简介：TheNi-AlalloycontainingCr,FeadditiveswerepreparedasRaneyNiCatalystbyhighenergymilling.ThesizeandsurfacestateofNi-Alalloypowderwerestudiedbyparticlesizeanalyzerandsanningelectronmicroscopy.theStructurewasanalyzedbyXRDandMoessbauermethods.Theresultsshowedthatafterahigh-energymilling(HEM).theNi-Alalloytransformstoanano-scaleNiAlstructurewithrichAl.Byannealingthealloy,ametastableNi2Al3phasecanbeobtained.

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简介：ThetransientopticalpropertiesofnovelPbSnanoparticlescoatedwith2.6-O-diallyl-β-cyclodextrines(CDs)werestudiedbythefemtosecondpump-probetechnique.Theresultsshowthattheultrafasttransient-inducedabsorptionforthenovelcase.ComparedtothePbSnanoparticlesstabilizedwithpolyvinylalcohol(PVA),wefindthattheprocessforthenovelcaseisdifferentfromthePbS(PVA),WesuggestthattheCDssurfacemodificationcantrapholesonthesurfaceofPbSnanoparticles.ThiscaninduceanefficientchargeseparationbetweenthePbSnanoparticlesanditssurfaceandresultinanultrsafast-inducedabsorptionfornovelPbSnanoparticles.

简介：Thenanoparticlesγ-Fe2O3coatedwithsurfactants.DBS,STandCTAB.repsectively.weresynthesizedbymicroemulsionmethod.Thecoatedferricoxides.whichshowenhancednonlinearopticalpropertiescomparedwiththeirbulkcounterpart.wereprobedbyEXAFSinsolutionforms.Thex=-rayabsorptionspectraforFeKedgeweremeasuredatroomtemperaturebyhelpofsynchrotronradiationlightsource.Extendedx-rayabsorptionfinestructureanalysisshowsthatthecoatinglayersoforganicmoleculesinteractwithsurfaceatomsofnanopartices,theFe-Obondlengthwasextended.

简介：利用北京同步辐射小角X光散射实验站，我们对超临界流体的抗溶剂过程中，高分子的构象变化进行了初步的研究。实验表明，在不断加入抗溶剂的过程中，高分子链发生了从伸展的无规线团到球形的转变。

简介：同步辐射X射线（白光）微束激发晶态物质和非晶态物质时，其中晶态物质的衍射线将严重影响元素的X射线能谱分析，其最有效的解决办法是采用同步辐射单色光激发样品，或在样品与Si(Li)探测器之间入一准直器以消除衍射作用的影响。

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简介：Themicrostructuresofloadedorganicphasesofthreequaternaryaminesolventextractionsystemsforgold,whichwereN263-xylene,N263-tributylphosphate(TBP)-dodecaneandN263-2-ethylhexanol(isooctanol)-dodecane(N263-trialkylmethylammoniumchloride;alkyl=C8-C10),werestudiedbyFouriertransforminfrared(FTIR)spectroscopyandextendedX-rayabso\rptionfinestructure(EXAFS)spectroscopy.AccordingtotheEXAFSresults,itwasfoundthatthegoldcoordinationenvironmentwasthesamebeforeandafterextraction.However,theC≡NstretchingvibrationsofAu(CN)2-werealsofoundtobedifferent,InordertoexplainthedifferencesintheIRcharacteristicsofC≡Ninthethreeextractionsystems,threemicrostructuremodelsareproposed.FortheN263-xylenesystem,themodelisasimpleionpair.Fortheothertwosystemswithamodifier(TBPandisooctanol),themodelsaretwosupramolecularstructuesbasedonhydrogenbondingbetweenthemodifierandAu(CN)2^-.SomerelatedworksuchasonthehydrationofacetonitrileandthefinestructureofC≡NinsolidKAu(CN)2wasalsoperformedinordertoofferadditionalsupportingevidenceforthereliabilityoftheproposedmodels.

简介：《ASME锅炉与压力容器规范》第Ⅷ卷第2册包含了压力容器及其相关的泄压装置的设计、材料、制造、检验、检查、试验、认证的强制性要求、具体禁令和非强制性指导。该文献旨在说明用于锅炉与压力容器规范第Ⅷ卷第2册的设计计算。

简介：ISO/TC85/SC2(国际标准化组织/核能标准化技术委员会/辐射防护分技术委员会)第16届年会于2005年3月28日至3月31日在北京召开。

简介：以超临界CO2为溶胀剂所制备的PET／PS共混物的小角X－射线散射（SAXS）研究表明，PET／PS共混物的结构参数与共混物的组成及热历史密切相关。按Vonk的一维电子密度相关函数法，得到共混物的结构参数。过度层厚随PS组分含量增加而增加，结晶片层厚却随PS含量增加而降低。热处理可提高共混物的结晶性。内比表面积随PS含量增加而增加是PS使PET韧性和抗冲击性能提高的本质原因。

