简介：Ca3Y2(BO3)(4):Eu3+黄磷被高温度solid-statereaction方法综合，并且光特征被调查。排放光谱在相应于电的dipoleD-5(0)的613和621nm展出二强壮的红排出物在365nm刺激下面的Eu3+的-F-7(2)转变，原因是Eu3+代替forY3+在Ca3Y2(BO3)(4)的水晶结构占据非中心对称的位置。为613nm的Theexcitation光谱显示黄磷能是有效地激动的由紫外(紫外)(254nm，365nm和400nm)并且蓝色(470nm)光。Ca3Y2(BO3)(4)的排放紧张上的Eu3+集中的效果:Eu3+黄磷被测量，排放紧张与增加Eu3+集中增加的结果表演，然后减少。Ca3Y2(BO3)(4)的CIE颜色坐标:Eu3+黄磷是(0.639，0.357)在15mol%Eu3+。

简介：ThenovelverticallystandingPtSe2filmontransparentquartzwaspreparedbyselenizationofplatinumfilmdepositedbythemagnetronsputteringmethod,andanNd：LuVO4passivelymode-lockedsolid-statelaserwasrealizedbyusingthefabricatedPtSe2filmasasaturableabsorber.TheX-raydiffractionpatternandRamanspectrumofthefilmindicateitsgoodcrystallinitywithalayeredstructure.ThethicknessofPtSe2filmismeasuredtobe24nmaccordingtothecross-sectionheightprofileoftheatomicforcemicroscopeimage.High-resolutiontransmissionelectronmicroscopyimagesclearlydemonstrateitsverticallystandingstructurewithaninterlayerdistanceof0.54nmalongthec-axisdirection.Themodulationdepth（AT）andsaturationfluence（Фs）ofPtSe2filmaremeasuredtobe12.6%and17.1μJ/cm2,respectively.Theobtainedmode-lockedlaserspectrumhasacentralwavelengthof1066.573nm,witha3dBbandwidthof0.106nm.Thetransformlimitedpulsewidthofthemode-lockedlaserwascalculatedtobe15.8ps.Amaximumaverageoutputpowerof180mWwithaworkingrepetitionrateof61.3MHzisobtained.Tothebestofourknowledge,thisisthefirstreportofthegenerationofultrafastmode-lockedlaserpulsesbyusinglayeredPtSe2asasaturableabsorber.

简介：Fe_(3–x)O_4raspberryshapednanostructures/graphenenanocompositesweresynthesizedbyaone-steppolyol-solvothermalmethodtobetestedaselectrodematerialsforLi-ionbattery(LIB).Indeed,Fe_(3–x)O_4raspberryshapednanostructuresconsistoforiginalorientedaggregatesofFe_(3–x)O_4magnetitenanocrystals,ensuringalowoxidationstateofmagnetiteandahollowandporousstructure,whichhasbeeneasilycombinedwithgraphenesheets.TheresultingnanocompositepowderdisplaysaveryhomogeneousspatialdistributionofFe_(3–x)O_4nanostructuresatthesurfaceofthegraphenesheets.TheseoriginalnanostructuresandtheirstronginteractionwiththegraphenesheetsresultedinverysmallcapacityfadinguponLi+ionintercalation.Reversiblecapacity,ashighas660mAh/g,makesthismaterialpromisingforanodeinLi-ionbatteriesapplication.

简介：Two-dimensional（2D）graphitecarbonnitride（g-C3N4）nanosheetshavebeensuccessfullyusedasasaturableabsorber（SA）inapassivelyQ-switchedNd:LLFlaserat1.3μmforthefirsttime,tothebestofourknowledge.Underanincidentpumppowerof9.97W,theshortestpulsedurationof275nswasacquiredwithoutputpowerof0.96Wandpulserepetitionrateof154kHz,resultinginapulseenergyof6.2μJ.Inaddition,thesaturableabsorptionbehaviorsofzero-dimensional12nmg-C3N4nanoparticles（g-C3N4-NPs）andthree-dimensionalorderedmesoporousg-C3N4（mpg-C3N4）werealsoobserved,althoughtheirmorphologyandstructurewerequitedifferentfrom2Dg-C3N4.Theexperimentalresultsintroducethepotentialapplicationofg-C3N4nanomaterialsasSAsinQ-switchedlasers.

