简介:Micro-mesoporouscompositemolecularsievesH-ZSM-5/MCM-41werepreparedbythehydrothermaltechniquewithalkali-treatedH-ZSM-5zeoliteasthesourceandcharacterizedbyscanningelectronmicroscopy,transmissionelectronmicroscopy,energydispersivespectroscopy,X-raydiffraction,N2adsorption-desorptionmeasurementandNH3temperature-programmeddesorption.ThecatalyticperformancesforthemethanoldehydrationtodimethyletheroverH-ZSM-5/MCM-41wereevaluated.Amongthesecatalysts,H-ZSM-5/MCM-41preparedwithNaOHdosage(nNa/nSi)varyingfrom0.4to0.47presentedexcellentcatalyticactivitywithmorethan80%methanolconversionand100%dimethyletherselectivityinawidetemperaturerangeof170—300℃,andH-ZSM-5/MCM-41preparedwithnNa/nSi=0.47showedconstantmethanolconversionofabout88.7%,100%dimethyletherselectivityandexcellentlifetimeat220℃.Theexcellentcatalyticperformanceswereduetothehighlyactiveanduniformacidicsitesandthehierarchicalporosityinthemicro-mesoporouscompositemolecularsieves.ThecatalyticmechanismofH-ZSM-5/MCM-41forthemethanoldehydrationtodimethyletherprocesswasalsodiscussed.
简介:针对带有两级串联式ISD半主动悬架的二自由度模型,选取加权函数阵整定两级串联式ISD半主动悬架系统的性能指标,应用LMIH。控制算法设计出两级串联式ISD半主动悬架H∞输出反馈控制器,该方法能够有效地解决系统的鲁棒干扰抑制问题.仿真结果表明,与传统半主动悬架、两级串联式ISD被动悬架以及传统被动悬架相比,所设计两级串联式ISD半主动悬架能够有效改善汽车的乘坐舒适性和行驶安全性.