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简介：AseriesofoxideizedCO-K-Mo/γ-Al2O3catalystsamples,preparedbyimpregnatingoxidizedK-Mo/γ-Al2O3sampleswithanaqueoussolutionofcalculatedCo(NO3)2andthencalcininginairattemperaturesof350℃，500℃65℃and800℃respectively,weresulfidedandtheninvestigatedfortheactivityinthesynthesisofmixedalcoholsfromCOhydrogenationunderconditionsofp=5.0MPa,T=350℃andGHSV=4800h^-1.TheresultsdemonstratethattheadditionofcobaltpromoterisfavorabletotheformationofhigheralcoholsandtheopimumcalcinationtemperaturesafterimpregnatingwithCo^2+areabout500-650℃.ThestructureofCoandMospeciesontheoxidizedandsulfidedsampleswasdeterminedbyX-raydiffraction(XRD),laserRamanspectrum(LRS)andextendedX-rayabsorptionfinestructure(EXAFS).Foroxidizedsamplecalcinedat350℃,cobaltexistsasCo3O4spectiesandcoversthesurfaceofK-Mo-Ospecies,thestructureofK-Mo-OspeciesisthesameasthatinK-Mo/Al2O3sample.TheinteractionbetweencobaltandK-Mo-Ospeciesisrelativelyweak.Aftersulfidation.Cobaltexistsassulfidecrystalliteswithanoctahedralcoordinatedstructure,andmolybdenumasMoS2crystallites.Foroxidizedsamplescalcinedat500-650℃,CocomponentinteractswiththeK-Mo-Ospeciesanddestroysthelong-rangeorderoftheK-Mo-Ospectesgradually,Aftersulfidation.CotendstoexistasasulfidewithtetrahedralcoordinatedstructureandMostillasMoS2crystallites.Foroxidizedsamplecalcinedat800℃,CocomponentexistsmainlyasCoAl2O4species,mostofwhichcannotbesultidedduringsulfidation.

简介：ToobtainthermotolerantmutantsofG.oxydans,whichcanenhancethetransformationrateofL-sorboseto2-Keto-L-gulonate(2-KLG)at33℃inatwo-stepprocessofvitaminCmanufacture,ionbeamwasusedasamutationsource.GluconobacteroxydansGOandBacillusmegateriumB0wereusedinthisstudy.TheoriginalstrainGluconobacteroxydansGOwasmutatedbytheheavyionimplantationfacilityattheInstituteofPlasmaPhysics,ChineseAcademyofSciences.SeveralmutantsincludingGluconobacteroxydansGI13wereisolatedandcoculturedwithBacillusmegateriumB0at33℃inshakingflasks.TheaveragetransformationrateofthenewmixedstrainGI13-B0inpergram-moleculereached94.4%aftersevenpassagesinshakingflasks,whichwasincreasedby7%whencomparedwiththeoriginalmixedstrainG0-B0(GluconobacteroxydansG0andBacillusmegateriumB0).Moreover,thetransformationrateofI13B0wasstableat94%attemperaturesrangingfrom25℃to33℃,whichwouldbeofmuchvalueinreducingenergyconsumptioninthemanufactureofL-ascorbicacid,especiallyintheseasonofsummer.Toclarifysomemechanismofthemutation,thespecificactivitiesofL-sorbosedehydrogenaseinbothG0andGI13wereestimated.

简介：InthedischargeofEASTtokamak,itisobservedthat（2,1）neoclassicaltearingmode（NTM）istriggeredbymodecouplingwitha（1,1）internalmode.Usingsingularvaluedecomposition（SVD）methodforsoftX-rayemissionandforelectroncyclotronemission（ECE）,thecouplingspatialstructuresandcouplingprocessbetweenthesetwomodesareanalyzedindetail.TheresultsofSVDforECErevealthatthephasedifferencebetweenthesetwomodesequalstozero.Thisisconsistentwiththeperfectcouplingcondition.Finally,performingstatisticalanalysisofγ1/1,ζ1/1andω2/1,wefindthatγ1/1moreaccuratelyrepresentsthecouplingstrengththanζ1/1,andγ1/1isalsostronglyrelatedtothe（2,1）NTMtriggering,whereγ1/1isthewidthof（1,1）internalmode,ζ1/1istheperturbedamplitudeof（1,1）internalmode,andω2/1denotesthemagneticislandwidthof（2,1）NTM.

简介：本文通过比较两个不同晶体生长历史的温梯法Al2O3晶体，通过同步辐射衍射形貌相研究了晶体内部的完整性，在正常晶体生长条件下Al2O3晶体的FWHM仅为10弧秒，而在正常晶体生长受到间停电破坏时，Al2O3晶体内易出现亚晶粒等缺陷。其内在原因与温梯法晶体生长工艺有关系。