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简介：Theelectronicstructures,dielectricfunctions,complexrefractiveindicesandabsorptionspectraforaperfectPbW04(PWO)crystalandthePWOcrystalscontainingleadvacancyV^2-pbhavebeencalculatedusingafull-potential(linearized)augmentedplane-wave(LAPW)+localorbitals(LO)methodwiththelatticestructureoptimized.Thepeaksoftheabsorptionspectracorrespondingtotheelectronictransitionshavebeenstudied.

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简介：我们从intra洞表明红轻femtosecond激光脉搏的产生加倍频率的Cr4+:forsterite激光。75mW的平均产量力量被在激光洞插入500-m-thickBBO晶体与55fs的脉搏宽度在647nm的中央波长获得。第二泛音脉搏的光谱的带宽是9nm，相应于0.355的一个时间带宽产品。

简介：Siliconcarbidefiber/siliconcarbidematrix(SiCf/SiC)compositesareofinterestasafuelcladdingandstructuralmaterialindesignsofadvancednuclearreactorduetotheirsuperiorthermo-mechanicalpropertiesandstabilitiesandlowcross-sectionforneutroncaptureunderthesevereserviceenvironmentincludinghightemperatureandhighenergyneutronbombardment.SiCf/SiCcompositionsconsistsofSiCfiberandSiCmatrixwhichexistinwellover100polymorphsdependentonthevariedstackingofSi-Cclose-packedatomicplanes,2H-SiC,4H-SiC,6H-SiC,3C-SiC,15R-SiC,etc.EnergeticHeatomscanbecreatedandaccumulatedvianuclearreactions.HeatomsagglomerateandcoarsenintoHebubblesandcandeterioratestructuralpropertiesbyinducingcrackandcreep.Inthisexperiment,thedamageofn-type4H-SiCwafers(researchstandard,suppliedbytheCreeResearchInc.)withathicknessof0.38mmimplantedwith100keVHe+toafluenceof31016He+/cm2andpost-implantation-annealedbehavioratdifferenttemperaturewerestudiedusingRamanscatteringspectroscopy.

简介：Weexperimentallydemonstratedadiode-pumpedKerr-lensmode-lockedfemtosecondlaserwithaYb:CaYAlO4crystalasthegainmedium.Pulsedurationasshortas33fswasobtaineddirectlyfromtheoscillatoratarepetitionrateof115MHz.Thecentralwavelengthwasat1059nmwithaspectralbandwidthof49nm.Theseare,tothebestofourknowledge,theshortestpulsesgeneratedfromaYb:CaYAlO4oscillator.

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简介：本文考察了稀土氧化物，合金和氧化锆对ＡｌＰＯ４５载体和Ｆｅ／ＡｌＰＯ４５催化剂的影响。结果表明，Ｌａ、Ｃｅ和Ｙ稀士氧化物的引入可有效地促进硝酸铁丙酮溶液中制备的Ｆｅ／ＡｌＰＯ４５催化剂在ＣＯ加氢反应中的催化活性；负载不同合金的ＡｌＰＯ４５催化剂具有明显不同的催化反应结果；ＺｒＯ可调变ＡｌＰＯ５载体的表面性能，削弱活性组份和载体间的相互作用，使在硝酸铁水溶液中制备的催化剂在合成气转化中具有一定的催化活性。更多还原

简介：One-potachievementofethyllevulinatefromcassavawasconductedinethanol-watersystemoverseveralsimplesulfatesaltcatalysts.Al2（SO4）3catalysthadthebestperformanceinsynthesizingethyllevulinatecomparingwiththoseofaseriesofsulfatesalts.Thehighestyieldsofethyllevulinatewasupto39.27%aswellas7.78%levulinateacidwhencassavawascatalyzedinethanolmediumbyadding10wt%water.13Cand1HNMRspectroscopicinvestigationsconfirmedthatisomerizationofglucosetofructoseoverAl2（SO4）3catalystisanimportantstepinproducingethyllevulinateandlevulinateacid.DuetoaggregationsofAl3+underhydrothermalconditions,tinyamountofAl3+weredetectedinfiltrateatthepercentageof0.32%evenifinabsolutewater.BronstedandLewisacidscouldimprovetheyieldofethyllevulinateandlevulinateacidbysynergisticeffect.AllresultssuggestedthatA12（SO4）3wasasimpleandefficientcatalystforethyllevulinateandlevulinateacidproduction.

