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  • 简介:铝和铬的性质有不少相似之处.它们都是两性金属,既能溶于酸又能溶于强碱;都被冷的浓硝酸钝化,其氧化物Al2O3、Cr2O3都是熔点高、硬度大的物质,其氢氧化物AlOH3、Cr(OH3都是难溶于水的两性氢氧化物,既能溶于酸又能溶于强碱.本文利用Al—H2O系统的(?)—pH图及Cr—H2O系统的(?)—pH图,对铝和铬及其氢氧化物的两性进行分析.一、Al—H2O系统(?)—pH图图1为Al—H2O系统的(?)—pH图,其作法是:(?)线代表H+/H2线.根据(?)(H+/H2)=-0.0592pH-(0.0592/2)1g(P(H2))

  • 标签: 两性金属 两性的 AL CR OH 图图
  • 简介:关于AlOH3沉淀问题常见三大类:第一类是OH^-与Al^3+液相混合;第二类是H^+和AlO2^-液相混合;第三类是Al^3+与AlO2^-液相混合。

  • 标签: 解法 沉淀问题 AL(OH)3 数形结合 中学 化学
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  • 简介:Researchonnewtypesofcastables,pre-castassemblypartsandthermalinsulationmaterialswithgoodresistancetowear,thermalshockanderosion,andlowthermalconductivity,wasdonetosolveproblemsofhighsystemenergyconsumption,crackingandspallingofpartialliningandmismatchoffurnacetopmaterialandhangingmaterialandsoon,causedbyunreasonabledesignofChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacelining.Severaldifficultproblemssuchasthematchingofdifferentmaterials,preservationofexpansionjointsamongdifferentzonesandreasonablemechanicaldistributionofliningweresolved.'Integratedfurnace'conceptwasestablishedincludingrefractoriesR&D,liningstructuredesign,constructionoptimization,furnacewarmingtechnology,initialoperationandliningmaintenancetechnology.Thekeytechnologiesofhigh-efficiencyandenergy-savingforfurnacesweredeveloped.TheseachievementshavebeenappliedtoChina'sAl(OH)3dilutephasefluidizedbedroastingfurnacestoreduceenergyconsumptionby1000MJpertonalumina,enhancethecapacityandreducetheexhaustgasemission.

  • 标签: AL(OH)3 流化床 能源效率 稀相 烧烤炉 技术
  • 简介:ThephaseandmorphologytransformationduringthehydrothermaltreatingprocessofY2O3wasevaluatedwithX-raydiffcrcnce(XRD),scanningelectronmicroscopy(SEM),transmissionelectronmicroscopy(TEM),particlesizeandspecificsurfaceareadetermination.TheresultsshowedthatthecubicY2O3didnottransferintohexagonalY(OH)3inpurewater.Therefore,purehexagonalY(OH)3withnanotubeandmicrorodmorphologieswereobtainedbyhydrothermaltreatingY2O3at150℃for12hin15mlof2mol/LNaOHsolutionwithandwith-outPVAorPEGItwassuggestedthatthecharacteristicpreferentialgrowthofY(OH)3wasattributedtothestructureanisotropyofhexahedronY(OH)3.TheadditionofPVAorPEGcouldpromotetheformingprocessofnanotubesbyselectiveadsorptionondifferentcrystalplanes,whichalteredthegrowthratealongdifferentdirectionsandresultedinthediffusionlimitofconstructingionsinthecentertopofrods.Finally,Y(OH)3:EuandY2O3:Eunanotubeswerealsosynthesizedbyusingthismethod,andtheirphotoluminescencepropertieswereevaluated.

  • 标签: HYDROTHERMAL synthesis Y(OH)3 Y(OH)3:Eu Y2O3:Eu NANOTUBE
  • 简介:Anewμ3-Otriiron(Ⅲ)complex[Fe3O(OBz)6(CH3OH3](NO3)(CH3OH)2(HOBZ=benzoicacid)hasbeensynthesized,itsstructurehasbeendeterminedandvariabletemperaturemagneticsusceptilityhasalsobeenmeasured.Inthemolecule,threeironatomsformedanequilateraltrianglewithu3-Oincenter.ThefittingtothemagneticsusceptibilityshowedthatanintramolecularantiferromagneticexchangeinteractionoccurredbetweenironatomswithJ=-25.51cm-1,andaweakerintermolecularantiferromagneticexchangeinteractionoccurredwithzJ’=-2.30cm-1.

  • 标签: Crystal STRUCTURE MAGNETIC exchange triiron complex.
  • 简介:Al(0H)3是环境友好的阻燃剂。由于Al(0H)3与高分子界面相容性差,所以在高分子基相中容易团聚。在以往关于粒径小于100nm或粒径在几到几十微米的AlOH),填充聚烯烃的研究中,实验结果多是AlOH3填充使聚烯烃的冲击强度、拉伸强度均降低。

  • 标签: AL(OH)3 河北科技大学 球晶结构 性能 PP 超细
  • 简介:胶体的电泳现象是胶体的重要性质之一,但教材没有安排相应的实验.据说是因该实验现象不够明显,且费时较长.我们高二化学研究性学习小组为了让同学们能看个究竞,决定依据教材中所配电泳现象的实验插图进行实验探究.

