P2O5.BaO.Na2O.K2OglassesdopedwithvariouscontentofEu2O3werepreparedusinghightemperaturemeltingmethod,andtheEu2+ionsinthephosphateglasseswereobtainedwiththeaidofthereductiveactionofsiliconpowder.Thefabricatingconditions,fluorescence,excitationspectraoftheglasseswerethenstudied.Theglassescontainingeuropiumshowabroademissionbandat450nmandsharpbandsfrom580to650nm,andtheco-existenceofEu2+andEu3+isidentified.Also,agoodglasswithadominantproportionandlargequantityofEu2+ionscanbeobtainedbythereductiveactionofsiliconpowderandproperprocessing.