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简介:Intrinsiccarrierconcentration(ni)isoneofthemostimportantphysicalparametersforunderstandingthephysicsofstrainedSiandSi1-xGexmaterialsaswellasforevaluatingtheelectricalpropertiesofSi-basedstraineddevices.Uptonow,thereportonquantitativeresultsofintrinsiccarrierconcentrationinstrainedSiandSi1-xGexmaterialshasbeenstilllacking.Inthispaper,byanalyzingthebandstructureofstrainedSiandSi1-xGexmaterials,boththeeffectivedensitiesofthestatenearthetopofvalencebandandthebottomofconductionband(NcandNv)at218,330and393KandtheintrinsiccarrierconcentrationrelatedtoGefraction(x)at300KweresystematicallystudiedwithintheframeworkofKPtheoryandsemiconductorphysics.ItisfoundthattheintrinsiccarrierconcentrationinstrainedSi(001)andSi1-xGex(001)and(101)materialsat300KincreasessignificantlywithincreasingGefraction(x),whichprovidesvaluablereferencestounderstandtheSibasedstraineddevicephysicsanddesign.
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简介:Si_3N_4-Si_2N_2Ocomposites被液相sintering(LPS)与非结晶的缩放nano的氮化矽粉末制作。Si_2N_2O阶段被in-situreaction2Si_3N_4(s)+1.5O_2(g)=3Si_2N_2O+N_2(g)产生直到在体积的60percent的Si_2N_2O阶段的内容在1650t的sintering温度被获得并且当sintering温度增加了或减少时,减少了,显示反应是可逆的。集体损失,相对密度和平均谷物尺寸与增加sintering温度增加了。当sintering温度在1700degC下面时,Theaverage谷物尺寸是不到500nm。Thesintering过程包含复杂结晶化和阶段转变:非结晶的氮化矽->equiaxialalpha-Si_3N_4->equiaxial->Si_3N_4->杆--相似Si_2N_2O->像针的beta-Si_3N_4。小回合--塑造的beta-Si_3N_4粒子在Si_2N_2O谷物被骗诱,界定差错的高密度位于在1650degC的sintering温度的Si_2N_2O谷物的中间。坚韧在1600degCto7.2MPa从3.5Mpa中心点m~(1/2)增加了在1800degC的中心点m~(1/2)。坚硬在1600degC象21.5GPa(Vickers)一样高。
简介:Defectsofpolymer-derivedSi-C-OfiberswereintensivelystudiedbytheSEMandTEMtechniquesandtheiroriginationswerealsodiscussedonthebasisoffactorsexperiments.Thedefectswerefoundmainlyintheformofstrumaes,pitsandsplitsonsurfacesaswellasmicroflawnetworks,porosityclustersandinclusionsinthebulk.Factorsexperimentsrevealthatanonuniformoraninsufficientcuringwouldresultinlarger-sizedstru-maesorinteriormicroflaws.Gasevolutionratesduetodifferentfiringrateshaveagreatinfluenceontheformationofinternalmicrofiawsorporosityclustersandsomeoxidation-inducedpitsorsplitsmaybeformedonsurfacesbe-causeoratraceofoxygenorwatervaporaccumulatedfromtheflowinginertatmosphereduringpyrolysis.
简介:Si3N4/TiCnanocompositeceramicshavebeenfabricatedbyhotpressingtechniquewithAl2O3andY2O3asadditives.TheresultsshowedthatwelldispersedcompositepowderwascarriedoutbyaddingdispersantandadjustingpHvaluesofsuspensions.RemarkableincreaseinflexuralstrengthatroomtemperatureswasobtainedbyaddingnanoparticlesinSi3N4matrixwith10%(wtpct)ofnano-Si3N4and15%ofnano-TiC.Theflexuralstrength,fracturetoughnessandhardnesswere1025MPa,7.5MPa·1/2and15.6GPa,respectively.Themicrostructuresofmaterialswereanalyzedbyscanningelectronmicroscopy(SEM)andtransmissionelectronmicroscopy(TEM),whichindicatedthatTiCnanoparticlesdistributeinthematrixandatthegrainboundaries.Accordingtothefractureform,lowcontentsofnanoparticlescouldrefinematrixgrainsandleadtothecrackdeflectionaswellascrackpinning.Themultiplexmicrostructurewasformedbymixingnano-Si3N4particles.Thecracktrajectoriesexhibitedcrackdeflection,rod-likegrainbridgingandpull-out.