  • 标签: 电泳现象 实验探究 小组 高二化学 教材 研究性学习
  • 简介:我们集中于与Ni-Al金属间化合的混合物扔合金由的ligth重量的表面加强在原处改进非铁的扔的表面性质的燃烧反应部件。在我们的以前的工作,元素的Ni和艾尔粉末紧缩的绿色被SHS(自我繁殖的高温度合成)反应到形式Ni3Al金属间化合的化合物有熔融的艾尔合金并且同时的热的反应与艾尔扔结合了合金。但是象微小的裂缝和孔那样的一些缺点在反应协议被仍然是。我们因此使用了压力阻止热裂缝并且与液体艾尔合金充满毛孔由压榨扔过程。压缩艾尔合金与Ni3Al金属间化合的混合物结合了是sectioned并且由光显微镜学和扫描电子显微镜学(SEM)观察了。在结合的接口附近并且在反应协议形成的intermetallics的stoichiometric作文被散光谱学(版本)和电子探查的精力识别微分析(EPMA).Si富人层被艾尔的顺序的团结在结合的接口附近在艾尔合金方面上形成合金。在反应Ni3Al协议观察的孔与液体艾尔合金被充满。从熔融的艾尔合金的Si粒子在反应Ni3Al金属间化合的协议的毛孔被检测。扔合金和Ni3Al金属间化合的化合物的艾尔被把压力用于液体艾尔合金很很熟加入。

  • 标签: 压力 燃烧合成技术 铝合金 物理性能
  • 简介:ItwasshownbyTEMandX-rayanalysisthatNi3AlisthemainphaseoftheintermetallicsynthesizedundercompressionfromthepowdermixtureofNiwithAlalloyedbyB.TheNi3Bisasecondaryphase.ThevalueofthelatticeparameteroftheintermetallicNi3AlwithandwithoutBincreaseswhentheconcentrationofAlincreases.TheincreaseinAlconcentrationfrom23.5to25.0intheinitialpowdermixtureleadstodecreasingthesolubilityofBintheNi3Alphase.

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  • 简介:在situcomposites在艾尔矩阵上研究严重塑料变丑的影响规则,10?wt%艾尔3在situ的Zr/2024Al增强粒子合成被准备由直接融化反应(DMR),然后,合成是由有90的一个方向的热伪造?%塑料变丑。然后,前进状态的微观结构合成被观察,并且机械性质的变化法律和磨擦表演在以后并且在塑料使变形前被比较。结果显示艾尔3增强Zr的粒子旋转并且闯入10-20的更小的尺寸?ng可溶的biopolymer有三个转变金属离子的牛的浆液白朊(BSA)(M,M=Cu,公司,Mn)。白朊一定的金属离子的有约束力的模式和比率被调查。BSA-M建筑群被紫外力的、圆形的二色性(CD)描绘系列和polyacrylamide胶化电气泳动(页)。当聚合物支架和金属建筑群作为催化活跃中心工作了,BSA服务了。当到BSA的转变金属离子建筑群的有约束力的比率是5:1时,结果证明BSA的结构仍然保持未改变。而且,清除superoxide阴离子自由的基(O\(_{2}^{\bullet-}\??

  • 标签: 原位复合材料 AL3ZR 摩擦性能 微观结构 颗粒增强复合材料 复合材料基体
  • 简介:Al2O3/Al的三个系列把陶器的矩阵composites,命名矿泉,SPV和HP压成薄片,被不同方法制作。矿泉和SPV经由屏幕在空或真空中打印和随后的热处理用Al2O3片和艾尔泥浆被准备。HP样品被热压成为艾尔陪衬和Al2O3片的分层的栈。SEM和XRD被使用分析微观结构和夹层水晶阶段。弯曲力量,破裂坚韧和三个方法做的样品的破裂工作被测量并且比较。结果证明composites比Al2O3片有好一些的坚韧和更高的破裂工作。在三个方法做的样品之中,热压做的样品有最佳机械性能。排水量负担曲线和骨折机制被分析。

  • 标签: 陶瓷基复合材料 力学性能 制备 AL2O3/AL 叠层 惠普公司
  • 简介:HotcompressionbehaviorofTiC–Al2O3/AlcompositeswasstudiedusingtheGleeble-1500systematatemperaturerangeof300–550°Candatstrainraterangeof0.01–10.00s-1.TheassociatedstructuralchangeswerestudiedbyTEMobservations.Theresultsshowthatstressleveldecreaseswithdeformationtemperatureincreasingandstrainratedecreasing,whichcanberepresentedbyaZener–Hollomonparameterinanexponent-typeequationwithhotdeformationactivationenergyQof172.56kJ·mol-1.Dynamicrecoveryoccurseasilywhenstrainratesarelessthan10.00s-1.Dynamicrecrystallizationcanoccuratstrainrateof10.00s-1.

