthespontaneousemissionduetothefactthatthetwogroundstates(leftandright)ofthethree-levelatomsarestablestates(ormetastablestates).
简介:AnovelacrylicmonomerbearingaromaticetherealitygroupN-(p-phenoxy-phenyl)methacrylamide(MAPOA)wassynthesizedandpolymerized.ThefluorescencespectraofMAPOAanditspolymerwerestudied,showingthatthepolymerdisplaysastrongerfluorescencethanitsmonomeratthesamechromophoreconcentration.ThefluorescenceofP(MAPOA)wasquenchedbyaddingelectrondeficiencymonomerssuchasMMA,ANetc..Itisanotherexampleofshowingthe"fluorescencestructuralself-quenchingeffect"aswereportedpreviously,fromwhichitisdemonstratedagainthatthisphenomenonisnotanaccidentalonebutacommoneffectforacrylicmonomersbearingelecton-donatingchromophores.ThephotopolymerizationofANsensitizedbyMAPOAandP(MAPOA)wasstudied.Thekineticequationofthepolymerizationwasobtainedandrepresentedasfollows:Rp∝[MAPOA]0.38×[AN]0.78,Rp∝[P(MAPOA)]0.33×[AN]0.71TheoverallactivationenergiesweredeterminedtobeEa=24.22kJ/mol(MAPOA)andEa=26.31kJ/mol[P(MAPOA)]respectively.ThefluorescenceanalysisoftheresultedP(AN)showedthatthesensitizeralsoenteredintotheP(AN)chains.AmechanismoftheformationofachargetransfercomplexandfreeradicalinitiationwassuggestedforthephotopolymerizationofANsensitizedbyMAPOAandP(MAPOA).
简介:Thebaryonspectrumandthebaryoncouplingsaretwoofthemostimportantissuesinhadronicphysicsandtheyareattractingmuchattention.Bothontheexperimentalandtheoreticalsides,thenucleonexcitedstatesbelow2.0GeVhavebeenextensivelystudied[1].However,thecurrentinformationforthepropertiesofstatesaroundorabove2.0GeVisscarce.Ontheotherhand,inthisenergyregion,manytheoreticalapproacheshavepredictedmissingNstates,whichhavenotbeensofarobserved.Hence,thestudyofthepossibleroleplayedbythe2.0GeVregionnucleonresonancesintheavailableaccuratedataistimelyandcouldshedlightintothecomplicateddynamicsthatgovernsthehighexcitednucleonspectrum.
简介:Inthispaperbyvirtueofthetechniqueofintegrationwithinanorderedproduct(IWOP)ofoperatorsandtheintermediatecoordinate-momentumrepresentationinquantumoptics,wederivethenormalorderingandantinormalorderingproductsoftheoperator(fQ+gP)nwhennisanarbitraryinteger.Theseproductsareveryusefulincalculatingtheirmatrixelementsandexpectationvaluesandobtainingsomeusefulmathematicalformulae.Finally,theapplicationsofsomenewidentitiesaregiven.
简介:§0.IntroductionOriginally,thedefinitionofexpansivehomeomorphismwasproposedin[9]asaconceptintopologicaldynamics.Sincethen,ithasbeeninvolvedinsomeimportanttopicsindifferentiatedynamics.Forinstance,thewell-knownAnosovdiffeomorphismandtherestrictionofSmale’shorseshoemaponitsfl-setaretypicalexamplesofexpansivehomeomorphisms.Thisconcepthasalsobeenapplied,forexample,inergodictheory110-1andthetheoryofstructuralstability1-43.Inthemathematicaldescriptionofthestrangeattractorgcs:i,expansivenessisoneofthe
简介:Themagnetoresistanceeffectofap–njunctionunderanelectricfieldwhichisintroducedbythegatevoltageatroomtemperatureisinvestigatedbysimulation.Asauxiliarymodels,theLombardiCVTmodelandcarriergenerationrecombinationmodelareintroducedintoadrift-diffusiontransportmodelandcarriercontinuityequations.Alltheequationsarediscretizedbythefinite-differencemethodandtheboxintegrationmethodandthensolvedbyNewtoniteration.Takingadvantageofthosemodelsandmethods,anabruptjunctionwithuniformdopingisstudiedsystematically,andthemagnetoresistanceasafunctionofdopingconcentration,SiO_2thicknessandgeometricalsizeisalsoinvestigated.Thesimulationresultsshowthatthemagnetoresistance(MR)canbecontrolledsubstantiallybythegateandisdependentonthepolarityofthemagneticfield.
简介:TheadsorptionanddiffusionofNatomsonthethreelow-indexCuplaneswerestudiedusing5-parameterMorsepotential(5-MP)method,andthebesttheory-experimentagreementwasobtained.NatomsofCu(100)surfacesitonthefourfoldhollowsitewiththeverticalheightof0.018nmcloselycoplanarwiththetopmostcopperlayer,andthefourCu-Nbondlengthsare0.182nmandthefifthCu-Ndistanceis0.199nm.ForCu(111)system,theexistenceofaberrantCu(100)reconstructedstructureisapprovedathighercoverage,andatlowcoveragethestructureisalmostanidealCu(111)surfacestructure.WithrespecttoCu(110)system,theNatomsareadsorbedatLBandH3sites,notatSBsite.ThediffusionpassageanddiffusionbarrierofadsorbedNatomswerealsostudied.
简介:ThispaperstudiestheasymptoticpropertiesoftherandomiterationsofboththeformGn=f1of2o……ofnandtheformFn=fnofn-1o…of1,where{fn}(包含于)H(Ω,Ω)andΩ(包含于)C^Nisahoundeddomain.Itisfoundthat,undersomeconditions.GnorFntendstoapointinΩasn→∞.Someexamplesarealsogiventoshowthattheconditionsthatwehavegivencannotbedroppedingeneral,Moreover,acompletedescriptionisgivenforFnorGntotendtoapointinΩundertheconditionfn→f.
简介:Letp(z)=beapolynomialdegreenandletThenaccord-ingtoBernstein’sinequality||p’||<n||p||.ItisawellknownopenproblemtoobtaininequalityanalogoustoBernstein’sinequalityfortheclassIInofpolynomialssatisfyingp(z)≡znp(1/z)HereweobtainaninequalityanalogoustoBernstein’sinequalityforasubclassofIInOurresultsincludeseveraloftheknownresultsasspecialcases.
简介:CrosslinkedN,O-carboxymethylchitosanresinswhichcanselectivelyadsorbtriglyceride,werepreparedbythereactionofN,O-carboxymethylchitosanwithglutaraldehydesolution.Adsorptionexperimentswereperformedbyaddingtheresinstotheserum.Theresultsshowedthatthistypeofadsoirbentcouldcutdowntheconcentrationoftriglycerideinserumby56.4%(3.35mg/gresin)atmost,whileconcentrationofthetotalprotein(TP)decreasedonlyby10.9%atleast,sothisnoveladsorbentcanbeusedtocurehypertriglyceridemiabyhemoperfusioninthefuture.