简介：Twofamiliesofcatalysts,basedonPdnanoparticlessupportedonceramicasymmetrictubularaluminamembranes,arestudiesinthedirectsynthesisofH_2O_2.TheyarepreparedbydepositingPdintwoways:(i)reductionwithN_2H_4inanultrasonicbathand(ii)byimpregnation-deposition.Thefirstpreparationleadstolargerparticles,withaveragesizeofaround11nm,whilethesecondpreparationleadstosmallerparticles,withaveragesizearound4nm.Thecatalyticmembranesweretestedasprepared,afterthermaltreatmentinairandafterfurtherpre-reductionwithH_2inmild(100℃)conditions.SampleswerecharacterizedbyTEM,CO-chemisorptionmonitoredbyDRIFTSmethodandTPR,whilecatalytictestshavebeenperformedinasemi-batchrecirculationmembranereactor.Experimentalcatalyticresultswereanalysedusingtwokineticsmodelstoderivethereactionconstantsfortheparallelandconsecutivereactionsofthekineticnetwork.SmallerparticlesofPdshowlowerselectivityduetothehigherrateofparallelcombustion,evenifthebetterdispersionofPdandthushighermetalsurfaceareainthesampleleadtoaproductivityinH_2O_2similarorevenhigherthanthesamplewiththelargerPdparticles.IndependentlyonthepresenceofsmallerorlargerPdnanoparticles,anoxidationtreatmentleadstoasignificantenhancementintheproductivity,althoughthecatalystprogressivelyreducesduringthecatalyticprocess.Theinhibitionoftheparallelcombustionreaction(towater)inducedfromthecalcinationtreatmentremainsafterthein-situreductionoftheoxidizedPdspeciesformedduringthepre-treatment.Thisislikelyduetotheeliminationofdefectsiteswhichdissociativelyactivateoxygen,andtentativelyattributedtoPdsitesabletogivethree-andfour-foldcoordinationofCO.

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简介：AKerr-lens,mode-lockedYVO4∕Nd:YVO4lasercoupledwithanacousto-opticmodulator（AOM）Q-switchingnear1064nmwasemployedtopumpanintracavityKTiOPO4（KTP）opticalparametricoscillator.Asubnanosecondsignalwavenear1572nmwithlowrepetitionratewasrealized.AtanAOMrepetitionrateof8kHz,themaximumoutputpowerwas165mW.Thehighestaveragepulseenergy,theshortestduration,andthehighestpeakpowerofamode-lockingsignalpulsewereestimatedtobe～10.3μJ,～120ps,and～82kW,respectively.

简介：Geant4LowEnergyElectromagneticpackageProvidesaprecisetreatmentofelectromagneticinterationsofparticleswithmatterdowntoverylowenergies(250oVforelectronsandphotons,<1keVforhadronsandions),Itincludesaverietyofmodelsfortheelectromagneticprocessesofelectrons,photons,hadronsandions,takingintoaccountadvancefeatures,suchasshelleffectsandeffectsduetochargedependence.Thecomprehensivesetofparticletypesitcanhandle,thevarietyofmodelingapproachesandtheextendedcoverageofenergyrangemakethispackageauniquetoolamongMonteCarlocodesonthemarket,andofrelevancetoserveralexperimentaldomainsinHIEP,astroparticlephysics,spacescienceandbiomedicalstudies.

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简介：Cu2ZnSnS4(CZTS)基于太阳能电池被microelectronic和photonic结构(AMPS-1D)的一个维的太阳能电池模拟软件分析数字地模仿。在模拟使用的设备结构是Al/ZnO:Al/nZn(O，S)/pCZTS/Mo。工作是在ZnO1xSx缓冲区层，它将产出更高的变换效率。由改变S/(S+O)比率x，在CZTS/Zn的传导乐队偏移量(CBO)(O，S)如果比率的完整的范围被考虑，接口能从0.23eV到1.06eV。当时，0.23eV的最佳的CBO能被完成ZnO1xSx缓冲区有S/(S+O)0.6的比率。太阳能电池效率首先与增加硫内容增加然后为x突然地减少>0.6，它由我们的建议的最佳的硫内容x=到达17.55%的最高的价值0.6。我们的结果在处理ZnO1x为高效率CZTS的Sx缓冲区层免职太阳能电池。

