简介：Inthiswork,MoOxpromotedIr/SiO2catalystswerepreparedandusedfortheselectivehydrogenolysisoftetrahydrofurfurylalcohol(THFA)to1,5-pentanediolinacontinuousflowreactor.Theeffectsofdifferentnoblemetals(Ir,Pt,Pd,Ru,Rh),supportsandIrcontentswerescreened.Amongtheinvestigatedcatalysts,4wt%Ir-MoOx/SiO2withaMo/Iratomicratioof0.13exhibitedthebestcatalyticperformance.ThesynergybetweenIrparticlesandthepartiallyreducedisolatedMoOxspeciesattachedonthemisessentialfortheexcellentcatalyticperformanceofIr-MoOx/SiO2.ThecatalystexhibitedabetterhydrogenolysisefficiencyofTHFAwiththeselectivityof1,5-pentanediolof65%–74%ataconversionofTHFAof70%–75%whentheinitialTHFAconcentrationisrangingfrom20wt%and40wt%.AndhighersystempressurewasalsoinfavoroftheconversionofTHFA.Duringastabilitytest,theconversionofTHFAand1,5-pentanediolyieldoverIr-MoOx/SiO2decreasedwithreactiontime,whichcanbeexplainedbytheleachingofMospeciesduringthereaction.

简介：我们在aquantum旋转网络的二平行1D旋转链调查纠纷转移，并且证明完美的纠纷转移能在somespecial时间被认识到。另外，“纠纷的现象在thespin被发现的所谓的突然的死亡”网络系统。

简介：用变分方法证明H~1（R~N）上一个带限制的半线性椭圆特征问题解的存在性.所获得的三个解：一个是正解,一个是负解.对于第三个解,本文只证明了它的存在性,而没有确定它是正解,负解,还是变号解.

简介：<正>一、中考内容要求"数与式"是初中数学的核心内容之一.实数与代数式在中考试题中所考查的知识主要有:有理数,倒数,相反数,绝对值,数轴的运用,实数的大小比较,乘方,科学记数法,有效数字,二次根式,实数的估算,列代数式,解析代数式,求代数式的值,探求数与式的规律.实数和代数式是初中数学的基础,也是每年中考的必考知识点.考试题型既有灵巧的填空题和选择题,也有独立的计算题.运用实数知识解决社会生活中的

简介：TheL-proline-functionalizedpolystyrenewith1-methyldecylenespacerwassynthesizedfrom2%divinylbenzene-crosslinkedpolystyrenegelvia10-bromo-1-methyldecylpolystyreneintermediate.Aftercomplexedwithcopper(Ⅱ）ion,thepolymerwithL-prolineligandwasusedasthechiralstationaryphase(CSP)forligandexchangechromatographyofaminoacidracemates.TheresultsshowedthattheCSPpossessedpowerfulenantioselectivityandallracematesofthefifteentriedaminoacidswerecompletelyseparated.

简介：Underinvestigationinthispaperisa(3+1)-dimensionalvariable-coefficientKadomtsev–Petviashviliequation,whichdescribesthepropagationofsurfaceandinternalwaterwaves.ByvirtueofthebinaryBellpolynomials,symboliccomputationandauxiliaryindependentvariable,thebilinearforms,solitonsolutions,B¨acklundtransformationsandLaxpairareobtained.Variablecoefficientsoftheequationcanaffectthesolitonicstructure,whentheyarespeciallychosen,whilecurvedandlinearsolitonsareillustrated.Elasticcollisionsbetween/amongtwoandthreesolitonsarediscussed,throughwhichthesolitonskeeptheiroriginalshapesinvariantexceptforsomephaseshifts.

