简介:Theproceduresofultrasonicextractionandclean-upwereoptimizedforthedeterminationofpolycyclicaromatichydrocarbons(PAHs)inmarinesediments.Sampleswereultrasonicallyextracted,andtheextractswerepurifiedwithaminiaturizedsilicagelchromatographiccolumnandanalyzedwithhighperformanceliquidchromatography(HPLC)withafluorescencedetector.Ultrasonicationwithmethanol-dichloromethane(2:1,v/v)mixturegavehigherextractionefficiencythanthatwithdichloromethane.Amongthethreeelutionsolventsusedinclean-upstep,dichloromethane-hexane(2:3,v/v)mixturewasthemostsatisfactory.Undertheoptimizedconditions,therecoveriesintherangeof54.82%to94.70%withRSDsof3.02%to23.22%foraspikedblank,andintherangeof61.20%to127.08%withRSDsof7.61%to26.93%foraspikedmatrix,wereobtainedforthe15PAHsstudied,whiletherecoveriesforaNISTstandardreferenceSRM1941bwereintherangeof50.79%to83.78%withRSDsof5.24%to21.38%.Thedetectionlimitswerebetween0.75ngL-1and10.99ngL-1fordifferentPAHs.AsamplefromtheJiaozhouBayareawasexaminedtotesttheestablishedmethods.
简介:采用5水平Box-Behnken设计的反应表面方法论(RSM)被用来优化铈(III)的biosorption到动物和植物起源viz的biowaste材料上。对虾甲壳(PC)和玉米风格(CS)。各种各样的过程参数viz。pH(一:3.0–9.0),生物资源剂量(B:0.05–0.35g/L),起始的金属集中(C:50–350mg/L),接触时间(D:2–6h)并且温度(E:20–60°C)为优化被选择。木头转变被盒子艇长阴谋在现在的盒子中建议。低p值<0.0001验证了模型的意义。为PC的218.3mg/g和为CS的180.2mg/g的最大的Ce(III)举起在最佳条件下面被注意。在平衡等温线之中,Freundlich模型被发现是而兰米尔模型证明最好适合在CS上建议铈biosorption的同类的模式,在PC上建议biosorption的一个异构的模式的最好适合的那个。这被扫描电子显微镜学(SEM)进一步证实。运动研究显示出作为位于这个过程下面的现象建议physisorption的伪first顺序模型的更好的适用性。电影散开被博伊德阴谋的非线性建议。热力学的研究证明这个过程吸热、自发。FTIR分析在Ce(III)biosorption期间证实了酰胺,胺,酉同类和主要白酒组的参予的主要参与。EDAX分析在Ce(III)biosorption期间证实了碳组的主要参予。这是Ce(III)biosorption的参数优化上的第一份报告到用可能从水的环境对Ce(III)的恢复有用的5水平Box-Behnken试验性的设计的biowaste材料上。
简介:ThepresentstudywasdesignedtoisolateandcharacterizeapurifiedextractfromFusariumsolaniFG319,termedMFS(MetaboliteofFusariumsolaniFG319)thatshowedanti-atherosclerosisactivitybyinhibiting3-hydroxy-3-methylglutarylcoenzymeA(HMG-CoA)reductase.Responsesurfacemethodology(RSM)wasemployedtoachieveanimprovedyieldfromthefermentationmedium.Theinhibitingeffectoftheisolate,MFS,onHMG-CoAreductasewasgreaterthanthatofthepositivecontrol,lovastatin.TheaveragerecoveryofMFSandtherelativestandarddeviation(RSD)rangedbetween99.75%to101.18%,and0.31%to0.74%,respectively.TheRSDsintra-andinter-assayofthethreesamplesrangedfrom0.288%to2.438%,andfrom0.934%to2.383%,respectively.FromtheRSM,theconcentrationofinducer,cultivationtime,andculturetemperatureshadsignificanteffectsontheMFSproduction,withtheeffectofinducerconcentrationbeingmorepronouncedthatotherfactors.Inconclusion,theoptimalconditionsfortheMFSproductionwereachievedusingRSMandthatMFScouldbeexploredasananti-atherosclerosisagentbasedonitsabilitytoinhibitHMG-CoAreductase.
简介:一个光标签的标签扑灭比率和分散赔偿正在交换传播系统优化,它采用40-Gb/s回来到调音的零微分阶段移动(RZ-DPSK)用622-Mb/s振幅移动调音标记的收费载重(问)控制数据。在我们的计划,收费载重和标签的接收装置敏感分别地完成-27.8dBm和-33.5dBm。在在40km上播送了以后,60km和80km挑选模式纤维(SMF)(与分散赔偿)分别地,收费载重能没有力量惩罚被恢复,当标签能与不到2dB惩罚被恢复时。
简介:Thesynthesis,compositionoptimization,VUVPhotoluminescence(PL)spectra,andopticalproperties,of(Y,Gd)(V,P)O4∶Eu3+phosphorswereinvestigatedbysynchrotronradiation.TheVUVPLEspectraandthecorrelationamongVUVPLintensity,λem,andEu3+,Gd3+,andP-contentwereestablished.ThePLEspectralstudiesshowedthat(Y,Gd)(V,P)O4∶Eu3+exhibitedsignificantabsorptionintheVUVrange.TheVUVPLintensitywasfoundtoenhancewithPO43-andGd3+-doping.Furthermore,thechromaticitycharacteristicsof(Y,Gd)(V,P)O4∶Eu3+werealsofoundtobe(0.6614,0.3286)andcomparedagainst(Y,Gd)BO3∶Eu3+asareference.Basedonthecharacterizationresults,wearecurrentlyimprovingandevaluatingthepotentialapplicationof(Y,Gd)(V,P)O4∶Eu3+asanewred-emittingPDPphosphor.