简介：Multilayerblackphosphorus（BP）nanoplateletsofdifferentthicknesseswerepreparedbytheliquidphaseexfoliationmethodanddepositedontoyttriumaluminumgarnetsubstratestoformsaturableabsorbers（SAs）.Thesewerecharacterizedwithrespecttotheirthickness-dependentsaturableabsorptionpropertiesat3μm.TheBP-SAswereemployedinapassivelyQ-switchedEr:Lu2O3laserat2.84μm.ByusingBPexfoliatedindifferentsolvents,stablepulsesasshortas359nsweregeneratedatanaverageoutputpowerofupto755mW.Therepetitionrateintheexperimentwas107kHz,correspondingtoapulseenergyof7.1μJ.TheseresultsprovethatBP-SAshaveagreatpotentialforopticalmodulationinthemid-infraredrange.

简介：Sn-dopedTiO_2nanoparticleswithhighsurfaceareaof125.7m~2·g~(-1)aresynthesizedviaasimpleone-stephydrothermaimethodandexploredasthecathodecatalystsupportforprotonexchangemembranefuelcells.ThesynthesizedsupportmaterialsarestudiedbyX-raydiffractionanalysis,energydispersiveX-rayspectroscopyandtransmissionelectronmicroscopy.Itisfoundthattheconductivityhasbeengreatlyimprovedbytheadditionof30mol%SnandPtnanoparticlesarewelldispersedonTi_(0.7)Sn_(0.3)O_2supportwithanaveragesizeof2.44run.ElectrochemicalstudiesshowthattheTi_(0.7)Sn_(0.3)O_2nanoparticleshaveexcellentelectrochemicalstabilityunderahighpotentialcomparedtoVulcanXC-72.Theas-synthesizedPt/Ti_(0.7)Sn_(0.3)O_2exhibitshighandstableelectrocatalyticactivityfortheoxygenreductionreaction.ThePt/Ti_(0.7)Sn_(0.3)O_2catalystreservesmostofitselectrochemicallyactivesurfacearea(ECA),anditshalfwavepotentialdifferenceis11mV,whichislowerthanthatofPt/XC-72(36mV)under10hpotentialholdat1.4Vvs.NHE.Inaddition,theECAdegradationofPt/Ti_(0.7)Sn_(0.3)O_2is1.9timeslowerthancommercialPt/XC-72under500potentialcyclesbetween0.6Vand1.2Vvs.NHE.Therefore,theassynthesizedPt/Ti_(0.7)Sn_(0.3)O_2canbeconsideredasapromisingalternativecathode,catalystforprotonexchangemembranefuelcells.

简介：AnapplicatiopnoftheopticalpyrometerisstudiedformeasuringmonochromaticemissivitiesofcementclinkerwithvariousFe2O3contnet.Theidsaofusing“brightnesstemperature”isintroducedintotheeimssivitymeasurement.Inthismethod,thereisnoneedformeasuringanactualtemperatureofsamplesurfaces,onlywithdeterminingbothbrightnesstemperaturesofasampleandablackbodycantherequiredemissivitybeevaluatedaccordingtoWien'sradiationlaw.Inpractice,thecementclinkerisregardedasagreybody,themonochromaticemissivityisapproximatelyequaltothetotalemissivity,soasingle-colouropticalpyrometerisappliedforthispurpose,Testmeasurementsarecarriedouton10kindsofcementclinkers,Experimentaldataaretreatedbytheleastsquaremethod.Asaresult,theemissivityvariationwithtemperatureatacertainFe2O3contentisquitewellrepresentedbyεn=a+bT.Furthermore,thisworkfirstreportedthattheeimissivitiesofcementclinkerchangeconsierablywithFe2O3contents.Inmultiplecementproductionthisconclusionisveryimportant.

简介：Ithasbeenproposedthatfusionreactionsbetweenneutron-richlightnuclei,forexample24C,24Oand28Ne,maycontributetoachievingtheignitiontemperatureforexplosivecarbonburningprocessduringsuperbusrsts[1,2].Studiesoffusionreactionsinvolvingneutron-richnucleiarebeyondordinaryexperimentaltechniques,sincetheintensityofradioactivebeambecomelowforthesemeasurements[3].TheactivetargettechniqueusingTPC(TimeProjectionChamber),withpropertiesofmulti-sampling,highefficiencyandlowbackground,isasuitablesolutiontotheproblem.