简介：Aseriesofbenzo-fusedheteroaromaticcompoundswith5-,6-and7-memberedtings,suchasbenzimidazole,quinoxalineand1H-1,5-benzodiazepinederivatives,weresynthesizedthroughcondensationreactionofo-pheny1-enediaminewithary1aldehydesorketones.Theexperimentalconditionswerecarefullyexamined,andtheproductswerecharacterizedby^1HNMR,^13CNMR,MS,IRandelementalanalyses.Inaddition,thestructureofabenzodiazaepinederivativewith7-memberedringwasconfirmedbysinglecrystalX-raydiffractionanalysis.

简介：ＩｎｔｒｏｄｕｃｔｉｏｎＨｅｔｅｒｏｂｉｎｕｃｌｅａｒｃｏｍｐｌｅｘｅｓａｒｅｅｒｙｖｅｒｙｉｍｐｏｒｔａｎｔｉｎａｎａｔｅｍｐｔｔｏｍｉｍｉｃｔｈｅｓｔｒｕｃｔｕｒａｌａｎｄｆｕｎｃｔｉｏｎａｌｐｒｏｐｅｒｔｉｅｓｏｆｂｉｏｌｏｇｉｃａｌｓｙｓｔｅ...

简介：对将运行于日-地L1点的太阳观测器进行了热设计，重点论述了日-地L1点的轨道外热流计算和Lymanα日冕仪（LACI）反射镜M2光阱、Lymanα日冕成像仪（LADI）滤光片组件、CCD组件、电箱、观测器主体等部分的热设计方案。通过在探测器对日面设置集热板，将观测器的主动加热功耗降低了73％；选用预埋热管的设计方案解决了对日定向观测导致的框架温差问题。仿真分析结果表明，在对日高温工作、对日低温工作、低温存储、轨道转移等4个极端工况下，观测器各组件温度均满足指标要求。该热设计方案以较低的加热功耗，解决了太阳观测器在轨工作阶段的散热、轨道转移阶段的保温等问题，满足CCD焦面工作温度＜-50℃的要求。

简介：根据财政部等五部委的要求，《企业内部控制基本规范》（财会[2008]7号）及其配套指引已于20儿年1月1日起在境内外同时上市的69家公司实施。同时，财政部、证监会又选择了200多家在境内主板上市的公司进行试点。实施一年总体进展顺利，

简介：

简介：Perovskite-typeLa1-xCexMnO3（x=0-10%）catalystswerepreparedbyflamespraypyrolysisandtheiractivitiesduringthecatalyticoxidationofbenzenewereexaminedoverthetemperaturerangeof100-450℃.ThestructuralpropertiesandreducibilityofthesematerialswerealsocharacterizedbyX-raydiffraction（XRD）,N2adsorption/desorption,H2temperature-programmedreduction（H2-TPR）andX-rayphotoelectronspectroscopy（XPS）.TheincorporationofCewasfoundtoimprovethebenzeneoxidationactivity,andtheperovskiteinwhichxwas0.1exhibitedthehighestactivity.Phasecompositionandsurfaceelementalanalysesindicatedthatnon-stoichiometriccompoundswerepresent.TheincorporationofCehadanegligibleeffectonthespecificsurfaceareaoftheperovskitesandhencethisfactorhaslittleimpactonthecatalyticactivity.IntroductionofCe44+resultedinmodificationofthechemicalstatesofbothB-siteionsandoxygenspeciesandfacilitatedthereducibilityoftheperovskite.ThesurfaceMn4+/Mn3+ratiowasincreasedasaresultofCe4+substitution,whileadecreaseinthesurface-adsorbedO/latticeO(Oads/Olatt)ratiowasobserved.Therelationshipbetweenthesurfaceelementalratiosandcatalyticactivitywasestablishedtoallowabetterunderstandingoftheprocessbywhichbenzeneisoxidizedoverperovskites.