简介:有关于30-50nm的谷物尺寸的nanocrystallineMg2Si(n-Mg2Si)的Densification行为被hot-pressing在显示的400°C.The结果调查n-Mg2Si的那个thedensification过程展出了三线性segments:p<0.3GPa,0.3GPa
1.2GPa由Heckel决定了公式,在哪个之中在高压力范围p>1.2GPa的第三个快增加片断很少在常规纹理粗糙的polycrystallinematerials.Nevertheless被报导了,在调查的整个压力范围(0.125-1.500GPa),n-Mg2Si的densificationbehavior能是Kawakita公式p/C=(1/a)描述的井有在对协议的起始的孔的好同意的constanta=0.452的p+1/(ab)。
简介:TheagingbehaviorsofirradiatedtungstenbyhighenergySi3+andH+ionsaremainlyinvestigatedusinginternalfriction(IF)methodcombinedwithSEMtechnology.TheSEManalysisindicatesthatmoresevereirradiationdamageappearsinthesurfaceofsimultaneousdualSi3+H+irradiatedspecimenthanthatinthesequentialdualSi3+H+irradiatedspecimenorthesingleSi3+irradiatedspecimensbecauseofthesynergisticeffectofSiandHirradiation.TheIFbackgroundoftheirradiatedsampleisaboutoneorderofmagnitudehigherthanthatoftheunirradiatedsampleowingtotheexistenceofhighdensityfreshdislocationsinducedbySi/Hirradiation,InthesequentialdualSi3+andH+irradiatedspecimen,thehydrogenSnoek-Ke-Koster(SKK)peakassociatedwiththemovementofdislocationsdragginghydrogenatomsisobservedanditsheightdecreaseswithagingtimeatroomtemperature.AsforthesimultaneousdualSi3+H+irradiatedspecimen,however,thereisnosuchhydrogenSKKpeak.Thereasoncanbeexplainedashydrogendiffusionandpinningeffectofdislocations.
简介:Al-inducedlateralcrystallizationofamorphoussiliconthinfilmsbymicrowaveannealingisinvestigated.ThecrystallizedSifilmsareexaminedbyopticalmicroscopy,Ramanspectroscopy,transmissionelectronmicroscopyandtransmissionelectrondiffractionmicrography.Aftermicrowaveannealingat480℃for50min,theamorphousSiiscompletelycrystallizedwithlargegrainsofmain(111)orientation.Therateoflateralcrystallizationis0.04μm/min.Thisprocess,labeledMILC-MA,notonlylowersthetemperaturebutalsoreducesthetimeofcrystallization.ThecrystallizationmechanismduringmicrowaveannealingandtheelectricalpropertiesofpolycrystallineSithinfilmsareanalyzed.ThisMILC-MAprocesshaspotentialapplicationsinlargeareaelectronics.
简介:TheX-raydiffractionpeak-shiftmethodwasintroducedintothedeterminationofdeformationfaultprobability(α)ofFe-Mn-SialloyswithvariousMncontentsandthermomechanicalcyclingnumbers.Thepreciselatticeconstantsrequiredwereobtainedbynumericalcalculationinsteadofusingstandardsamplewithoutanyfault.Theinfluenceofinternalstressonthedeterminedαhasbeenevaluated,andthecausedrelativeerrorwasdeterminedasabout4%andthusnegligible.TheresultsshowthatthedeformationfaultprobabilityincreaseswithdecreasingMn-contentandincreasingcyclenumber,whicharequalitativelyconsistentwiththoseresultsofPsfdeterminedbypeak-broadeningmethod.
简介:AhypereutecticAl-Sialloypowderwaspreparedbyultrasonicgasatomizationprocess.Themorphologies,microstructureandphaseconstituentofthealloypowderwerestudied.TheresultsshowedthatpowderofthealloywasveryfineanditsrnicrostructurewasmainlyconsistedofSicrystalsplusintermetalliccompoundAl9FeSi3,whichwere.veryfineanduniformlydistributed.