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简介：ThepresolarSiCgrains[1]carrytheoriginalstellarnucleosynthesissignature.Theirisotopicanomaliescomparedtothesunarethestrongconstrainsinthesupernovae(SN)modelcalculations.The15N-excessinsomeSiC-ABgrains(12C/13C<10and14N/15N<272)isoneofthechallengesofcore-collapsesupernovae(CCSNe)models[2].Recently,PignataripointedoutthattheentrainmentofH-richmaterialintotheHeshellbeforetheSNexplosionallowsthecoproductionof13C,15Nand26Al,whichprovidesanewproductionscenarioforSiC-ABgrains[2].IntheHeshellnucleosynthesis,the13Cisproducedthrough12C(p,γ)13N(β+γ)13Creaction.The14Nissynthesizedthrough13N(n,γ)and13C(p,γ)reactions.

简介：ＥｘｐｅｒｉｍｅｎｔａｌＭｅａｓｕｒｅｍｅｎｔｓｏｆＮｅｕｔｒｏｎＤｉｓｔｒｉｂｕｔｉｏｎｓｉｎ５０ＭｅＶ／ｕ１８Ｏ＋Ｂｅ，ＣｕａｎｄＡｕＲｅａｃｔｉｏｎｓ￥ＬｉＧｕｉｓｈｅｎｇ；ＺｈａｎｇＴｉａｎｍｅｉ；ＬｉＺｏｎｇｗｅｉａｎｄＳｕＹｏｕｗｕ?..

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简介：TheroleoftemperatureontheoxidationdynamicsofCu2OonZnO(0001)wasinvestigatedduringtheoxidationofCu(111)/ZnO(0001)byusingoxygenplasmaastheoxidant.AtransitionfromsinglecrystallineCu2O(111)orientationtomicro-zonephaseseparationwithmultipleorientationswasrevealedwhentheoxidationtemperatureincreasedabove300°C.TheexperimentalresultsclearlyshowtheeffectoftheoxidationtemperaturewiththeassistanceofoxygenplasmaonchangingthemorphologyofCu(111)filmandenhancingthelateralnucleationandmigrationabilitiesofcuprousoxides.Averticaltop-downoxidationmodeandalateralmigrationmodelwereproposedtoexplainthedifferentnucleationandgrowthdynamicsofthetemperature-dependentoxidationprocessintheoxidationofCu(111)/ZnO(0001).

简介：Two-dimensionalatomic-layeredmaterialisarecentresearchfocus,andsinglelayerTa2O5usedasgatedielectricinfield-effecttransistorsisobtainedviaassembliesofTa2O5nanosheets.However,theelectricalperformanceisseriouslyaffectedbyelectronicdefectsexistinginTa2O5.Therefore,spectroscopicellipsometryisusedtocalculatethetransitionenergiesandcorrespondingprobabilitiesfortwodifferentchargedoxygenvacancies,whoseexistenceisrevealedbyx-rayphotoelectronspectroscopyanalysis.SpectroscopicellipsometryfittingalsocalculatesthethicknessofsinglelayerTa2O5,exhibitinggoodagreementwithatomicforcemicroscopymeasurement.NondestructiveandnoncontactspectroscopicellipsometryisappropriatefordetectingtheelectricaldefectslevelofsinglelayerTa2O5.

简介：用多光子光电效应理论简要分析了多光子光电效应实验,指出多光子光电效应满足nhν=12mv20+φ(hν0)且nν/ν0=4/3。同时用微扰法及单光子光电效应理论分析了H原子电离问题,结果表明也是当ω/ω0=4/3时电离几率最大

简介：本文用少体方法对Ａ≤４的Ｓ壳超核动力学结构进行系统研究，同时研究Ａ≤３的普通原子核的结构，通过比较，看到了超子进入核内使结构产生变化，超子的加入，造成壳心核的缩聚，核子间均方根距离缩短，超子在核内起胶粘凝聚作用。对这些核体系内部结构的研究表明．粒子间相对运动主要处于Ｏｓ轨道。

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