简介：Cobaltandnickelcomplexes(1a-1dand2a-2d,respectively)supportedby2-imidate-pyridineligandsweresynthesizedandusedfor1,3-butadienepolymerization.ThecomplexeswerecharacterizedbyIRandelementanalysis,andcomplex1awasfurthercharacterizedbysingle-crystalX-raydiffraction.Thesolidstatestructureofcomplex1adisplayedadistortedtetrahedralgeometry.Uponactivationwithethylaluminumsesquichloride(EASC),allthecomplexesshowedhighactivitiestoward1,3-butadienepolymerization.Thecobaltcomplexesproducedpolymerswithhighcis-1,4contentsandhighmolecularweights,whilethenickelcomplexesdisplayedlowcis-1,4selectivityandtheresultingpolymershadlowmolecularweights.Thecatalyticactivitiesofthecomplexeshighlydependedontheligandstructure.Withtheincrementofpolymerizationtemperature,thecis-1,4contentandthemolecularweightoftheresultingpolymerdecreased.

简介：Refluxingcalix[4]-1,3-substitutedbenzaldehydederivative(4)withglycinehydrazidederivative,weobtainedanovelcalix[4]arenehydrazonederivative(5)via'1+2'condensationinayieldof78%.Inthereactionofcompound4withL-leucinehydrazidederivativeatroomtemperature,lariatcalix[4]-1,3-aza-crown(6)withchiralaminoacidgroupasbranchedchainwassynthesizedvia'1+1'additioninayieldof70%.Thepreliminaryextractionexperimentssuggestedthathostingcompounds5and6possessedgoodcomplexationabilitiesforα-aminoacids.

简介：应用分子力学、半经验量子化学RM1方法优化了32个抗野生型HIV-1病毒毒株的二芳基嘧啶类（DAPYs）化合物分子结构，从分子构象模型中提取了多种参数并结合疏水性参数与指示性参数建立QSAR多元线性回归方程．回归方程显示：分子体积V的增大会降低其抑制活性，而左苯环与嘧啶环间二面角日增大可以提高抑制活性．同时指示性参数工表明左苯环CN基团加入可以明显增加抑制活性，嘧啶环上R1位置苯基与硝基的加入可以极大降低抑制活性．

简介：给出了一种利用BP神经网络从中子活化测量数据中直接求解1MeV等效中子注量的新方法。该方法选用了含两层隐藏层的BP神经网络,并围绕先验谱建立输入输出集合,对网络进行训练、检验和测试,最终形成含20个BP神经网络的网络群。该BP神经网络群可实现在输入测量活化率数据后,直接输出相应的1MeV等效中子注量。利用该方法求解了西安脉冲堆大空间中子辐照实验平台内的1MeV等效中子注量。与实测中子能谱计算的1MeV等效中子注量结果对比,二者偏差小于6.6%。

简介：证明了指数型超椭圆方程x^2=p^2m-p^m＋n＋1无解（x，p，m，n），其中x，m，n∈N^＋，m〉n〉1，p∈P．上述结果部分解决了组合论中关于可逆Abel差集的Ma猜想．

简介：研究了同时考虑单重休假和N-策略两种休假策略的排队系统，其休假准则为任一个条件满足．我们给出了此排队系统的稳态队长，忙期分布等基本指标，并得到稳态等待时间的LST（Laplace—StieltjesTrans—form）。

简介：<正>以0,1为元素所构成的n阶方阵A=(aij)n×n,i,j=0,1,2,…n-1,其元素之间的加法与乘法运算按下列方式:则称A为布尔矩阵,文[1],[2]对这类矩阵的性质作了深入的研究和全面的介绍,文[4][5]给出了经典循环矩阵可约性和本原性的条件,本文给出了另一类循环布尔矩阵的可约性和本原性的充分必要条件。设g是一个非负整数,一个n阶g-循环矩阵A=(aij)n×n是一个这样的矩阵,除

简介：关于递推数列Ｘｎ＋１＝（ａｘｎ＋ｂ）／（ｃｘｎ＋ｄ）的极限的注记田文平（南京审计学院）关于递推数列Ｚ．＋ｌ一；；＝：一的极限．文Ｄ」给出了下面两个结论：”—”——“”””“”－ｘ＋ｄ”“”’””““－“”“““’””“’—””“”结论１设数列?..