简介：WehavesynthesizedandinvestigatedphysicalpropertiesoftwonewquaternarycompoundsGd2CoAl4T2(T=Si,Ge)singlecrystals,whichareisostructuraltoTb2NiAl4Ge2andEr2CoAl4Ge2.Themostimportantstructuralfeatureofthesematerialsistheanti-CaF2-typeCoAl4T2slabs.Thesematerialsshowmetallicbehaviorbelow300Kandthereisalong-rangeantiferromagnetic(AFM)transitionappearingat20and27KforGdCoAl4Ge2andGd2CoAl4Si2,respectively.ResistivityandheatcapacitymeasurementsalsoconfirmthesebulkAFMtransitions.Furtheranalysisindicatesthatthislong-rangeantiferromagnetismshouldresultfromthemagneticinteractionbetweenlocalmomentsofGd^3+ions.

简介：对制造的单mesa终端4H-SiCPIN二极管,采用数值仿真和测试结果比对的方法,分析了各向异性迁移率效应对4H-SiCPIN二极管正向直流特性的影响。详细阐述了器件的正向直流仿真物理模型和参数选取,其中,迁移率的各向异性关系是在各向同性迁移率模型的基础上引入的,载流子寿命采用空间赋值的方法代入模型进行计算。对比结果显示,采用各向同性迁移率模型的仿真结果与实验值偏差较大,对迁移率模型进行各向异性修正后,仿真结果与实验结果符合得较好。研究表明,实际制造的4H-SiCPIN二极管在直流开态下,存在迁移率的各向异性效应。

简介：Severecapacityfadingandpoorhighrateperformanceoflithiumsulfur(Li-S)batterycausedby"shuttleeffect"andlowconductivityofsulfurhampersitsfurtherdevelopmentsandapplications.Li4Ti50i2(LTO)possesseshigh1whiumionconductivity,anditisalsocanbeusedasanactiveadsorbentforpolysulfide.Herein,fineLTOparticlecoatedcarbonnanofibers(CNF)werepreparedandaconductivenetworkbothforelectronandlithiumionwasbuilt,whichcangreatlypromotetheelectrochemicalconversionofpolysulfideandimprovetherateperformanceofLi-Sbatteries.Meanwhile,aquantityofadsorptionsitesisconstructedbydefectsofthesurfaceofLTO-CNFmembranetoeffectivelyimmobilizepolysulfide.ThemultifunctionalLTO-CNFinterlayercouldimpedetheshuttleeffectandenhaneecomprehensiveelectrochemicalperformanceofLi-Sbatteries,especiallyhighrateperformanee.WithsuchLTO-CNFinterlayer,theLi-Sbatterypresentsaspecificcapacityof641.9mAh/gat5Crate.After400cyclesat1C,acapacityof618.0mAh/gisretained.ThisworkprovidesafeasiblestrategytoachievehighperformanceofLi-Sbatteryforpracticalutilization.

简介：Ablackphosphorus（BP）saturableabsorber（SA）solutionwithdifferentconcentrations（1.0and0.5mg/ml）isfabricatedwiththeliquid-phaseexfoliationmethod.ByusingtheBP-SA,acompactdiode-pumpedpassivelyQ-switchedNd：YV04laserisdemonstrated.OnereflectingBragggratingsisusedastheoutputcouplerformodeselection.ByinsertingthoseBP-SAsolutionsinthelasercavity,themaximumsinglelongitudemode,Q-switchedoutputpowersof126mWat692.5kHzand149mWat630.3kHzareachievedatthepumppowerof8.0W,correspondingtothepulsedurationsof144nsand196ns,respectively.Moreover,longitudinal-modecharacteristicsofQ-switchedoutputlaserindifferentopticalcavitylengthsbasedontwo-kindBP-SAsolutionconcentrationsareinvestigated.OurresultsshowthatBP-SAcouldalsobedevelopedasaneffectiveSAfortheQ-switched,singlelongitudinalmodepulselaser.