  • 标签: TiC–Al2O3/Al COMPOSITES HOT DEFORMATION Flow stres
  • 简介:ThecorrelationbetweenphasestructuresandsurfaceacidityofAl2O3supportscalcinedatdifferenttemperaturesandthecatalyticperformanceofNi/Al2O3catalystsintheproductionofsyntheticnaturalgas(SNG)viaCOmethanationwassystematicallyinvestigated.Aseriesof10wt%NiO/Al2O3catalystswerepreparedbytheconventionalimpregnationmethod,andthephasestructuresandsurfaceacidityofAl2O3supportswereadjustedbycalciningthecommercialγ-Al2O3atdifferenttemperatures(600–1200C).COmethanationreactionwascarriedoutinthetemperaturerangeof300–600Catdifferentweighthourlyspacevelocities(WHSV=30000and120000mL·g-1h-1)andpressures(0.1and3.0MPa).ItwasfoundthathighcalcinationtemperaturenotonlyledtothegrowthinNiparticlesize,butalsoweakenedtheinteractionbetweenNinanoparticlesandAl2O3supportsduetotherapiddecreaseofthespecificsurfaceareaandacidityofAl2O3supports.Interestingly,NicatalystssupportedonAl2O3calcinedat1200C(Ni/Al2O3-1200)exhibitedthebestcatalyticactivityforCOmethanationunderdifferentreactionconditions.LifetimereactiontestsalsoindicatedthatNi/Al2O3-1200wasthemostactiveandstablecatalystcomparedwiththeotherthreecatalysts,whosesupportswerecalcinedatlowertemperatures(600,800and1000C).ThesefindingswouldthereforebehelpfultodevelopNi/Al2O3methanationcatalystforSNGproduction.

  • 标签: Ni catalyst ALUMINA CO METHANATION synthetic
  • 简介:A60%Fe/Al2O3catalystwaspreparedbytheco-precipitationmethod.ItwasreducedbyH2toproducemetallicFe,whichwasthensulfidedbyCS2toFe0.96SandFe3S4orphosphidedbytriphenylphosphine(PPh3)inliquidphasestoFe2PandFeP.Itwasfoundthattheironsulfides(Fe0.96SandFe3S4)exhibitedthelowactivityforthehydrodesulfurization(HDS)reactions.TheHDSactivitywasalsolowontheFe(metal)/Al2O3andFe2P/Al2O3catalystssincetheywereconvertedintoFe0.96SandFe3S4duringtheHDSreactions.Incontrast,theFeP/Al2O3wasfoundtobestableandactivefortheHDSreactions.Inparticular,FeP/Al2O3possessedsignificantlysmallerFePparticlesthanFeP/C,leadingtothesignificanthigherHDSactivityofFeP/Al2O3thanFeP/C.

  • 标签: Fe2P/Al2O3 CATALYST FeP/Al2O3 CATALYST Liquid phase
  • 简介:TheinteractionbetweenZn-AleutecticalloyandAl2O3p/6061Alcompositesinthevacuumfurnacewasinvestigated.Greatattentionhasbeenpaidtotheelementsdiffusion,themicrostructureandformationoftheinterfacebetweenZn-AIeutecticalloyandAl2O3p/6061Alcomposites.ExperimentalresultsshowthatZn-AleutecticalloyhasagoodwettingabilitytoAl2O3p/6061Alcompositesandthewettingangledecreaseswithincreasingthetemperatureinvacuum.Aftertheinteraction,aninteractionlayerformsbetweenZn-AIalloyandAl2O3p/6061Alcomposites.Thephasesintheinteractionlayermainlyconsistofα-Al(Zn),Al2O3andCuZn5resultedfromthediffusionofelementsfromtheZn-Alalloy.SeveralporositiesdistributeintheregionneartheinterfaceoftheZn-Alalloy/interactionlayer.TheamountofshrinkagevoidsintheinteractinglayerisrelevanttothepenetrationofZnelementintoAl2O3p/6061Alcompositeswhichisafunctionoftemperature.SoitisnecessarytolowerheatingtemperatureinordertolimittheZnpenetration.

  • 标签: 锌铝共晶合金 Al2O3p/6061Al化合物 湿润 界面微结构 焊接技术
  • 简介:IntroductionAsitiswell-known,Yamāri'sPramā(n)avārttikāla(n)kāra(t)īkāSupari(s)uddhā(hereafterPVATS)1onPraj(n)ākaragupta'sPramā(n)avārttikāla(n)kāra(hereafterPVA)containsalotofmaterialsconcerningvarioustopicswhichareveryimportantforhistoricalreconstructionofthelaterdevelopmentoftheBuddhistepistemologicalsystem,especiallythetraditionbeginningwithDharmakīrti'sPramā(n)avārttika(hereafterPV).

  • 标签: 开本 认识论 PVA